GB405618A - Process for the manufacture of soluble arsenic-bismuth compounds - Google Patents
Process for the manufacture of soluble arsenic-bismuth compoundsInfo
- Publication number
- GB405618A GB405618A GB22146/32A GB2214632A GB405618A GB 405618 A GB405618 A GB 405618A GB 22146/32 A GB22146/32 A GB 22146/32A GB 2214632 A GB2214632 A GB 2214632A GB 405618 A GB405618 A GB 405618A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formaldehyde
- bismuth
- aminophenyl
- sodium
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XCUCRSRQUDMZLU-UHFFFAOYSA-N [As].[Bi] Chemical class [As].[Bi] XCUCRSRQUDMZLU-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- UMFBJQXMVPWYSB-UHFFFAOYSA-N acetic acid 2-amino-4-arsanylphenol Chemical compound C(C)(=O)O.OC1=C(C=C(C=C1)[AsH2])N UMFBJQXMVPWYSB-UHFFFAOYSA-N 0.000 abstract 2
- XUIVKWAWICCWIQ-UHFFFAOYSA-M sodium;formaldehyde;hydrogen sulfite Chemical compound [Na+].O=C.OS([O-])=O XUIVKWAWICCWIQ-UHFFFAOYSA-M 0.000 abstract 2
- -1 Aminoaryl arsenic-bismuth compounds Chemical class 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- QPULOVFQLRSNTH-UHFFFAOYSA-N aminoarsanylbenzene Chemical class N[AsH]C1=CC=CC=C1 QPULOVFQLRSNTH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 abstract 1
- 150000001622 bismuth compounds Chemical class 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- SULICOHAQXOMED-YDXPQRMKSA-H dibismuth;(2r,3r)-2,3-dihydroxybutanedioate Chemical compound [Bi+3].[Bi+3].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O.[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O.[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O SULICOHAQXOMED-YDXPQRMKSA-H 0.000 abstract 1
- QJQZEJFUIOWFMS-UHFFFAOYSA-N formaldehyde;sulfanediol Chemical compound O=C.OSO QJQZEJFUIOWFMS-UHFFFAOYSA-N 0.000 abstract 1
- DXRFSTNITSDOKK-UHFFFAOYSA-N formaldehyde;sulfurous acid Chemical compound O=C.OS(O)=O DXRFSTNITSDOKK-UHFFFAOYSA-N 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- VYGBQXDNOUHIBZ-UHFFFAOYSA-L sodium formaldehyde sulphoxylate Chemical compound [Na+].[Na+].O=C.[O-]S[O-] VYGBQXDNOUHIBZ-UHFFFAOYSA-L 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/94—Bismuth compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Aminoaryl arsenic-bismuth compounds, obtainable by the interaction of aminophenyl-arsines with bismuth compounds, are converted into stable, therapeutically-valuable compounds, soluble to neutral solutions, by treatment with formaldehyde - bisulphite or formaldehyde-sulphoxylate in the absence of air. According to the examples: (1) 4-hydroxy-3-aminophenyl-arsine acetate is combined with bismuth tartrate or with the sodium salt of bismuth 1 : 2-dihydroxybenzene-3 : 5-disulphonic acid in caustic soda solution and the product treated with formaldehyde-sodium sulphoxylate or formaldehyde-sodium bisulphite; (2) the reaction product of 4-hydroxy-3-aminophenyl-arsine acetate with bismuth chloride in acetone solution is treated with formaldehyde-sodium bisulphite.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE405618X | 1931-08-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB405618A true GB405618A (en) | 1934-02-06 |
Family
ID=6421962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB22146/32A Expired GB405618A (en) | 1931-08-06 | 1932-08-06 | Process for the manufacture of soluble arsenic-bismuth compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB405618A (en) |
-
1932
- 1932-08-06 GB GB22146/32A patent/GB405618A/en not_active Expired
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB405618A (en) | Process for the manufacture of soluble arsenic-bismuth compounds | |
| GB291991A (en) | Manufacture of dextrose | |
| GB425804A (en) | A process for the preparation of washing agents | |
| GB462693A (en) | Process for the manufacture of new acid wool dyestuffs of the anthraquinone series | |
| GB599073A (en) | Improvements in sulphur recovery | |
| GB460281A (en) | Improvements in or relating to the production of potassium sulphate | |
| GB350862A (en) | Manufacture of a stable reduction compound of a vat-dyestuff | |
| GB179031A (en) | A process for the manufacture of o-alkyl derivatives of hydrocupreine | |
| GB489612A (en) | Manufacture of fluorene derivatives | |
| GB265777A (en) | Improved process for the manufacture of organic auro-mercapto acids and salts thereof | |
| GB311986A (en) | Process for the production of white lead | |
| GB435721A (en) | Improvements in process for preparing metol | |
| GB483945A (en) | Process for the preparation of new compounds of therapeutic value | |
| GB425075A (en) | Process for making anhydrous citric acid | |
| GB357798A (en) | Process for the production of dry, high-grade calcium hypochlorite | |
| GB485805A (en) | Improved concentrated casein solutions having an acid reaction | |
| GB189968A (en) | Process of finishing textile fabrics | |
| GB389098A (en) | Process of separating 1-naphthylamine-8-sulfonic acid from its isomers | |
| GB274558A (en) | Improvements in and relating to the manufacture of derivatives, of the anthraquinone series | |
| GB455991A (en) | Process for the manufacture of a chrysene monosulphonic acid | |
| GB370724A (en) | Improved process for preparing beta-amino-anthraquinone | |
| GB462337A (en) | Manufacture of 2:6-dimethylnapththalene-7-sulphonic acid | |
| GB352283A (en) | Manufacture of stable reduction compounds of vat-dyestuffs | |
| GB294078A (en) | Manufacture of 2:3-and 2:5-dichloro-4-acetamino-1-methyl-benzene and of pure 2:3-and2:5-dichloro-4-amino-1-methylbenzene | |
| GB283822A (en) | A process for the manufacture of 2-phenylquinoline-4-carboxylic acid |