GB353422A - Manufacture of new vat dyes - Google Patents

Manufacture of new vat dyes

Info

Publication number
GB353422A
GB353422A GB1223330A GB1223330A GB353422A GB 353422 A GB353422 A GB 353422A GB 1223330 A GB1223330 A GB 1223330A GB 1223330 A GB1223330 A GB 1223330A GB 353422 A GB353422 A GB 353422A
Authority
GB
United Kingdom
Prior art keywords
tetrachlorthiophen
anthranol
alizarine
naphthalene
vat dyes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1223330A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB1223330A priority Critical patent/GB353422A/en
Publication of GB353422A publication Critical patent/GB353422A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B49/00Sulfur dyes
    • C09B49/12Sulfur dyes from other compounds, e.g. other heterocyclic compounds
    • C09B49/124Sulfur dyes from other compounds, e.g. other heterocyclic compounds from polycarbocyclic compounds

Abstract

Anthraquinone vat dyes, dyeing in green shades, are obtained by the interaction of a hydroxylated anthranol derived from alizarine with a tetra-halogenothiophen, either simultaneously with, or subsequent to, alkylation; in the latter case the alkylation must be partial only, so that a free hydroxyl group is present. The reaction is effected in the presence of a solvent or diluent, such as trichlorbenzene or naphthalene, and an acid-binding agent may be added if desired. The products may be halogenated to produce further vat dyes. In examples, (1) alizarine is reduced to the anthranol with zinc dust and ammonia, and the product heated with commercial trichlorbenzene, containing tetrachlorthiophen, sodium carbonate, and dimethylsulphate, (2) the anthranol obtained from alizarine is heated with tetrachlorthiophen, naphthalene, dimethylsulphate and sodium carbonate, and (3) 4-hydroxy-3-methoxyanthranol is heated with tetrachlorthiophen or tetrabromthiophen in naphthalene. The same product is obtained in all the examples, the whole of the halogen being eliminated.
GB1223330A 1930-04-17 1930-04-17 Manufacture of new vat dyes Expired GB353422A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1223330A GB353422A (en) 1930-04-17 1930-04-17 Manufacture of new vat dyes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1223330A GB353422A (en) 1930-04-17 1930-04-17 Manufacture of new vat dyes

Publications (1)

Publication Number Publication Date
GB353422A true GB353422A (en) 1931-07-17

Family

ID=10000800

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1223330A Expired GB353422A (en) 1930-04-17 1930-04-17 Manufacture of new vat dyes

Country Status (1)

Country Link
GB (1) GB353422A (en)

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