GB2303693A - Gas treatment with liquid spray - Google Patents

Gas treatment with liquid spray Download PDF

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Publication number
GB2303693A
GB2303693A GB9515388A GB9515388A GB2303693A GB 2303693 A GB2303693 A GB 2303693A GB 9515388 A GB9515388 A GB 9515388A GB 9515388 A GB9515388 A GB 9515388A GB 2303693 A GB2303693 A GB 2303693A
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GB
United Kingdom
Prior art keywords
gas
chamber
water
outlet
inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB9515388A
Other versions
GB9515388D0 (en
Inventor
Maurice Edward George Maton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to GB9515388A priority Critical patent/GB2303693A/en
Publication of GB9515388D0 publication Critical patent/GB9515388D0/en
Priority to AU66209/96A priority patent/AU6620996A/en
Priority to PCT/GB1996/001791 priority patent/WO1997004854A1/en
Publication of GB2303693A publication Critical patent/GB2303693A/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28CHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
    • F28C3/00Other direct-contact heat-exchange apparatus
    • F28C3/06Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

Gas treatment apparatus comprises a generally cylindrical chamber 1 through which the gas is caused to flow. The chamber 1 has a gas inlet pipe 2 projecting into the chamber from which the gas flows towards a gas outlet 3. A pair of water pipes 4 conduct water coolant to opposite sides of the chamber 1 where it is sprayed into the gas flow through nozzles 5 directed at least partially towards the gas outlet 3. The water cools the gas, condenses hydrocarbon impurities such as tars and oils, and collects solid particles from the gas. A mixture of the water, hydrocarbon condensate and solid particles falls to the bottom of the chamber 1 and down to a drain 6 at the outlet end 3' of the chamber. Each nozzle 5 produces a spray in the form of a thin, curtain-like water film which extends to the opposite side of the chamber.

Description

GAS TREATMENT APPARATUS This invention relates to gas treatment apparatus. One application of the invention is for cooling gas and for removing solid particles and other impurities therefrom.
An example of another application of the invention uses a stream of hot gas for heating water.
In many cases the gas under treatment will be air.
According to a first aspect of the invention, gas treatment apparatus comprises a chamber through which gas is caused to flow between an inlet and outlet thereof, and nozzle means for introducing liquid into the chamber for treating the gas, the nozzle means being adapted to produce a plurality of sprays in the form of sheets of the liquid.
Preferably each sheet comprises a thin, curtain-like film forming an obstacle in the path of the gas. The films may be distorted by the gas flow when this is introduced into the chamber.
The nozzle means conveniently comprises a plurality of spray nozzles, each nozzle producing a said spray.
The spray nozzles are preferably disposed In arrays on opposite sides of the chamber, and most preferably, on passing along the chamber from the inlet to the outlet the gas encounters a series of sprays coming alternately from opposite sides of the chamber.
An outlet from the chamber for the gas is conveniently provided in an upper side wall portion of one end of the chamber, an outlet from the chamber for liquid from the nozzles being conveniently provided in a lower side wall portion, preferably at the same end of the chamber.
Forms of gas treatment apparatus are known in which a stream of gas is introduced into one end of a chamber, and water for treating the gas is sprayed downwardly into the stream of gas from spray nozzles mounted near the upper wall of the chamber, the treated gas then being taken off from the other end of the chamber, and the water from the nozzles being collected from the bottom of the chamber.
However, the form of the sprays disclosed in connection with the first aspect of the invention, as well as the preferred arrangements of the sprays, conveniently provides a high level of exposure of the gas to the liquid being used for treating the gas, enabling a compact and efficient form of gas treatment apparatus to be constructed.
The invention may be used purely for removing impurities from a gas including, for example, solid particles and condensible substances which are trapped by the liquid sprays. Additionally, or alternatively, the invention may use the liquid to change the temperature of the gas.
Where the invention is applied for heating water, the water is the liquid introduced into the chamber, and this is heated by the gas being hot gas. A convenient supply of hot gas is exhaust gas from suitable fuel burning apparatus.
In attempting to use existing forms of commercial apparatus for cooling gas rapidly from temperatures above about 500 -800 C to near room temperature using water sprays, it has been found that the rapid cooling can result in shock waves which cause an undesirable, pulsating flow of gas.
The applicants have realised that a steady suction effect can be obtained by angling the spray nozzles slightly towards the gas outlet from the chamber, so reducing any tendency to produce shock waves.
According to a second aspect of the invention, gas treatment apparatus comprises a chamber through which gas is caused to flow between an inlet and outlet thereof, and nozzle means for introducing liquid into the chamber for treating the gas, the nozzle means being directed at least partially towards said outlet so as to be angled at less than 90" to the general direction of gas flow between said inlet and said outlet.
In a preferred form of gas treatment apparatus according to the second aspect of the invention, the nozzle means is also adapted to produce a plurality of sprays in the form of sheets of the liquid, in accordance with the first aspect of the invention.
Preferably sald sprays in the form of sheets of the liquid are directed by the nozzles at an angle of substantially 45" to 850 to the longitudinal axis of the chamber. The angle is most preferably substantially 80".
The spray nozzles are desirably disposed in arrays on opposite sides of the chamber such that, on passing along the chamber from the inlet to the outlet, the gas encounters a series of sprays coming alternately from opposite sides of the chamber. Conveniently the angling and spacing of each of the nozzles is such that each spray in the series is directed at the base of the next spray In the series so that, at least prior to introduction of the gas flow into the chamber, the sprays do not intersect.
Where the invention is used with pyrolysis apparatus for cooling the gas produced by the pyrolysis apparatus and for removing condensate and solid particles from the gas, hydrocarbon condensate is desirably returned to the pyrolysis apparatus for further pyrolysls treatment.
Where the gas carries solid or condensible material, as in the case of use with pyrolysis apparatus, the inlet to the gas treatment apparatus may desirably be provided with scraping means for removing any material deposited in the inlet.
However, the inlet most preferably comprises a pipe projecting into at least the first spray of a series of the liquid sprays since this has been found to reduce any tendency for the inlet to foul with the material carried by the gas.
The chamber of the apparatus of the invention is preferably of elongate form, with the inlet for the gas located towards one end of the chamber, and the outlet for the gas towards the other end of the chamber. The chamber is conveniently of cylindrical form, and the inlet end is preferably higher than the outlet end.
For this reason, the longitudinal axis of the chamber is typically inclined, the angle of inclination preferably being substantially 50 to 15 to the horizontal, but most preferably substantially 10 to the horizontal.
By way of example only, a specific embodiment of the apparatus of the invention will now be described with reference to the accompanying drawings, in which: Figure l is a diagrammatic side view of the apparatus, Figure 2 is a diagrammatic section view along on section line 2-2 of Figure 1, Figure 3 is a diagrammatic end view of the apparatus, viewed from the lower end of the chamber, and Figure 4 is a diagrammatic cross-section view on section line 4-4 of Figure 1, showing the spray configuration.
The applicants international patent application No. PCTIGB 93/01213 (WO 93/25848) describes apparatus for pyrolysis of waste materials such as domestic rubbish, which produces a stream of hot, combustible gas bearing solid particles such as particles of carbon, and oils, tars and other impurities.
The specific embodiment is a gas cooling apparatus using water sprays for cooling gas produced from such pyrolysis apparatus from around 500"-800"C to about 25"C and for condensing and removing liquid substances from the gas together with solid particles and various other impurities.
As shown in the accompanying drawings, gas-cooling apparatus according to the invention comprises a generally cylindrical chamber 1 through which the gas is caused to flow. The chamber 1 has an inlet for the gas which comprises an inlet pipe 2 projecting into the chamber (Figures 1 and 2) from which the gas flows towards an outlet 3 for the gas at outlet end 3 of the chamber 1. A partition 20 forms one end wall of chamber 1, whilst the opposite end wall is indicated by reference 30. The chamber 1 is supported by a leg 11.
A pair of water pipes 4 conduct water coolant to opposite sides of the chamber 1 where it is sprayed into the gas flow through nozzles 5 directed at least partially towards the gas outlet 3. The water not only cools the gas, but also condenses hydrocarbon impurities such as tars and oils, and collects solid particles from the gas A mixture of the water, hydrocarbon condensate and solid particles therefore falls to the bottom side of the chamber 1 and then, due to the axis 7 of the chamber being inclined to the horizontal at about 10 , the mixture flows down to a drain 6 at the outlet end 3 of the chamber, from which it leaves the chamber.
The hydrocarbon condensate may then be separated from the mixture and returned to the pyrolysis apparatus, for further pyrolysis treatment.
Due to the nozzle shape, each nozzle 5 produces a spray in the form of a thin, curtain-like water film which extends to the opposite side of the chamber. The films are not directed perpendicularly to the cylinder axis, but are angled slightly towards the outlet end 3 of the chamber, so as to intersect the axis 7 at about 80".
As viewed in Figure 3, dotted line 8 delimits the rear of a water film coming from a nozzle 5 on the left hand side of the chamber l, whereas dotted line 9 delimits the rear of a water film coming from a nozzle 5 on the right hand side of the chamber 1.
The angle and spacing of the nozzles is such that the film produced by each nozzle impinges near the base of the next nozzle in the series on the opposite side, at least prior to introduction of the gas flow into the chamber. The chamber is thus partitioned by a series of water films passing in a zig-zag formation from the gas inlet 2 to the gas outlet 3.
Although the films are disrupted by the flow of gas, the angled configuration of the films gives a steady suction effect as the gas is cooled and promotes flow of the gas from inlet pipe 2 to outlet 3 without pulsating.
The inlet is in the form of a pipe 2, the end of which projects into the first of the series of sprays, since this arrangement has been found to reduce any tendency for the inlet to foul with impurities carried by the gas. An automatic scraping device (not shown) can also be provided to remove any impurities deposited at the inlet.
A demister in the form of a mesh may cover the gas outlet 3 to remove spray and other remaining particles from the gas.
In a preferred embodiment, there is a series of 12 nozzles on each side of the chamber, although in the drawings only six are shown on each side. Suitable nozzles have been found to be gas burner fan nozzles produced by Bray Burners of Education Road, Leeds. The nozzles have part number 23A1906 and part reference CAT 4277.

Claims (7)

1. Gas treatment apparatus comprising a chamber through which gas is caused to flow between an inlet and outlet thereof, and nozzle means for introducing liquid into the chamber for treating the gas, the nozzle means being adapted to produce a plurality of sprays In the form of sheets of the liquid.
2. Apparatus as claimed in claim 1, in which the nozzle means ls directed at least partially towards said outlet so as to be angled at less than 90" to the general direction of gas flow between said inlet and said outlet.
3. Apparatus as claimed in claim 1 or claim 2, in which the nozzle means comprises a plurality of spray nozzles, the chamber having a longitudinal axis, and the spray nozzles directing the sprays at an angle of substantially 45" to 85" to said axis.
4. Apparatus as claimed in claim 3, in which the spray nozzles are disposed in arrays on opposite sides of the chamber, and most preferably, on passing along the chamber from the inlet to the outlet the gas encounters a series of said sprays coming alternately from opposite sides of the chamber.
5. Apparatus as claimed in claim 4, in which the inlet comprises a pipe projecting into at least the first spray of the series of said sprays.
6. Apparatus as claimed in any one of the preceding claims for use in heating water, the water being the liquid introduced into the chamber, and heating of the water resulting from the temperature of the gas being higher than that of the water.
7. Gas treatment apparatus substantially as hereinbefore described with reference to the accompanying drawings.
GB9515388A 1995-07-27 1995-07-27 Gas treatment with liquid spray Withdrawn GB2303693A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB9515388A GB2303693A (en) 1995-07-27 1995-07-27 Gas treatment with liquid spray
AU66209/96A AU6620996A (en) 1995-07-27 1996-07-25 Gas treatment apparatus
PCT/GB1996/001791 WO1997004854A1 (en) 1995-07-27 1996-07-25 Gas treatment apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9515388A GB2303693A (en) 1995-07-27 1995-07-27 Gas treatment with liquid spray

Publications (2)

Publication Number Publication Date
GB9515388D0 GB9515388D0 (en) 1995-09-27
GB2303693A true GB2303693A (en) 1997-02-26

Family

ID=10778331

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9515388A Withdrawn GB2303693A (en) 1995-07-27 1995-07-27 Gas treatment with liquid spray

Country Status (3)

Country Link
AU (1) AU6620996A (en)
GB (1) GB2303693A (en)
WO (1) WO1997004854A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6648932B1 (en) * 1998-06-16 2003-11-18 Graveson Energy Management Ltd. Gasification reactor apparatus
FR2861318A1 (en) * 2003-10-23 2005-04-29 Air Liquide Method of continuously cooling and purifying gas, for use in food industry, involves transferring material and heat in counter-flow with cooling and washing water in transfer units
FR2884731A1 (en) * 2005-04-20 2006-10-27 Air Liquide Process for purifying and cooling carbon dioxide, comprises transferring heat between humid gas flux and washing water flux, and circulating cooled water-, purified gas- and condensed flux
FR3069459A1 (en) * 2017-07-27 2019-02-01 Lab Sa PROCESS AND INSTALLATION FOR WET PURIFICATION OF EXHAUST FUMES FROM AN ENGINE OF A SEA VESSEL
WO2021068674A1 (en) * 2019-10-12 2021-04-15 万华化学集团股份有限公司 Apparatus and method for rapid cooling of high temperature gas

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110170219A (en) * 2019-05-31 2019-08-27 中国一冶集团有限公司 A kind of building waste channel automatic dustfall device
CN112316571B (en) * 2020-09-10 2022-03-15 江苏吉能达环境能源科技有限公司 Dust remover with blowback device for cement production

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB165451A (en) * 1920-06-28 1922-09-27 Rudolf Adler Improvements in or relating to the absorption and purification of gases and vapours
GB1283510A (en) * 1970-04-02 1972-07-26 Pechiney Saint Gobain Apparatus and method for cooling hot gases
GB1344641A (en) * 1970-02-02 1974-01-23 Lummus Co Quenching of hot fluids
US3847714A (en) * 1972-06-15 1974-11-12 Dasi Industries Method and apparatus for heat treating liqueform materials
GB1546180A (en) * 1975-05-30 1979-05-16 Tecnochim Srl Method and apparatus for the cooling and the washing of gases
GB2262895A (en) * 1991-12-31 1993-07-07 Huang Min Su Waste gas washing apparatus

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US3668839A (en) * 1971-05-28 1972-06-13 Combustion Control Devices Air pollution controller
GB1357783A (en) * 1971-07-23 1974-06-26 Carrier Drysys Ltd Method of and apparatus for treating a gas with a liquid
US4127621A (en) * 1977-08-04 1978-11-28 American Air Filter Company, Inc. Quenching device
US4508555A (en) * 1982-04-08 1985-04-02 Isover Saint-Gobain Method and apparatus for scrubbing effluent gases from mineral fiber production
US4810268A (en) * 1985-11-07 1989-03-07 Ppg Industries, Inc. Apparatus and method of washing air
DE3715263A1 (en) * 1987-05-08 1988-11-17 Zabel Kg Kunststoffverarbeitun Process and apparatus for purifying exhaust air
US5154734A (en) * 1991-07-12 1992-10-13 Calvert Environmental, Inc. Pollution control system and method of using same
US5308385A (en) * 1992-06-10 1994-05-03 Dennis Winn Pollution abatement apparatus and method
FR2693124A1 (en) * 1992-07-02 1994-01-07 Wackermann Guy Device for washing air or similar gas for conditioning or ventilation - using a series of convex-concave baffles streaming with washing solution and a curtain of washing solution jetted down under pressure
GB9326430D0 (en) * 1993-12-24 1994-02-23 Colt Int Licensing Gas scrubber

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB165451A (en) * 1920-06-28 1922-09-27 Rudolf Adler Improvements in or relating to the absorption and purification of gases and vapours
GB1344641A (en) * 1970-02-02 1974-01-23 Lummus Co Quenching of hot fluids
GB1283510A (en) * 1970-04-02 1972-07-26 Pechiney Saint Gobain Apparatus and method for cooling hot gases
US3847714A (en) * 1972-06-15 1974-11-12 Dasi Industries Method and apparatus for heat treating liqueform materials
GB1546180A (en) * 1975-05-30 1979-05-16 Tecnochim Srl Method and apparatus for the cooling and the washing of gases
GB2262895A (en) * 1991-12-31 1993-07-07 Huang Min Su Waste gas washing apparatus

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6648932B1 (en) * 1998-06-16 2003-11-18 Graveson Energy Management Ltd. Gasification reactor apparatus
FR2861318A1 (en) * 2003-10-23 2005-04-29 Air Liquide Method of continuously cooling and purifying gas, for use in food industry, involves transferring material and heat in counter-flow with cooling and washing water in transfer units
WO2005039740A2 (en) * 2003-10-23 2005-05-06 L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for scrubbing and cooling a gas by direct contact with water and installation for carrying out said method
WO2005039740A3 (en) * 2003-10-23 2009-03-12 Air Liquide Method for scrubbing and cooling a gas by direct contact with water and installation for carrying out said method
FR2884731A1 (en) * 2005-04-20 2006-10-27 Air Liquide Process for purifying and cooling carbon dioxide, comprises transferring heat between humid gas flux and washing water flux, and circulating cooled water-, purified gas- and condensed flux
FR3069459A1 (en) * 2017-07-27 2019-02-01 Lab Sa PROCESS AND INSTALLATION FOR WET PURIFICATION OF EXHAUST FUMES FROM AN ENGINE OF A SEA VESSEL
WO2021068674A1 (en) * 2019-10-12 2021-04-15 万华化学集团股份有限公司 Apparatus and method for rapid cooling of high temperature gas

Also Published As

Publication number Publication date
GB9515388D0 (en) 1995-09-27
WO1997004854A1 (en) 1997-02-13
AU6620996A (en) 1997-02-26

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