GB396053A - Improvements relating to the pickling of metals - Google Patents
Improvements relating to the pickling of metalsInfo
- Publication number
- GB396053A GB396053A GB1795/32A GB179532A GB396053A GB 396053 A GB396053 A GB 396053A GB 1795/32 A GB1795/32 A GB 1795/32A GB 179532 A GB179532 A GB 179532A GB 396053 A GB396053 A GB 396053A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphur
- acid
- bases
- pyridine
- restrainer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
- C23G1/065—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors sulfur-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
A substance for use as a restrainer in the pickling of iron or steel or as an ingredient in a material for cleaning iron or steel prior to painting, is prepared by heating with sulphur a mix whose predominating constituents are homologues of pyridine and quinoline, separately or admixed together in any proportion, but which may also contain other cyclic nitrogenous bases, such as piperidine bases or the dipiperidyls. Or such a mix may be heated with sulphur chloride to give a sulphurated product. It is preferred to use a mix commercially known as heavy pyridine bases, and consisting essentially of the higher homologues of pyridine boiling above 160 DEG C. which are extracted from tar distillates by acid treatment. When using sulphur heating may take place at temperatures of 130 DEG C. and upwards; when using sulphur chloride the more violent reaction may be modified by the presence of diluents such as benzene or paraffin hydrocarbons. In an example heavy pyridine bases boiling between 155-205 DEG C. (95 per cent between 160-205 DEG C.) are heated with sulphur at 135 DEG C. for 20-25 hours. The sulphurized product is mixed with an equal volume of sulphuric acid, impurities which separate are removed, and the liquid then blown with steam. The product so obtained may be used with or without dilution as a restrainer in a pickling bath. Casein, glue, size, sulphite cellulose lye, &c. may be p added to produce a frothing restrainer which decreases acid spray and facilitates subsequent removal of dirt from the metal. For treating iron or steel prior to painting the sulphurated base is added together with one or more organic solvents to an acid such as phosphoric acid. A composition consisting of phosphoric acid, sulphurated base, furfural and industrial spirit is specified for this purpose.ALSO:A substance for use as an ingredient in a material for cleaning iron or steel prior to painting, is prepared by heating with sulphur or sulphur chloride a mix whose predominating constituents are homologues of pyridine and quinoline, separately or admixed together in any proportion, but which may also contain other cyclic nitrogenous bases, such as piperidine bases or the dipiperidyls. It is preferred to use a mix commercially known as heavy pyridine bases, and consisting essentially of the higher homologues of pyridine boiling above 160 DEG C. which are extracted from tar distillates by acid treatment. When using sulphur heating may take place at temperatures of 130 DEG C. and upwards; when using sulphur chloride the more violent reaction may be modified by the presence of diluents such as benzene or paraffin hydrocarbons. In an example heavy pyridine bases boiling between 155-205 DEG C. (95 per cent between 160-205 DEG C.) is heated with sulphur at 135 DEG C. for 20-25 hours. The sulphurized product is mixed with an equal volume of sulphuric acid, impurities which separate are removed, and the liquid then blown with steam. The product so obtained may be used with or without dilution as a restrainer in a pickling bath. Casein, glue, size, sulphite, cellulose, lye, &c. may be added to produce a frothing restrainer which reduces acid spray and facilitates subsequent removal of dirt from the metal. For treating iron or steel prior to painting the sulphurized base is added together with one or more organic solvents to an acid such as phosphoric acid. A composition consisting of phosphoric acid, sulphurated base, furfural and industrial spirit is specified for this purpose.ALSO:A substance for use as a restrainer in the pickling of iron or steel or as an ingredient in a material for cleaning iron or steel prior to painting, is prepared by heating with sulphur a mix whose predominating constituents are homologues of pyridine and quinoline, separately or mixed together in any proportion, but which may also contain other cyclic nitrogenous bases, such as piperidine bases or the dipiperidyls. Or such a mix may be heated with sulphur chloride to give a sulphurated product. It is preferred to use a mix commercially known as heavy pyridine bases, and consisting essentially of the higher homologues of pyridine boiling above 160 DEG C. which are extracted from tar distillates by acid treatment. When using sulphur heating may take place at temperatures of 130 DEG C. and upwards; when using sulphur chloride the more violent reaction may be modified by the presence of diluents such as benzene or paraffin hydrocarbons. In an example heavy pyridine bases boiling between 155-205 DEG C. (95 per cent between 160-205 DEG C.) is heated with sulphur at 135 DEG C. for 20-25 hours. The sulphurized product is mixed with an equal volume of sulphuric acid, impurities which separate are removed, and the liquid then blown with steam. The product so obtained may be used with or without dilution as a restrainer in a pickling bath. Casein, glue, size, sulphite cellulose lye, &c. may be added to produce a frothing restrainer which decreases acid spray and facilitates subsequent removal of dirt from the metal. For treating iron or steel prior to painting the sulphurated base is added together with one or more organic solvents to an acid such as phosphoric acid. A composition consisting of phosphoric acid sulphurated base, furfural and industrial spirit is specified for this purpose.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE393824D BE393824A (en) | 1932-01-20 | ||
GB1795/32A GB396053A (en) | 1932-01-20 | 1932-01-20 | Improvements relating to the pickling of metals |
US652024A US2010562A (en) | 1932-01-20 | 1933-01-16 | Pickling restrainer and the manufacture thereof |
FR749246D FR749246A (en) | 1932-01-20 | 1933-01-19 | Improvements in pickling of iron and steel and process for the manufacture of substances intended for this and other uses |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1795/32A GB396053A (en) | 1932-01-20 | 1932-01-20 | Improvements relating to the pickling of metals |
GB3266532 | 1932-11-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB396053A true GB396053A (en) | 1933-07-20 |
Family
ID=26236990
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1795/32A Expired GB396053A (en) | 1932-01-20 | 1932-01-20 | Improvements relating to the pickling of metals |
Country Status (4)
Country | Link |
---|---|
US (1) | US2010562A (en) |
BE (1) | BE393824A (en) |
FR (1) | FR749246A (en) |
GB (1) | GB396053A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2474179A (en) * | 1947-05-02 | 1949-06-21 | Dow Chemical Co | Acid cleaning composition |
US2807585A (en) * | 1953-12-02 | 1957-09-24 | American Chem Paint Co | Inhibitor acid |
-
0
- BE BE393824D patent/BE393824A/xx unknown
-
1932
- 1932-01-20 GB GB1795/32A patent/GB396053A/en not_active Expired
-
1933
- 1933-01-16 US US652024A patent/US2010562A/en not_active Expired - Lifetime
- 1933-01-19 FR FR749246D patent/FR749246A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
US2010562A (en) | 1935-08-06 |
BE393824A (en) | |
FR749246A (en) | 1933-07-20 |
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