GB2199843B - A process for the conversion of coal and gypsum to valuable products - Google Patents

A process for the conversion of coal and gypsum to valuable products

Info

Publication number
GB2199843B
GB2199843B GB8728870A GB8728870A GB2199843B GB 2199843 B GB2199843 B GB 2199843B GB 8728870 A GB8728870 A GB 8728870A GB 8728870 A GB8728870 A GB 8728870A GB 2199843 B GB2199843 B GB 2199843B
Authority
GB
United Kingdom
Prior art keywords
gypsum
coal
conversion
valuable products
valuable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
GB8728870A
Other languages
English (en)
Other versions
GB8728870D0 (en
GB2199843A (en
Inventor
Jerome Herbert Marten
Timothy J Kendron
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Florida Industrial and Phosphate Research Institute FIPR
Original Assignee
Florida Industrial and Phosphate Research Institute FIPR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Florida Industrial and Phosphate Research Institute FIPR filed Critical Florida Industrial and Phosphate Research Institute FIPR
Publication of GB8728870D0 publication Critical patent/GB8728870D0/en
Publication of GB2199843A publication Critical patent/GB2199843A/en
Application granted granted Critical
Publication of GB2199843B publication Critical patent/GB2199843B/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/48—Sulfur dioxide; Sulfurous acid
    • C01B17/50—Preparation of sulfur dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/86—Other features combined with waste-heat boilers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/15—Details of feeding means
    • C10J2200/152—Nozzles or lances for introducing gas, liquids or suspensions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0909—Drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
    • C10J2300/1628—Ash post-treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1687—Integration of gasification processes with another plant or parts within the plant with steam generation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Processing Of Solid Wastes (AREA)
GB8728870A 1986-12-10 1987-12-10 A process for the conversion of coal and gypsum to valuable products Expired - Lifetime GB2199843B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/939,964 US4744969A (en) 1986-12-10 1986-12-10 Process for the conversion of coal and gypsum to valuable products

Publications (3)

Publication Number Publication Date
GB8728870D0 GB8728870D0 (en) 1988-01-27
GB2199843A GB2199843A (en) 1988-07-20
GB2199843B true GB2199843B (en) 1991-07-03

Family

ID=25474009

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8728870A Expired - Lifetime GB2199843B (en) 1986-12-10 1987-12-10 A process for the conversion of coal and gypsum to valuable products

Country Status (9)

Country Link
US (1) US4744969A (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html)
KR (1) KR950011827B1 (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html)
CN (1) CN1017060B (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html)
BR (1) BR8706689A (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html)
GB (1) GB2199843B (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html)
IN (1) IN170295B (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html)
TN (1) TNSN87137A1 (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html)
TR (1) TR24716A (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html)
ZA (1) ZA879269B (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4946658A (en) * 1986-11-06 1990-08-07 Florida Institute Of Phosphate Research Addition of pyritic materials to feed mix for desulfurization of phosphogypsum
US5066474A (en) * 1988-05-10 1991-11-19 Science Ventures, Inc. Method for sulfur dioxide production from calcium sulfate by entrained high-temperature slagging reduction
US5271919A (en) * 1989-01-19 1993-12-21 Bayer Aktiengesellschaft Process for the thermal decomposition of metal sulphates
US4963513A (en) * 1989-05-24 1990-10-16 Florida Institute Of Phosphate Research Coal gasification cogeneration process
US4917024A (en) * 1989-05-24 1990-04-17 Florida Institute Of Phosphate Research Coal fired power plant with pollution control and useful byproducts
US6337058B1 (en) * 1996-09-16 2002-01-08 E&C Williams Inc. Process for producing calcium sulfide
KR100767563B1 (ko) * 2006-04-03 2007-10-17 한국전력기술 주식회사 볼 밀링의 도입에 의하여 넓은 온도 대역에서 우수한질소산화물의 제거활성을 갖는 바나듐/티타니아계 촉매의제조방법 및 이의 사용방법
WO2009158539A1 (en) * 2008-06-26 2009-12-30 Casella Waste Systems, Inc. Engineered fuel feed stock useful for displacement of coal in coal firing plants
US9657937B2 (en) * 2010-08-23 2017-05-23 Saudi Arabian Oil Company Steam generation system having multiple combustion chambers and dry flue gas cleaning
CA2737825A1 (en) * 2011-04-20 2012-10-20 Carbon Solutions Incorporated Conversion of acid gas to sulphate or phosphate-based fertilizers
WO2013095828A1 (en) * 2011-12-20 2013-06-27 Exxonmobil Upstream Research Company Method of separating carbon dioxide from liquid acid gas streams
US20140026483A1 (en) * 2012-07-30 2014-01-30 General Electric Company Systems for preheating feedstock
JP6695163B2 (ja) * 2016-02-17 2020-05-20 三菱日立パワーシステムズ株式会社 微粉燃料供給装置及び方法、ガス化複合発電設備
CN112960652B (zh) * 2021-05-06 2022-01-28 西南科技大学 一种工业副产石膏渣制备高浓度二氧化硫气体的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB837027A (en) * 1956-03-31 1960-06-09 Bayer Ag A process for the production of sulphur dioxide from sulphates
US4017272A (en) * 1975-06-05 1977-04-12 Bamag Verfahrenstechnik Gmbh Process for gasifying solid carbonaceous fuel
US4503018A (en) * 1983-02-14 1985-03-05 Davy Mckee Corporation Desulfurization of phosphogypsum

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3717700A (en) * 1970-08-25 1973-02-20 Us Interior Process and apparatus for burning sulfur-containing fuels
US3729551A (en) * 1971-01-07 1973-04-24 Cons Coal Co Conversion of calcium sulfate to calcium oxide and elemental sulfur
CA1061987A (en) * 1974-05-15 1979-09-11 Iowa State University Research Foundation, Inc. Decomposition of calcium sulfate by zoned reduction and oxidation in a fluidized bed
US4197285A (en) * 1977-12-07 1980-04-08 The United States Of America As Represented By The United States Department Of Energy Regeneration of lime from sulfates for fluidized-bed combustion
DE3264214D1 (en) * 1981-03-24 1985-07-25 Exxon Research Engineering Co Apparatus for converting a fuel into combustible gas

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB837027A (en) * 1956-03-31 1960-06-09 Bayer Ag A process for the production of sulphur dioxide from sulphates
US4017272A (en) * 1975-06-05 1977-04-12 Bamag Verfahrenstechnik Gmbh Process for gasifying solid carbonaceous fuel
US4503018A (en) * 1983-02-14 1985-03-05 Davy Mckee Corporation Desulfurization of phosphogypsum

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Kirk-Othmer "Encyclopedia of Chemical Technology"vol22pp267-297 Third Edn (1983) *

Also Published As

Publication number Publication date
GB8728870D0 (en) 1988-01-27
GB2199843A (en) 1988-07-20
KR950011827B1 (ko) 1995-10-11
ZA879269B (en) 1988-08-31
KR880007353A (ko) 1988-08-27
US4744969A (en) 1988-05-17
CN1017060B (zh) 1992-06-17
IN170295B (c_deeref_Disk_and_Scratch_Disk_Pools_and_Their_Defaults.html) 1992-03-07
TR24716A (tr) 1992-01-13
CN87107443A (zh) 1988-11-02
TNSN87137A1 (fr) 1990-01-01
BR8706689A (pt) 1988-07-19

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19931210