GB454013A - Manufacture of acetals of polyvinyl alcohol - Google Patents
Manufacture of acetals of polyvinyl alcoholInfo
- Publication number
- GB454013A GB454013A GB5191/35A GB519135A GB454013A GB 454013 A GB454013 A GB 454013A GB 5191/35 A GB5191/35 A GB 5191/35A GB 519135 A GB519135 A GB 519135A GB 454013 A GB454013 A GB 454013A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- solution
- polyvinyl alcohol
- released
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/28—Condensation with aldehydes or ketones
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Polyvinyl acetals are manufactured, in a condition in which they can well be further treated, by dissolving, under pressure, a polyvinyl acetal, made in known manner, in a solvent which is gaseous at ordinary temperature and pressure but liquid under the pressure used in the dissolution, and releasing the solution obtained into a liquid or gaseous agent which does not dissolve the acetal, e.g. water, alcohol or alcohol diluted with water. Alternatively the acetal is produced in the solvent under pressure. Suitable volatile solvents are methyl chloride, ethyl chloride, dimethyl ether, ethylene oxide and similar bodies which owing to their content of halogen or oxygen have strong solvent properties, and also sulphur dioxide. The polyvinyl acetals may be prepared by reacting a carbonyl compound (e.g. acetaldehyde, p formaldehyde or a ketone, especially a hydroaromatic ketone) with a polyvinyl alcohol or ester in the presence of a strong acid as catalyst, e.g. a mineral acid such as sulphuric acid or an aromatic sulphonic acid such as toluenesulphonic acid. When the production of the acetal is effected in liquid sulphur dioxide, this substance itself acts as a catalyst, probably in the form of sulphurous acid, and also binds the water liberated in the reaction. In examples: (1) a formaldehyde acetal of polyvinyl alcohol, prepared by reacting polyvinyl acetate and formaldehyde in the presence of ethyl alcohol and sulphuric acid is precipitated in water, dried, and dissolved under pressure in sulphur dioxide, and the solution is released into water; (2) an acetaldehyde acetal prepared by reacting an aqueous solution of polyvinyl alcohol with acetaldehyde in the presence of hydrochloric acid is dried and treated as in (1); (3) a butyraldehyde acetal prepared by reacting polyvinyl alcohol in ethanol with butyraldehyde in the presence of sulphuric acid is worked up by steam distilling the solvent and drying under reduced pressure, and is then dissolved under pressure in methyl chloride and the solution is released into water; (4) polyvinyl alcohol and butyraldehyde or octoic aldehyde are reacted in a bomb in the presence of hydrochloric acid and dimethyl ether, and the solution is released into water; alternatively sulphur dioxide is used as solvent and the hydrochloric acid is dispensed with; (5) polyvinyl alcohol and acetaldehyde are reacted in a bomb in the presence of sulphur dioxide, and the solution is released into water; (6) polyvinyl alcohol and benzaldehyde are reacted in a bomb in the presence of hydrochloric acid and methyl chloride, and the solution is released into water. Samples have been furnished under Sect. 2 (5) of products obtained as follows: (1) polyvinyl acetate and formaldehyde are reacted in an autoclave in the presence of sulphur dioxide and hydrochloric acid, and the solution is released into water; (2) polyvinyl alcohol and isohexaldehyde are reacted in a bomb in the presence of propane and sulphuric acid, and the solution is released into a mixture of water and alcohol. The Specification as open to inspection under Sect. 91 contains an additional example according to which polyvinyl alcohol and paraformaldehyde are reacted in a bomb in the presence of sulphur dioxide, and the solution is released into water. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE454013X | 1934-02-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB454013A true GB454013A (en) | 1936-09-18 |
Family
ID=6538854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5191/35A Expired GB454013A (en) | 1934-02-17 | 1935-02-18 | Manufacture of acetals of polyvinyl alcohol |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB454013A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2204873A (en) * | 1987-04-09 | 1988-11-23 | David Charlesworth | Polymer coagulation methods and apparatus therefor: tubular prostheses |
-
1935
- 1935-02-18 GB GB5191/35A patent/GB454013A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2204873A (en) * | 1987-04-09 | 1988-11-23 | David Charlesworth | Polymer coagulation methods and apparatus therefor: tubular prostheses |
GB2204873B (en) * | 1987-04-09 | 1991-08-07 | David Charlesworth | Method and apparatus for making polymer material |
US5132066A (en) * | 1987-04-09 | 1992-07-21 | Newtec V.P. Limited | Method of forming a bio-compatible vascular prosthesis |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB416549A (en) | Improvements in the manufacture of cellulose and lignocellulosic materials | |
GB454013A (en) | Manufacture of acetals of polyvinyl alcohol | |
Spencer et al. | The action of diazomethane on lactones and on lignins | |
Pew | Structural Aspects of the Color Reaction of Lignin with Strong Acid2 | |
Jones et al. | 158. Studies in the polyene series. Part VI. The preparation of ethinylcarbinols from αβ-unsaturated aldehydes | |
US2180730A (en) | Alkyl 12-ketostearate | |
Phillips | The chemistry of lignin. I. Lignin from corn cobs | |
US1946459A (en) | Method for producing synthetic resin | |
Wright et al. | Studies on lignin and related compounds. XXVI. The properties of spruce lignin extracted with formic acid | |
GB510168A (en) | Manufacture of polymeric compounds | |
US2055391A (en) | Process of preparing acetals | |
GB489343A (en) | Manufacture of condensation products | |
GB484200A (en) | Improvements in or relating to the preparation of compositions containing urea-formaldehyde condensation products | |
GB327673A (en) | Improvements in the manufacture and production of condensation products of urea or derivatives thereof and formaldehyde | |
West | CONDENSATION PRODUCTS OF ETHYL ACETO-ACETATE. I. A NEW COMPOUND OF GLYOXAL AND ETHYL ACETO-ACETATE, FORMYLMETHYLENE-BIS-ACETO-ACETIC ESTER | |
GB261029A (en) | Improvements in the manufacture and production of condensation products of urea and formaldehyde | |
GB443967A (en) | The manufacture of tanning materials | |
GB477036A (en) | Improvements in or relating to the manufacture of cellulose derivative compositions | |
Clark et al. | Extractives of douglas fir and douglas fir lignin residue | |
GB568529A (en) | Improvements in or relating to the separation of reaction mixtures containing aldehydes | |
GB472066A (en) | Improvements in or relating to synthetic resins | |
SU61851A1 (en) | The method of obtaining cast transparent artificial resin | |
SU58289A1 (en) | The method of obtaining artificial tanning | |
GB484415A (en) | A process for the manufacture of condensation products from urea and/or thiourea and formaldehyde | |
GB717412A (en) | Resinous condensation products |