GB261029A - Improvements in the manufacture and production of condensation products of urea and formaldehyde - Google Patents
Improvements in the manufacture and production of condensation products of urea and formaldehydeInfo
- Publication number
- GB261029A GB261029A GB27912/26A GB2791226A GB261029A GB 261029 A GB261029 A GB 261029A GB 27912/26 A GB27912/26 A GB 27912/26A GB 2791226 A GB2791226 A GB 2791226A GB 261029 A GB261029 A GB 261029A
- Authority
- GB
- United Kingdom
- Prior art keywords
- urea
- formaldehyde
- condensation
- dimethylol
- employed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/10—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with acyclic compounds having the moiety X=C(—N<)2 in which X is O, S or —N
- C08G12/12—Ureas; Thioureas
Abstract
261,029. I. G. Farbenindustrie Akt.- Ges. Nov. 7, 1925, [Convention date]. Urea-formaldehyde condensation products.-In the production of urea-formaldehyde condensation products, the urea and formaldehyde comprising the starting materials are replaced by dimethylolurea, and the condensation is effected in an organic solvent in the absence of water using an acid condensing agent. Dimethylol-urea is obtained by the action of formaldehyde on urea in alkaline or neutral aqueous solution at ordinary temperature. Organic solvents can then be employed which are less suitable when working with urea and formaldehyde, e.g. methyl or ethyl alcohol, and acetone. A phenol or a mixture of phenols may also be employed as solvent; the formaldehyde liberated during the reaction is fixed by the phenol, thereby permitting of the condensation being carried out directly in casting- moulds. It is advantageous to add resins, plasticizers, talcum, diatomaceous earth, plaster of Paris, or the like. According to the examples, (1) dimethylol-urea is dissolved in hot ethyl alonhol and condensation started by the addition of hydrochloric acid; when the reaction is complete, sodium acetate is added, the alcohol evaporated in vacuo, and the product heated for some time; a hard glass results; (2) dimethylolurea is dissolved in ethylene glycol monoethyl ether and condensed by adding hydrochloric acid; after neutralization with sodium bicarbonate a clear, colourless lacquer is obtained, which may be mixed with diluents or other lacquers. The Specification as open to inspection under Sect. 91 (3) (a) states also that, in place of dimethylol-urea, products of higher molecular weight resulting from the condensation of urea and formaldehyde with splitting off of water may be employed, as well as analogous compounds obtainable from other aldehydes and urea or its derivatives. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE261029T | 1925-11-07 | ||
GB13404/28A GB319251A (en) | 1925-11-07 | 1928-05-07 | Improvements in the manufacture and production of condensation products of derivatives of urea and aldehydes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB261029A true GB261029A (en) | 1928-05-07 |
Family
ID=62527949
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB27912/26A Expired GB261029A (en) | 1925-11-07 | 1926-11-06 | Improvements in the manufacture and production of condensation products of urea and formaldehyde |
GB13404/28A Expired GB319251A (en) | 1925-11-07 | 1928-05-07 | Improvements in the manufacture and production of condensation products of derivatives of urea and aldehydes |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB13404/28A Expired GB319251A (en) | 1925-11-07 | 1928-05-07 | Improvements in the manufacture and production of condensation products of derivatives of urea and aldehydes |
Country Status (1)
Country | Link |
---|---|
GB (2) | GB261029A (en) |
-
1926
- 1926-11-06 GB GB27912/26A patent/GB261029A/en not_active Expired
-
1928
- 1928-05-07 GB GB13404/28A patent/GB319251A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB319251A (en) | 1929-09-09 |
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