GB334872A - Improvements in and relating to the production of dyestuffs and intermediates - Google Patents
Improvements in and relating to the production of dyestuffs and intermediatesInfo
- Publication number
- GB334872A GB334872A GB720229A GB720229A GB334872A GB 334872 A GB334872 A GB 334872A GB 720229 A GB720229 A GB 720229A GB 720229 A GB720229 A GB 720229A GB 334872 A GB334872 A GB 334872A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- benzoylbenzoic
- condensed
- product
- nitro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
- C09B1/32—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups
- C09B1/325—Dyes with no other substituents than the amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
334,872. Smith, W., Willimott, S. G., Thomas, J., and Scottish Dyes, Ltd. March 5, 1929. Benzoylbenzoic acids; azines. - 2-Benzoylbenzoic acids are condensed with anthraquinones by means of an amino group in the one end and a halogen atom in the other, the amino group or halogen atom being in o-position to a nitro group. The products are converted into phenazines by treatment with reducing agents. In examples (1) 4<1>-chlor-3<1>-nitro-2-benzoylbenzoic acid is converted into its methyl ester by treating with methyl alcohol and sulphuric acid, and is then condensed with 1-aminoanthraquinone by heating in nitrobenzene in the presence of copper bronze and soda ash; the product, which is brown in colour, dyes wool or cellulose acetate silk. (2) the product of example 1 is reduced with sodium sulphide in alcohol; the product, which appears to be 2<1> - carbaxybenzoyl - anthraquinonephenazine, dyes wool in dark blue shades from an acid bath, and on further treatment with dehydrating agents yields a blue vat dye, presumably of the dianthraquinoneazine type, and (3) 4'-amino-3'-nitro-2- benzoylbenzoic acid methyl ester (prepared from the acid, methyl alcohol and sulphuric acid) is condensed with 1-chloranthraquinone in the presence of nitrobenzene, magnesium carbonate, sodium acetate and copper powder. Specification 265,545 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB720229A GB334872A (en) | 1929-03-05 | 1929-03-05 | Improvements in and relating to the production of dyestuffs and intermediates |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB720229A GB334872A (en) | 1929-03-05 | 1929-03-05 | Improvements in and relating to the production of dyestuffs and intermediates |
Publications (1)
Publication Number | Publication Date |
---|---|
GB334872A true GB334872A (en) | 1930-09-05 |
Family
ID=9828554
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB720229A Expired GB334872A (en) | 1929-03-05 | 1929-03-05 | Improvements in and relating to the production of dyestuffs and intermediates |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB334872A (en) |
-
1929
- 1929-03-05 GB GB720229A patent/GB334872A/en not_active Expired
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