GB402106A - Improvements in processes for the de-esterification of filaments, yarns, fabrics andthe like of cellulose esters - Google Patents
Improvements in processes for the de-esterification of filaments, yarns, fabrics andthe like of cellulose estersInfo
- Publication number
- GB402106A GB402106A GB506632A GB506632A GB402106A GB 402106 A GB402106 A GB 402106A GB 506632 A GB506632 A GB 506632A GB 506632 A GB506632 A GB 506632A GB 402106 A GB402106 A GB 402106A
- Authority
- GB
- United Kingdom
- Prior art keywords
- saponification
- cellulose
- filaments
- yarns
- saponified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002678 cellulose Polymers 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 6
- 239000004744 fabric Substances 0.000 title abstract 2
- 238000005886 esterification reaction Methods 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 9
- 238000007127 saponification reaction Methods 0.000 abstract 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 4
- 239000001913 cellulose Substances 0.000 abstract 4
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 235000011941 Tilia x europaea Nutrition 0.000 abstract 3
- 239000004571 lime Substances 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 239000012752 auxiliary agent Substances 0.000 abstract 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 abstract 2
- 229920002301 cellulose acetate Polymers 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 235000011187 glycerol Nutrition 0.000 abstract 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 abstract 2
- 239000001632 sodium acetate Substances 0.000 abstract 2
- 235000017281 sodium acetate Nutrition 0.000 abstract 2
- 238000011282 treatment Methods 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 abstract 1
- 150000001447 alkali salts Chemical class 0.000 abstract 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 abstract 1
- 229910001864 baryta Inorganic materials 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000000337 buffer salt Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- -1 e.g. Substances 0.000 abstract 1
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
- 125000004185 ester group Chemical group 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 238000010409 ironing Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000002895 organic esters Chemical class 0.000 abstract 1
- 235000011056 potassium acetate Nutrition 0.000 abstract 1
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000012047 saturated solution Substances 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 239000001488 sodium phosphate Substances 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 abstract 1
- 235000019801 trisodium phosphate Nutrition 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/385—Saponification of cellulose-acetate
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Filaments, yarns, fabrics, and the like, of organic esters of cellulose, are subjected to saponification by means of a medium comprising caustic soda, caustic potash, or other alkaline compound of an alkali metal, e.g. sodium silicate or trisodium phosphate, in quantity less than that necessary to effect the desired degree of saponification, and in presence of an auxiliary agent which is not a compound of an alkali metal, and is alkaline in character though less alkaline than the saponifying agent proper, or is capable of reacting with sodium or potassium acetate or other salt formed by the saponification of the cellulose ester to re-form the saponifying agent. Examples of such auxiliary agents are lime, baryta, strontia, or the corresponding hydroxides or basic salts. Such a reagent is present as a saturated solution or in the form of a fine suspension. The saponifying agent may be applied to the goods by bath or padding treatments, by spraying or printing methods, followed by batching the goods, or passing them over heated rollers. The filaments and yarns may be saponified while they are in warp formation, using, for example, the process of Specification 313,404, [Class 2(ii), Cellulose &c.] In order to render the saponification more uniform, there may be present in the saponifying media, buffer salts, e.g., sodium chloride, sodium acetate, or soaps, or substances such as glycerine. The degree of saponification varies from 2 per cent up to substantially complete elimination of the ester groups, according to whether the object is to confer upon the materials an affinity for cotton dyestuffs, increase the safe ironing point, or to produce a reconstituted cellulose yarn. The saponification process may be applied to textile materials containing cellulose esters of high viscosity characteristics, for example, up to 200 or more in the case of cellulose acetate, measured by comparing the viscosity of a 6 per cent acetone solution against a standard of glycerine taken as 100. Furthermore, the materials may be stretched, before, during, or after saponification, with a view to obtaining products of high tenacity, for example by the process of Specification 277,089, 323,790, [both in Class 2 (ii), Cellulose &c.], 370,430, or 371,461. The stretching may take place continuously with the production of the filaments as is described in Specifications 340,324, 340,325, 340,326, 340,436, 340,437, 343,062, and 378,858. In order to improve the extention of the filaments, they may be subjected to treatment with shrinking agents as in the processes of Specifications 380,504, 380,505, and 389,823. In examples, dry-spun cellulose acetate yarns which may have been stretched to 400 to 500 per cent of their original lengths are saponified in aqueous baths containing caustic soda and lime in various concentrations. In a further example, similar yarns, are saponified in an aqueous-alcoholic bath containing caustic soda and lime. Specifications 343,063 and 402,105 also are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB506632A GB402106A (en) | 1932-02-19 | 1932-02-19 | Improvements in processes for the de-esterification of filaments, yarns, fabrics andthe like of cellulose esters |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB506632A GB402106A (en) | 1932-02-19 | 1932-02-19 | Improvements in processes for the de-esterification of filaments, yarns, fabrics andthe like of cellulose esters |
Publications (1)
Publication Number | Publication Date |
---|---|
GB402106A true GB402106A (en) | 1933-11-20 |
Family
ID=9789104
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB506632A Expired GB402106A (en) | 1932-02-19 | 1932-02-19 | Improvements in processes for the de-esterification of filaments, yarns, fabrics andthe like of cellulose esters |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB402106A (en) |
-
1932
- 1932-02-19 GB GB506632A patent/GB402106A/en not_active Expired
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