GB2227021A - Phosphate-and silicate-free cleaning compositions - Google Patents
Phosphate-and silicate-free cleaning compositions Download PDFInfo
- Publication number
- GB2227021A GB2227021A GB9000224A GB9000224A GB2227021A GB 2227021 A GB2227021 A GB 2227021A GB 9000224 A GB9000224 A GB 9000224A GB 9000224 A GB9000224 A GB 9000224A GB 2227021 A GB2227021 A GB 2227021A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- composition according
- polycarboxylate
- alkali
- phosphonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 42
- 238000004140 cleaning Methods 0.000 title description 2
- 239000003513 alkali Substances 0.000 claims description 15
- 229920005646 polycarboxylate Polymers 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- -1 aminomethylene phosphonic acid Chemical compound 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000005260 corrosion Methods 0.000 claims description 6
- 230000007797 corrosion Effects 0.000 claims description 6
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 239000003352 sequestering agent Substances 0.000 claims description 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 4
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 4
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 4
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 4
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 150000003009 phosphonic acids Chemical class 0.000 claims 1
- 238000005406 washing Methods 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 229920002125 Sokalan® Polymers 0.000 description 6
- 239000004584 polyacrylic acid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 5
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- NYYLZXREFNYPKB-UHFFFAOYSA-N 1-[ethoxy(methyl)phosphoryl]oxyethane Chemical compound CCOP(C)(=O)OCC NYYLZXREFNYPKB-UHFFFAOYSA-N 0.000 description 2
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical group 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- DXMISFVOLRPPNP-UHFFFAOYSA-M sodium;nitrite;hydrate Chemical compound O.[Na+].[O-]N=O DXMISFVOLRPPNP-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/36—Organic compounds containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Description
9 i 1 1 A 1 j- PHOSPHATE- AND SILICATE-FREE LAUNDRY DETERGENT COMPOSITIONS
The invention relates to phosphate and silicate free aqueous washing compositions that contain alkali and a combination of a polycarboxylate and a phosphonate.
It is desirable to avoid having washing compositions containing phosphates and/or silicates. Phosphates are well known to be ecologically undesirable and indeed in certain countries are no longer permitted. Silicates have the disadvantage that they tend to form deposits in the particular washing machine in which they are used.
According to the invention there is provided a phosphate and silicate free aqueous washing composition comprising (i) 5-45% of alkali, (ii) 0.5-20% of polycarboxylate and (iii) 0.1-107. of phosphonate, the balance comprising water.
When preparing compositions according to the invention, the polycarboxylate and/ or the phosphonate can be formed in situ by adding the corresponding free acid which on contact with the alkali forms the salt or by adding the salt form per se.
All percentages given in the compositions according to the invention are by weight of the active compound or material and relate to the total composition.
Further, compositions according to the invention may contain further additives for example other sequestering agents and/or corrosion inhibitors.
Preferably in compositions according to the invention, the ratio Case 150-5302 of polycarboxylate to phosphonate is 1:1 to 30:1, more preferably 1.5:1 to 12:1.
Compositions according to the invention may be used as alkali donors in industrial washing processes. Preferably such a composition according to the invention comprises (i) 15-35%, more preferably 18-30% of alkali, (ii) 3-10%, more preferably 4-7% of polycarboxylate and (iii) 0.2-1.5%, more preferably 0.5-1.2% of phosphonate, the balance being water and one or more compounds selected from sequestering agents and corrosion inhibitors.
Compositions according to the invention may also be used as washing liquids for use in a dish washer. Such compositions must be free of any chlorine containing compounds. Preferably such a composition according to the invention comprises:
(i) 10-35%, more preferably 13-20% of alkali, (ii) 0.5-15%, more preferably 0.5-10.5% of polycarboxylate and (M) 0.2-5%, more preferably 0. 4-3% of phosphonate, the balance comprising water.
The pH of these compositions is preferably over 10.
Preferred alkali used in the aqueous compositions according to the invention are alkali metal -hydroxide or -carbonate, more preferably sodium or potassium hydroxide or carbonate. The alkali can be used in solid form or as a very strongly concentrated aqueous solution.
Preferably in a composition according to the invention the polycarboxylate is one that is preferably derived from medium to high molecular weight polymers (preferably having a molecular weight of 800 1 4 b c - 3 - Case 150-5302 to 500,000, more preferably 1,000-250,000, especially 4,000-120,000); more preferably it is derived from one of the following acids:
methacrylic acid, acrylic acid, a-hydroxyacrylic acid, maleic acid or copolymers thereof.
Such polycarboxylic acids are in aqueous solution. Preferably the polycarboxylic acid is in the form of an alkali metal salt, preferably sodium or potassium salts. Preferably the polymer is a polyaerylate polymer.
Preferred phosphonates are those derived from hydroxy Cl-4alkylene phosphonic acid or aminomethylene phosphonic acid or phosphonic Cl4alkylene carboxylic acid. More preferably the phosphonic acid is one derived from:
1-hydroxyethane-l,l-disphosphonic acid (HEDP), aminotri(methylenephosphonic acid) (ATMP), ethylene diamine tetra(methylene phosphonic acid) (EDTMP), Diethylene triamine penta(methylene phosphonic acid) (DETPMP), hexamethylene diamine tetra(methylene phosphonic acid), amine oxide tri(methylene phosphonic acid) and 2-phosphono butane -1,2,4-tricarboxylic acid (PBTC).
Preferably compositions according to the invention contain one or more sequestering agents selected from salts of nitrilotriacetic acid and citric acid. Preferably the amount of sequester ing agent used is from 320%, based on the weight of the composition Preferred salt forms are those derived from the alkali metals, e.g. sodium and potassium.
Where a composition according to the invention is to be used as dish washing machine liquid (and therefore does not contain any chlorine containing compounds), then it optionally includes one or more corrosion inhibitors. Preferred corrosion inhibitors are selected 4 a from sodium nitrite, benzotriazoles or tolyltriazoles. Preferably when a corrosion inhibitor is present it is preferably present in an amount selected from 0.5-1% of sodium nitrite and 0.2-0.4 of benzotriazole or tolyltriazole.
Compositions according to the invention when used as dish washing machine liquids (i.e. without the chlorine containing compounds) have extremely good wash and cleaning properties and also do not have the abovementioned disadvantages associated with phosphate and silicate containing washing liquids.
Compositions according to the invention when used as alkali donors in industrial washing liquids produce stable, strong alkali concentrates, which through the addition of anionic or nonionic surface active agents make up useful industrial washing liquids.
a D The invention will now be illustrated by the following examples in which all amounts are given in percent by weight of the composition.
Polyacrylic acid A has a molecular weight of 100,000 and is used as 29% solution of the half neutralised acid (sodium salt form), polyacrylic acid B has a molecular weight of 4,500 and is used as 49X solution, the sodium salt of nitrilo triacetic acid (NTA) is used as 40% solution, the diethylenetriamine penta(methylene phosphonic acid) (DETPMP) is used as 50% solution and the 1-hydroxyethane-l,l-diphosphonic acid (HEDP) is used as 60% solution, all solutions being in water.
Examples 1-8:
The following compositions were made up as follows:
Table 1
1 2 3 4 6 7 8 Demineralised water 58 39 58 54 36 55 46 56.2 Sodium hydroxide 98% 20 30 10 22 15 21 15 24.8 Potassium hydroxide 95% -- --- 20 -- 15 - Polyacrylic acid B 13 20 10 7 5 9.5 Polyacrylic acid A -- --- is 15 7 5 -- NTA 8 10 10 8 12 9 12 8.5 DEMP 0.5 0.5 1 0.5 1 0.5 1 0.5 HEDP 0.5 0.5 1 0.5 1 0.5 1 0.5 100 100 100 100 100100 This compositions are useful as alkali donors in industrial washing systems.
4 Examples 9-14:
Demineralised water sodium nitrite NTA sodium hydroxide 98% potassium hydroxide 95X Polyacrylic acid B Polyacrylic acid A DEMP HEDP Tolyltriazole The following compositions were made up as follows Table 2
9 10 11 12 13 14 39 33 26 0.7 0.7 0.7 12 12 12 14 16 18 15 17 35 2 3 3 5 5 1.0 2 3 5 5 6 0.3 0.3 0.3 0.3 0.3 27 0.7 12 15 15 20 23 43.7 0.7 -- 12 38.0 is 15.3 17 -- 2.0 100 100 100 100 100 The compositions of examples 9-14 are useful as dish washing machine liquids.
Claims (13)
- Claims:Case 150-5302 1. A phosphate and silicate free aqueous composition comprising (i) 5-45X of alkali, (ii) 0.5-20% of polycarboxylate and (iii) 0.1-10X.of phosphonate, the balance comprising water.
- 2. A composition according to Claim 1 in which the ratio of polycarboxylate to phosphonate is 1:1 to 30:1.
- 3. A composition according to Claim 1 or Claim 2 comprising (i) 15-35% of alkali, (ii) 3-10% of polycarboxylate and (M) 0.2-1.5% of phosphonate, the balance being water and one or more compounds selected sequestering agents and corrosion inhibitors.
- 4. A composition according to any one of Claims 1 to 3 comprising (i) 1035% of alkali, (ii) 0.5-15% of polycarboxylate and (M) 0.2-5% of phosphonate, the balance comprising water.
- 5. A composition according to any one of the preceding claims in which the alkali used is an alkali metal -hydroxide or -carbonate.
- 6. A composition according to any one of the preceding claims in which the polycarboxylate has a molecular weight of 1,000 to 250,000.
- 7. A composition according to Claim 6 in which the carboxylate is a salt derived from those selected from one of the following acids:i Case 150-5302 methacrylic acid, acrylic acid, cc-hydroxyacrylic acid, maleic acid or copolymers thereof.
- 8. A composition according to any one of the preceding claims in which the phosphonates are salts of one of the following acids: hydroxy Cl4alkylene phosphonic acid or aminomethylene phosphonic acid or phosphonic Cl-4alkylene carboxylic acid.
- 9. A composition according to any one of the preceding claims in which the phosphonate is a salt of one or more of the following phosphonic acids: 1-hydroxyethane-l,l-disphosphonic acid (HEDP), aminotri(methylene phosphonic acid) (ATMP), ethylene diamine tetra(methylene phosphonic acid) (EDTMP), diethylene triamine penta(methylene phosphonic acid) (DETPMP), hexamethylene diamine tetra(methylene phosphonic acid), amine oxide tri(methylene phosphonic acid) and 2-phosphono butane -1,2,4tricarboxylic acid (PBTC).
- 10. A composition according to any one of the preceding claims containing one or more sequestering agents selected from salts of nitrilotriacetic acid and citric acid.
- 11. A composition substantially as herein described with reference to any one of Examples 1 to 14.
- 12. A detergent composition containing a composition according to any one of the preceding claims and one or more surface active agents.
- 13. A detergent composition according to Claim 12 in which the surface active agents are selected from anionic or nonionic surface active agents.Published 1990 at The Patent Office, State House, 6"1 Holborn, London WC1R4TP. Further copies maybe obtainedfrom The Patent 0Mce. Sales Branch, St Mary Cray, Orpington, Kent BR5 3ED. Printed by Multiplex tecbxuques ltd, St Mary Cray, Kent, Con. 1187 Sales Branch, St Mary Gray, Orpington, lient Bitb;jkw. kTinteci oy mxutipiex tecnxuques mi, bT, jaury ur&Ly, jr!, unL, vv" &,..
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3900310 | 1989-01-07 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB9000224D0 GB9000224D0 (en) | 1990-03-07 |
| GB2227021A true GB2227021A (en) | 1990-07-18 |
| GB2227021B GB2227021B (en) | 1992-08-05 |
Family
ID=6371680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9000224A Expired - Lifetime GB2227021B (en) | 1989-01-07 | 1990-01-05 | Phosphate-and silicate-free detergent compositions |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPH02228399A (en) |
| BE (1) | BE1003581A5 (en) |
| CH (1) | CH679311A5 (en) |
| FR (1) | FR2641544A1 (en) |
| GB (1) | GB2227021B (en) |
| IT (1) | IT1239740B (en) |
| NL (1) | NL9000040A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0659873A1 (en) * | 1993-12-23 | 1995-06-28 | The Procter & Gamble Company | Rinsing compositions |
| EP0791095A1 (en) * | 1994-11-10 | 1997-08-27 | The Procter & Gamble Company | Method of cleaning carpets |
| WO1997031996A1 (en) * | 1996-02-29 | 1997-09-04 | Unilever N.V. | Machine dishwashing gel compositions |
| US5801137A (en) * | 1993-12-23 | 1998-09-01 | The Procter & Gamble Company | Detergent compositions containing (poly)carboxylates, organo diphosphonic and acrylic acid derived components, and silicate |
| US5905065A (en) * | 1995-06-27 | 1999-05-18 | The Procter & Gamble Company | Carpet cleaning compositions and method for cleaning carpets |
| US5928384A (en) * | 1994-11-10 | 1999-07-27 | The Procter & Gamble Company | Method of cleaning carpets |
| EP1253192A1 (en) * | 2001-04-23 | 2002-10-30 | BetzDearborn Inc | Anti-scuffing treatment for alkaline bottle washing systems |
| EP2604677A1 (en) * | 2011-12-14 | 2013-06-19 | Soro Internacional S.A. | Detergent for dishwashing machine |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9423495D0 (en) * | 1994-11-21 | 1995-01-11 | Unilever Plc | Cleaning method |
| JP3566015B2 (en) * | 1997-02-17 | 2004-09-15 | 花王株式会社 | Detergent composition for dishwashers |
| DE10002710A1 (en) * | 2000-01-22 | 2001-08-02 | Henkel Ecolab Gmbh & Co Ohg | Production of creamy alkaline-aqueous cleaning agents containing complexing agents |
| JP6232246B2 (en) * | 2013-09-26 | 2017-11-15 | シーバイエス株式会社 | Cleaning composition for automatic dishwasher and method of using the same |
| JP6444245B2 (en) * | 2015-04-06 | 2018-12-26 | 株式会社Adeka | Concentrated liquid detergent composition for automatic dishwasher and method for washing dishes with automatic dishwasher |
| JP6490292B2 (en) * | 2018-11-27 | 2019-03-27 | 株式会社Adeka | Concentrated liquid detergent composition for automatic dishwasher and method for washing dishes with automatic dishwasher |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1234320A (en) * | 1968-11-02 | 1971-06-03 | ||
| GB1314790A (en) * | 1970-11-20 | 1973-04-26 | Benckiser Gmbh Joh A | Prevention of scale-forming deposits in aqueous systems containing hard water |
| GB2051115A (en) * | 1979-05-31 | 1981-01-14 | Chemed Corp | Detergent additive |
| GB2203163A (en) * | 1987-04-03 | 1988-10-12 | Sandoz Ltd | Dishwasher detergents |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA661932B (en) * | 1965-04-01 | |||
| GB1443570A (en) * | 1973-09-17 | 1976-07-21 | Diversey Ltd | Detergent compositions |
| AU7353874A (en) * | 1973-09-26 | 1976-03-25 | Diversey Australasia | Hard water scale control |
| DE3717227A1 (en) * | 1987-05-21 | 1988-12-01 | Henkel Kgaa | PHOSPHATE-FREE DETERGENT WITH REDUCED INCRUSTING TENDENCY |
-
1990
- 1990-01-03 CH CH27/90A patent/CH679311A5/de not_active IP Right Cessation
- 1990-01-05 BE BE9000017A patent/BE1003581A5/en not_active IP Right Cessation
- 1990-01-05 JP JP2000135A patent/JPH02228399A/en active Pending
- 1990-01-05 GB GB9000224A patent/GB2227021B/en not_active Expired - Lifetime
- 1990-01-05 FR FR9000103A patent/FR2641544A1/en active Granted
- 1990-01-08 IT IT47510A patent/IT1239740B/en active IP Right Grant
- 1990-01-08 NL NL9000040A patent/NL9000040A/en not_active Application Discontinuation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1234320A (en) * | 1968-11-02 | 1971-06-03 | ||
| GB1314790A (en) * | 1970-11-20 | 1973-04-26 | Benckiser Gmbh Joh A | Prevention of scale-forming deposits in aqueous systems containing hard water |
| GB2051115A (en) * | 1979-05-31 | 1981-01-14 | Chemed Corp | Detergent additive |
| GB2203163A (en) * | 1987-04-03 | 1988-10-12 | Sandoz Ltd | Dishwasher detergents |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0659873A1 (en) * | 1993-12-23 | 1995-06-28 | The Procter & Gamble Company | Rinsing compositions |
| US5712244A (en) * | 1993-12-23 | 1998-01-27 | Proctor & Gamble Company | Rinse aid compositions comprising non-nitrogen-containing organs diphosphonic acid, salt or complex thereof |
| US5801137A (en) * | 1993-12-23 | 1998-09-01 | The Procter & Gamble Company | Detergent compositions containing (poly)carboxylates, organo diphosphonic and acrylic acid derived components, and silicate |
| EP0659874B1 (en) * | 1993-12-23 | 2002-10-09 | The Procter & Gamble Company | Detergent compositions |
| EP0791095A1 (en) * | 1994-11-10 | 1997-08-27 | The Procter & Gamble Company | Method of cleaning carpets |
| EP0791095A4 (en) * | 1994-11-10 | 1997-10-15 | Procter & Gamble | Method of cleaning carpets |
| US5928384A (en) * | 1994-11-10 | 1999-07-27 | The Procter & Gamble Company | Method of cleaning carpets |
| US5905065A (en) * | 1995-06-27 | 1999-05-18 | The Procter & Gamble Company | Carpet cleaning compositions and method for cleaning carpets |
| WO1997031996A1 (en) * | 1996-02-29 | 1997-09-04 | Unilever N.V. | Machine dishwashing gel compositions |
| EP1253192A1 (en) * | 2001-04-23 | 2002-10-30 | BetzDearborn Inc | Anti-scuffing treatment for alkaline bottle washing systems |
| EP2604677A1 (en) * | 2011-12-14 | 2013-06-19 | Soro Internacional S.A. | Detergent for dishwashing machine |
Also Published As
| Publication number | Publication date |
|---|---|
| IT9047510A0 (en) | 1990-01-08 |
| GB9000224D0 (en) | 1990-03-07 |
| JPH02228399A (en) | 1990-09-11 |
| CH679311A5 (en) | 1992-01-31 |
| BE1003581A5 (en) | 1992-04-28 |
| IT9047510A1 (en) | 1990-07-08 |
| NL9000040A (en) | 1990-08-01 |
| GB2227021B (en) | 1992-08-05 |
| FR2641544B1 (en) | 1994-07-13 |
| FR2641544A1 (en) | 1990-07-13 |
| IT1239740B (en) | 1993-11-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19960105 |