GB2313076A

GB2313076A - Long nozzle with gas passages for continuous casting

Info

Publication number: GB2313076A
Application number: GB9620377A
Authority: GB
Inventors: Mitsuru Ando; Shigeaki Takahashi; Andy Elksnitis
Original assignee: AKECHI CERAMICS KK; Akechi Ceramics Co Ltd
Current assignee: AKECHI CERAMICS KK; Akechi Ceramics Co Ltd
Priority date: 1996-05-17
Filing date: 1996-09-30
Publication date: 1997-11-19
Anticipated expiration: 2016-09-30
Also published as: JP2934187B2; GB9620377D0; CA2185627C; US5885473A; JPH09308950A; GB2313076B; CA2185627A1

Abstract

A long nozzle 3 used to prevent molten steel flowing out of a collector nozzle 2 of a sliding nozzle from being oxidized by atmospheric air when molten metal, particularly molten steel, is poured from a ladle into a tundish is of such construction that (a) the long nozzle 3 made of a refractory causes molten metal to flow down from the collector nozzle (2 and the head thereof is covered by a metallic shell 16; (b) a first gas passage is provided to blow inert gas to the vicinity of a fitting portion 7 between the collector nozzle 2 and the long nozzle 3 through a first gas inlet port 8 provided on the side wall of the metallic shell 16; and (c) a second gas passage is provided to blow inert gas into an inner hole 18 of the long nozzle through a second gas inlet port 10 provided on the side wall of the metallic shell 16.

Description

LONG NOZZLE FOR CONTINUOUS CASTING The present invention relates to a long nozzle used for pouring molten metal like molten steel flowing out of a collector nozzle of a sliding nozzle for controlling flow rate, which is provided at the bottom of a ladle, for example, into a tundish for continuous casting of molten metal while preventing oxidation caused by atmospheric air when molten metal, particularly molten steel is poured from a ladle into a tundish.

To control the flow rate of molten steel flow when molten metal , particularly molten steel, is poured from a ladle into a tundish in continuous casting of steel, a sliding gate attached to the bottom of the ladle is used. FIG. 5 shows a sliding gate 200 attached to the bottom of a ladle 100.

On the lower side of this sliding nozzle 200 is disposed a so-called collector nozzle 2. A long nozzle is a very important functional member used for preventing molten steel from being oxidized by atmospheric air and for preventing molten steel from splashing when molten steel is poured from the collector nozzle 2 to a tundish (not shown).

When molten steel is poured from the ladle 100 into the tundish, molten steel flows down rapidly through a long nozzle inner hole. By the dynamic pressure of this molten steel, the pressure in the inner hole becomes negative with respect to the outside atmospheric air. By this pressure difference, atmospheric air is sucked into the long nozzle inner hole through a fitting portion between the long nozzle and the collector nozzle. The sucked air oxidizes the molten steel flowing down in the long nozzle inner hole. As a result, the quality such as cleanliness of cast steel and the yield thereof are remarkably lowered.

To solve the above problem, that is, to prevent molten metal from being oxidized by the air sucked through the fitting portion, a method in which an inert gas such as argon gas or nitrogen gas is blown to around the fitting portion or a method in which a sealing material such as a refractory plastic material is additionally used has been carried out.

FIG. shows an example of prior art which was disclosed in Japanese Patent, Laid-Open No. 1-100656 by the applicant of this invention. A porous brick 50 is disposed at a fitting portion 7 between a head of a long nozzle 3 and a collector nozzle 2, and the head is reinforced by a metallic cover 16. An inert gas is blown by passing through the porous brick 50 through an inert gas supply port 70, so that the air at the fitting portion and the upper and lower portions thereof is replaced with the inert gas, and the pressure in a long nozzle inner hole is brought from negative pressure closer to the atmospheric pressure, by which the suction of air through the fitting portion is controlled and the sealing function is enhanced.

The above conventional methods presents various problems as described below, and there is a big problem in carrying out continuous casting stably and economically.

In recent continuous casting, molten steel of 3 to 6 ladles has usually been cast continuously in one sequence cast, and further continuous-continuous casting (sequence continuous casting) of molten steel of 10 to 15 ladles has frequently been carried out.

In such continuous-continuous casting, the supply of molten steel from a first ladle to the tundish is carried out so that an allowable maximum amount of molten steel is supplied to the tundish when the remaining molten steel in this ladle decreases, the first ladle is rapidly changed to a second ladle before the lower limit of tundish capacity is reached, and the supply of molten steel to the tundish is restarted.

Specifically, when the ladle is changed, the supply of molten steel to the tundish is finished, and after a sliding gate is closed, the collector nozzle of the sliding gate is separated from the long nozzle. As long as the long nozzle is sound even if the ladle is changed, the head of the long nozzle is cleaned to remove a sealing material or splashed steel around the head, and the collector nozzle of the next ladle is fitted to this long nozzle.

Before the collector nozzle of the next ladle is fitted to the long nozzle, a worker sometimes removes the remaining steel sticking to the fitting portion of the long nozzle by using an iron bar, or cleaning is sometimes done by means of, for example, oxygen gas to dissolve and remove the metal sticking and solidifying to the lower part of the fitting portion. By such repair work, the surface of the fitting portion 7 of the long nozzle gets rough. As the change frequency of the ladle increases, this phenomenon proceeds, and finally the smoothness is lost and the sealing function in fitting the long nozzle to the collector nozzle is impaired.

Thereupon, the limit of use of tbe long nozzle itself is reached, and the quality and yield of the cast steel are lowered.

The porous brick 50, which is integrally fixed to the long nozzle by means of less permeable refractory mortar disposed at the fitting portion 7, is subjected to heat cycle of heating and cooling by the aforementioned work.

Therefore, there arise various problems in that the head of the long nozzle is destroyed by thermal stress and physical stress, the blowing mode of inert gas is disturbed, and the sealing property is greatly impaired, so that the inflow of air into the long nozzle inner hole is allowed. These problems can be avoided to some degree, for example, by increasing the blowing amount of inert gas supplied to around the fitting portion between the collector nozzle and the long nozzle through the porous brick. However, if the blowing amount of inert gas is increased too much, the inert gas blown into the long nozzle inner hole flows down directly into the tundish, resulting in rampage of molten steel.

Consequently, slag and powder, which are a protective layer for molten steel surface, are broken by violent rampage of molten steel, so that the molten steel is exposed to the atmospheric air, or a large amount of molten steel is splashed. As a result, the quality of molten steel is degraded, or a safety problem arises. These problems cannot be overcome even when the blowing amount of inert gas is controlled.

The present invention was made to solve the above problems, and has a construction described belo.w.

According to the invention there is provided a long nozzle for continuous casting, to be fitted to a collector nozzle of a sliding gate attached to the bottom of a ladle, wherein: (a) said long nozzle is made of a refractory and arranged to carry molten metal flowing down from said collector nozzle through an inner passageway thereof and the head thereof is covered by a metallic shell; (b) a first gas passage is provided to blow inert gas to the vicinity of a fitting portion of the long nozzle, between said collector nozzle and said long nozzle when fitted to the collector nozzle, from a first gas inlet port provided in the side wall of said metallic shell; and (c) a second gas passage is provided to blow inert gas into said inner passageway of said long nozzle through a second gas inlet port provided in the side wall of said metallic shell.

A first embodiment of the invention provides a long nozzle for continuous casting, in which the first gas passage comprises a gas chamber, which is provided between the metallic shell and the side wall of long nozzle head and connects to the first gas inlet port, and a slit provided between the metallic shell and the upper surface of the long nozzle head, which connects to the gas chamber.

A second embodiment of the invention provides a long nozzle for continuous casting, in which the first gas passage comprises a first gas chamber provided between the metallic shell and the side wall of the long nozzle head, which connects to the first gas inlet port, and a highly permeable porous brick capable of blowing inert gas from the gas chamber to the vicinity of the fitting portion between the long nozzle and the collector nozzle.

In either embodiment, the second gas passage may comprise a gas passage connected to the second gas inlet port provided on the side wall of long nozzle head, a second gas chamber connected to the gas passage, and a gas blowing ring provided with many small holes for blowing gas from the second gas chamber into the inner passageway of the long nozzle.

Alternatively, the second gas passage may comprise a second gas chamber connected to the second gas inlet port , and a ring-shaped porous brick for blowing gas from the second gas chamber into the inner passageway of the long nozzle.

The invention will be better understood by referring by way of example, to the accompanying drawings, in which: FIG. 1 shows a longitudinal cross section of a long nozzle, forming one embodiment of the invention; FIG. 2 shows a horizontal cross section cut along X-X plane of the invented long nozzle FIG. 3 shows a longitudinal cross section of another embodiment; FIG. 4 shows a longitudinal cross section of another embodiment; FIG. 5 is a longitudinal cross section showing a collector nozzle connected to a slide gate; and FIG. 6 is a longitudinal cross section of a conventional long nozzle according to Japanese Patent, Laid-Open No. 1-100656.

In the a long nozzle to be described, unlike in the conventional long nozzle, a first gas flow passage for supplying a large amount of inert gas to the fitting portion between a collector nozzle and the long nozzle is provided to prevent molten metal more completely from being oxidized, and a second gas flow passage for blowing a small amount of inert gas is provided to compensate a negative pressure produced in a long nozzle inner hole. This long nozzle, having such a construction, can prevent-the oxidation of molten metal more completely than the conventional long nozzle.

Embodiments of the present invention are shown in FIGS. 1 to 3. In these embodiments, the long nozzle was manufactured as follows: After a compound produced by compounding organic binder of 10% to an aggregate composed of 26 wtW of graphite, 49 wt% of alumina, and 25 wtW of silica, as a typical composition, was kneaded, and the raw material was formed by using a press, and fired at 13000C.

With reference to Figure 1, the approximate dimensions of the manufactured long nozzle are as follows: The outside diameter (d4) is 170 mm, the inside diameter (d3) is 110 mm, the head (H1 + H2) is 200 mm, and the total length is 700 mm. The outside diameter (d2) of the collector nozzle is 160 mm, and the inside diameter (dl) thereof is 95 mm.

FIG. 1 is a longitudinal sectional view of the head of the long nozzle in accordance with one embodiment of the present invention. A long nozzle 3 is connected to a collector nozzle 2 at a socket-shaped fitting portion 7. An inert gas (hereinafter referred to simply as gas) is introduced through a first gas inlet port 8 via a first gas chamber 34, and blown to the upper part of the fitting portion through a slit 32 provided between a metallic shell 16 and the upper surface of long nozzle head. The slit 32 is disposed radially at predetermined intervals on the long nozzle head surface as shown in FIG. 2, which is a sectional view taken along the line X-X of FIG. 1.

This slit 32 communicates with the gas chamber 34 formed between the side surface of long nozzle head and the metallic shell, and this gas chamber 34 communicates with the first gas inlet port 8. Therefore, the gas introduced by pressure through the first gas inlet port 8 is sufficiently blown to the upper side of the fitting portion 7 between the collector nozzle and the long nozzle, so that the atmospheric air absorbed into an inner passageway 18 through the fitting portion is shut off, by which the oxidation of molten steel flowing down in the inner passageway can be prevented.

The gas blown through the slit 32 seals the whole of the collector nozzle and the sliding gate, which prevents the absorption of atmospheric air caused by a negative pressure produced by the flowing-down of molten metal from a ladle nozzle to the collector nozzle.

As described above, the long nozzle in accordance with the present invention is provided with the first gas passage consisting of the first gas chamber 34 provided between the metallic shell 16 and the side wall of long nozzle head, which connects to the first gas inlet port 8, and the slit 32 provided between the metallic shell 16 and the long nozzle head, which connects to the gas chamber 34. Therefore, since the resistance to the flow of gas is small, a large amount of gas, for example, 100 to 500 1/mien of gas can be blown to the fitting portion between the long nozzle and the collector nozzle, so that the absorption of atmospheric air into the nozzle inner passageway through the fitting portion can be prevented.

In the present invention, a second gas passage is further provided. This gas passage comprises, for example, a gas inlet passage 42 provided in a refractory of long nozzle, which is connected to a second gas inlet port 10 provided on the side wall of long nozzle head, a second gas chamber 44 connected to the gas inlet passage 42, and agas blowing ring 45 made of a refractory, which is provided with many small holes of about 1 mm in diameter for blowing the gas from the second gas chamber 44 into the inner hole of long nozzle. This gas blowing ring 45 may be manufactured independently and then pushed in the long nozzle, or it may be manufactured integrally when the long nozzle body is manufactured.

The second gas passage is a passage for the gas blown to compensate the negative pressure produced by the molten metal flowing down in the long nozzle inner passageway. Therefore, the second gas passage may be a passage sufficient to introduce a relatively small amount of gas unlike the first gas inlet port 8.

The flow rate of gas passing through this passage is about 3 to 30 1/mien. The portion between the first gas inlet port 8 and the second gas inlet port 10 is made airtight by means of mortar 14.

FIG. 3 shows another embodiment. In this embodiment, both of the first and second gas passages are formed by porous bricks 60 and 47, respectively. However, the porous brick 60 forming the first gas passage has a higher permeability than the porous brick forming the second gas passage so that about tenfold gas can be blown. The porous brick 47 is made of, for example, 70 wtW alumina and balance silica.

FIG. 4 shows another embodiment. In this embodiment, the first gas passage has the slit 32 like the above-described embodiment shown in FIG. 1, while the second gas passage is formed by the porous brick 47. As described above, for the specific configuration of the first and second gas passages, various combinations are possible.

In the above embodiments, in the first and second gas passages, the supplied gas has a pressure of about 1 kg/cm2G (gauge pressure). However, since the resistances of gas passages differ, the flow rate of gas is different as described above.

The desirable inert gases are nitrogen gas, Ar gas, etc., and Ar gas is preferable when the amount of nitrogen in steel presents a problem.

Examples Continuous casting of low carbon aluminum killed steel (C:0.05 wtk , Mn: 0.45 wtk , P: not more than 0.01 wtW ,S: not more than 0.01 wt% , Al:0.03-0.06 wtW , N:0.003-0.006 wt% ) being used for automotive cold rolled steel sheets was carried out many times by using the above-described long nozzle. The results are given in Tables 1 and 2.

Table 1 gives the service life of long nozzles in the case where continuous-continuous casting was performed using the conventional long nozzle (FIG. 6) and a long nozzle in accordance with Fig. 1. The service life of the conventional long nozzle was 6 heats (where a "heat" is a charge of molten metal in the ladle) on the average, while that of the long nozzle in accordance with the present invention was 9 heats on the average.

Here, the service life means the number of heats in which the fitting between the collector nozzle and the long nozzle is acceptable.

Also, the amounts of atmospheric air absorbed in the casting of aforementioned low carbon aluminum killed steel were compared by carrying out continuous casting of 20 heats using the conventional long nozzle and the long nozzle in accordance with Fig. 1. The results are given in Table 2. Table 2 gives the changes in amounts of nitrogen (N) and Al, which are compositions of steel, and the change in amount of oxygen in steel between the ladle and the tundish.

The increased amount of nitrogen, the decreased amount of Al, and the increase in amount of oxygen in steel are proportional to the amount of absorbed air between the ladle and the tundish. The results given in Table 2 show that the use of the long nozzle in accordance with Fig. 1 significantly decreased the absorption of atmospheric air. Needless to say, the increase in amount of nitrogen increases the hardness of steel. Also, the decrease in amount of Al reduces the aging property, and the increase in amount of oxygen in steel deteriorates the cleanliness of steel. Particularly for tinned steel sheets for deep drawing, the highest possible cleanliness of steel is necessary. Therefore, the present invention as exemplified by the disclosed embodiments provides a yital technology for continuous casting of the tinned steel sheets etc.

Table 1

Service life of long nozzle in continuous-continuous casting (number of heats) Conventional 6 heats on the average nozzle Nozzle of this 9 heats on the average invention Table 2 N = 20 heats

Item Conventional Nozzle of this nozzle invention Increased amount 8 + 2 1 + 0.5 of nitrogen (ppm) Decreased amount 0.007 + 0.003* 0.003 + 0.001* of Al (wt%) Increased amount 10 + 3* 5 + 1* of oxygen in steel (ppm) (Note) (*): 3 x standard deviation Average composition of low carbon aluminum killed steel C: 0.05 wtA, Mn: 0.32 wt% Al: 0.035 wtW, P,S < 0.015 wtW In the conventional long nozzle, inert gas is blown from one place of the long nozzle. In the present invention, inert gas blowing passages are provided independently at the upper and lower parts of the fitting portion between the ladle collector nozzle and the long nozzle. Thereby,. the independent blowing flow rate of inert gas can be set arbitrarily. Therefore, a quite stable sealing property can be kept from the start of continuous casting to the end thereof despite the roughness produced on the surface of the fitting portion, so that the quality of cast steel can be upgraded significantly.

In the conventional long nozzle, the flow rate of inert gas cannot be regulated in response to the surface roughness of fitting portiqn. Therefore, when the surface roughness proceeds to some degree, the long nozzle being used must be thrown away. In the present invention, the flow rate of inert gas can be regulated independently at the upper and lower parts of the fitting portion, so that a sufficient sealing effect can be achieved even if the surface roughness of fitting portion occurs. Therefore, the service life of the long nozzle can be increased.

Claims

CLAIMS:

1. A long nozzle for continuous casting, to be fitted to a collector nozzle of a sliding gate attached to the bottom of a ladle, wherein: (a) said long nozzle is made of a refractory and arranged to carry molten metal flowing down from said collector nozzle through an inner passageway thereof and the head thereof is covered by a metallic shell; (b) a first gas passage is provided to blow inert gas to the vicinity of a fitting portion of the long nozzle, between said collector nozzle and said long nozzle when fitted to the collector nozzle, from a first gas inlet port provided in the side wall of said metallic shell; and (c) a second gas passage is provided to blow inert gas into said inner passageway of said long nozzle through a second gas inlet port provided in the side wall of said metallic shell.

2. A long nozzle for continuous casting according to claim 1, wherein said first gas passage comprises a first gas chamber, which is provided between said metallic shell and the side wall of the long nozzle head and connects to said first gas inlet port, and a slit provided between said metallic shell and the upper surface of the long nozzle head, which connects to said gas chamber.

3. A long nozzle for continuous casting according to claim 1, wherein said first gas passage comprises a first gas chamber, which is provided between said metallic shell and the side wall of long nozzle head and connects to said first gas inlet port, and a highly permeable porous brick capable of blowing inert gas from said gas chamber to the vicinity of said fitting portion between said long nozzle and said collector nozzle when said long nozzle is fitted to said collector nozzle.

4. A long nozzle for continuous casting according to any preceding claim, wherein said second gas passage comprises a gas passage connected to said second gas inlet port, a second gas chamber connected to said second gas passage, and a gas blowing ring provided with small holes for blowing gas from said second gas chamber into said inner passageway of said long nozzle.

5. A long nozzle for continuous casting according to claim 1 or 2, wherein said second gas passage comprises a second gas chamber which is provided between said metallic shell and the side wall of the long nozzle head and connects to said second gas inlet port, and a ring-shaped porous brick for blowing gas from said second gas chamber into said inner passageway of said long nozzle.

6. A long nozzle according to any preceding claim and fitted to a collector nozzle of a sliding gate attached to the bottom of a ladle.

7. A long nozzle substantially as hereinbefore described with reference to Figure 1 and 2, 3 or 4 of the accompanying drawings.

7. A long nozzle according to claim 6, wherein the arrangement is such that, in operation, the gas flow rate through the first gas passage is larger than that through the second gas passage.

8. A long nozzle substantially as hereinbefore described with reference to Figures 1 and 2, 3 or 4 of the accompanying drawings.

9. A long nozzle for continuous casting, to be fitted to a collector nozzle of a sliding gate attached to the bottom of a ladle, wherein: (a) said long nozzle is made of a refractory and arranged to carry molten metal flowing down from said collector nozzle through an inner passageway thereof; (b) a first gas passage is provided to blow inert gas to the vicinity of a fitting portion of the long nozzle, between said collector nozzle and said long nozzle when fitted to the collector nozzle, from a first gas inlet port provided in the head of the long nozzle; and (c) a second gas passage is provided to blow inert gas into said inner passageway of said long nozzle through a second gas inlet port provided in the head of the long nozzle.

Amendments to the claims have been filed as follows CLAIMS: 1. A long nozzle for continuous casting, to be fitted to a collector nozzle of a sliding gate attached to the bottom of a ladle, wherein: (a) said long nozzle is made of a refractory and arranged to carry molten metal flowing down from said collector nozzle through an inner passageway thereof and the head thereof is covered by a metallic shell; (b) a first gas passage is provided to blow inert gas to the vicinity of a fitting portion of the long nozzle, between said collector nozzle and said long nozzle when fitted to the collector nozzle from a first gas inlet port, the first gas passage comprising a gas chamber, provided between said metallic shell and the side wall of the long nozzle head and connected to said first gas inlet port, and a slit provided between said metallic shell and the upper surface of long nozzle head, which connects to said gas chamber; and (c) a second gas passage is provided to blow inert gas into said passageway of said long nozzle through a second gas inlet port provided on the side wall of said metallic shell.

2. A long nozzle for continuous casting according to claim 1, wherein said first gas passage comprises, in addition to said first gas chamber, a highly permeable porous brick capable of blowing inert gas from said gas chamber to the vicinity of said fitting portion between said long nozzle and said collector nozzle when said long nozzle is fitted to said collector nozzle.

3. A long nozzle for continuous casting according to claim 1 or 2, wherein said second gas passage comprises a gas passage connected to said second gas inlet port, a second gas chamber connected to said second gas passage, and a gas blowing ring provided with small holes for blowing gas from said second gas chamber into said inner passageway of said long nozzle.

4. A long nozzle for continuous casting according to claim 1 or 2, wherein said second gas passage comprises a second gas chamber which is provided between said metallic shell and the side wall of the long nozzle head and connects to said second gas inlet port, and a ring-shaped porous brick for blowing gas from said second gas chamber into said inner passageway of said long nozzle.

5. A long nozzle for continuous casting according to any preceding claim, wherein said nozzle is fitted to a collector nozzle of a sliding gate attached to the bottom of a ladle.

6. A long nozzle for continuous casting according to claim 5, wherein the arrangement is such that, in operation, the gas flow rate through the first gas passage is larger than that through the second passage.