GB1593601A - Insecticide composition - Google Patents
Insecticide composition Download PDFInfo
- Publication number
- GB1593601A GB1593601A GB48564/77A GB4856477A GB1593601A GB 1593601 A GB1593601 A GB 1593601A GB 48564/77 A GB48564/77 A GB 48564/77A GB 4856477 A GB4856477 A GB 4856477A GB 1593601 A GB1593601 A GB 1593601A
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- GB
- United Kingdom
- Prior art keywords
- shampoo
- composition
- insecticide
- colonies
- volume
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 239000002917 insecticide Substances 0.000 title claims abstract description 28
- 239000000080 wetting agent Substances 0.000 claims abstract description 13
- 238000011282 treatment Methods 0.000 claims abstract description 10
- 230000000590 parasiticidal effect Effects 0.000 claims abstract description 7
- 239000002297 parasiticide Substances 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims abstract description 4
- 239000004141 Sodium laurylsulphate Substances 0.000 claims abstract description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 44
- 239000002453 shampoo Substances 0.000 claims description 39
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 claims description 15
- 229960002809 lindane Drugs 0.000 claims description 15
- 241000238631 Hexapoda Species 0.000 claims description 14
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N gamma-hexachlorocyclohexane Natural products ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 244000166675 Cymbopogon nardus Species 0.000 claims description 10
- 235000018791 Cymbopogon nardus Nutrition 0.000 claims description 10
- 239000000686 essence Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 9
- 241000699670 Mus sp. Species 0.000 claims description 6
- 238000009472 formulation Methods 0.000 claims description 6
- 231100000518 lethal Toxicity 0.000 claims description 6
- 230000001665 lethal effect Effects 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 231100000419 toxicity Toxicity 0.000 claims description 6
- 230000001988 toxicity Effects 0.000 claims description 6
- 244000061408 Eugenia caryophyllata Species 0.000 claims description 5
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 5
- 235000007303 Thymus vulgaris Nutrition 0.000 claims description 5
- 240000002657 Thymus vulgaris Species 0.000 claims description 5
- 239000001585 thymus vulgaris Substances 0.000 claims description 5
- 241000894006 Bacteria Species 0.000 claims description 4
- 244000223760 Cinnamomum zeylanicum Species 0.000 claims description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 4
- 235000005979 Citrus limon Nutrition 0.000 claims description 4
- 244000131522 Citrus pyriformis Species 0.000 claims description 4
- 240000008853 Datura stramonium Species 0.000 claims description 4
- 241000721662 Juniperus Species 0.000 claims description 4
- 244000178870 Lavandula angustifolia Species 0.000 claims description 4
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 4
- 244000246386 Mentha pulegium Species 0.000 claims description 4
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 4
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 4
- 241001529744 Origanum Species 0.000 claims description 4
- 235000011203 Origanum Nutrition 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 244000178231 Rosmarinus officinalis Species 0.000 claims description 4
- 240000004460 Tanacetum coccineum Species 0.000 claims description 4
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 4
- 240000006909 Tilia x europaea Species 0.000 claims description 4
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 235000017803 cinnamon Nutrition 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 235000001050 hortel pimenta Nutrition 0.000 claims description 4
- 230000009027 insemination Effects 0.000 claims description 4
- 239000002085 irritant Substances 0.000 claims description 4
- 231100000021 irritant Toxicity 0.000 claims description 4
- 239000001102 lavandula vera Substances 0.000 claims description 4
- 235000018219 lavender Nutrition 0.000 claims description 4
- 239000004571 lime Substances 0.000 claims description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 4
- 210000003689 pubic bone Anatomy 0.000 claims description 4
- 229940015367 pyrethrum Drugs 0.000 claims description 4
- 230000001846 repelling effect Effects 0.000 claims description 4
- 210000003491 skin Anatomy 0.000 claims description 4
- 241000723346 Cinnamomum camphora Species 0.000 claims description 3
- 241000124008 Mammalia Species 0.000 claims description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 3
- 241000018646 Pinus brutia Species 0.000 claims description 3
- 235000011613 Pinus brutia Nutrition 0.000 claims description 3
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229960000846 camphor Drugs 0.000 claims description 3
- 229930008380 camphor Natural products 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 claims description 3
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 claims description 3
- 229920001817 Agar Polymers 0.000 claims description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 claims description 2
- 241000588724 Escherichia coli Species 0.000 claims description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 239000008272 agar Substances 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000003899 bactericide agent Substances 0.000 claims description 2
- 230000003385 bacteriostatic effect Effects 0.000 claims description 2
- 201000010099 disease Diseases 0.000 claims description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 210000005069 ears Anatomy 0.000 claims description 2
- 210000002615 epidermis Anatomy 0.000 claims description 2
- 230000012447 hatching Effects 0.000 claims description 2
- 230000035876 healing Effects 0.000 claims description 2
- 230000000622 irritating effect Effects 0.000 claims description 2
- 230000007794 irritation Effects 0.000 claims description 2
- 231100000682 maximum tolerated dose Toxicity 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 229960002446 octanoic acid Drugs 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 206010061217 Infestation Diseases 0.000 claims 2
- 241000282472 Canis lupus familiaris Species 0.000 abstract description 5
- 241000238876 Acari Species 0.000 abstract description 2
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 241001674048 Phthiraptera Species 0.000 description 13
- 235000011054 acetic acid Nutrition 0.000 description 13
- 210000004209 hair Anatomy 0.000 description 8
- 244000045947 parasite Species 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- 229940085790 synthetic camphor Drugs 0.000 description 3
- 241000517307 Pediculus humanus Species 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 241000254171 Curculionidae Species 0.000 description 1
- 241001124144 Dermaptera Species 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 150000001243 acetic acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229940095714 cider vinegar Drugs 0.000 description 1
- -1 citronella Chemical compound 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/02—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/24—Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/44—Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Pest Control & Pesticides (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Botany (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cosmetics (AREA)
Abstract
A proportion by volume of from 1 to 25 % at least of an organic acid possessing from 2 to 8 carbon atoms is introduced into a mixture comprising a wetting agent so as to bring the pH of the resulting mixture to a value below 4.5. Natural or synthetic insecticidal and parasiticidal substances may also be added. Sodium lauryl sulphate is preferred as a wetting agent. The products obtained are used as parasiticides and insecticides, preferably for the treatment of dogs against fleas and ticks.
Description
(54) INSECTICIDE COMPOSITION
(71) We, SOCIETE D'ETUDES. DE RECHERCHES, DE TRAVAUX D'ORGA
NISATION ET DE GESTION S.E.R.T.O.G., of 53 Bld. Victor Hugo -92200 - Neuilly s/Seine, France, a French body corporate, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:
This invention relates to an insecticide composition for use especially as a shampoo, and intended in particular for destroying and repelling particularly resistant insects such as lice and fleas.
Various constituents are known which are capable of destroying these types of insects, as for example D.D.T, hexachlorocyclohexane and lindane. However, these substances are generally available as a powder, and their high toxicity makes it dangerous to use them in direct contact with the skin of mammals.
Taking as an example lice and fleas, these pests preferably attack young animals (children, puppies and kittens), namely those which are particularly sensitive to toxic substances.
On the other hand, it is known that certain acid constituents in liquid form such as acetic acid are active against insects and parasites, in particular when used in concentrated solution with a pH of around 2.
However, at such pH values, these liquid substances substantially attack the skin of animals to the extent that they have to be used in dilute solution, which substantially reduces their efficiency.
The object of the present invention is to provide an insecticide composition which mitigates or overcomes these drawbacks, and which by its action both enables the insects and parasites to be effectively destroyed and prevents their return to the treated parts.
The composition of the present invention, to be used in particular as a shampoo, comprises a proportion of a wetting agent, such as sodium lauryl sulphate, ammonia or triethanolamine, and 1 to 25% by volume of at least one organic carboxylic acid having 2 to 8 carbon atoms such that the pH of the composition is less than 3.5.
In particular, the compositions according to the invention may comprise 2 to 12% of acetic acid by volume such that the pH of the composition is less than 3.2, plus 0.5 to 20%, and in particular 0.5 to 3%, by volume of insecticides and/or parasiticides deriving from natural substances or those obtained artificially by synthesis, such as extracts or essences of clove, lavender, peppermint, origanum, rosemary, lime, juniper, lemon, citronella, thyme,
Datura Stramonium, pine, pyrethrum or pyrethrin, and essential oils of peel or Ceylon cinnamon leaves. In one particular application, there may be applied to a region to be protected such an insecticide and/or parasiticide, followed by shampooing the region with an insecticide composition according to the invention.
The composition may also advantageously contain an insecticide and healing substance such as natural or synthetic camphor in a proportion by volume of 0.5 to 5%, more preferably 0.5 to 1.50to.
For a better understanding of the advantages and the mode of action of the composition according to the invention, a description is given hereinafter of non-limiting examples of formulations corresponding to the main applications of the composition, together with examples of the treatment carried out.
For each formulation, it will be noted that the proportion of wetting agent is important.
In this respect it has been surprisingly found that the insecticide effect of acetic acid is considerably increased by the addition of wetting agents such as ammonia, triethanolamine or sodium lauryl sulphates, traditional cationic bases or non-ionic products used traditionally in the shampoo field.
This observation may be verified by the following test carried out on weevils, ants, earwigs: the product used in the examples described hereinafter is diluted to a third of its volume, and a few drops are placed on each insect held in an object slide so that the body of the insect is impregnated over approximately three quarters.
The time required for the insect to show no further movement is then measured. This time is compared with that obtained when using an aqueous solution of acetic acid of an equivalent pH.
The results obtained show that the times are on an average 2 to 5 times less for the shampoo than for the pure acetic acid (20 to 50 seconds instead of 1 to 3 minutes).
First Example: hygienic shampoo effective against lice, for adults and children. The proportions are by volume.
- Texapant (R) N 40 wetting agent (HENKEL) diluted to 30% . . . . . . . . . . . . . . . . .. 75to95% synthetic camphor .. 0.5 to 1.5% - Citronella . .. 0.5 to 1.5% - Acetic acid . 5 to 10% -pH ... .......... ... .... 1.8 to 2.3.
Case 1: Two children aged respectively 11 and 13 with hair comprising a considerable colony of adult lice and nits were treated with a shampoo containing 1% of synthetic camphor, 1% of citronella essence, 5% of acetic acid and 93% of Texapant (R) diluted to 30% (pH adjusted to 2.1).
The shampoo wash was carried out at 9 o'clock in the morning. The shampoo was used actively for 15 minutes, followed by a water wash.
An examination of the head showed that there were no longer any adult lice, and the proportion of nits was reduced.
Further shampooing was carried out 2, 4 and 6 days later although no adult louse was observed. The number of nits continuously decreased.
New washes were made every week. After three weeks the nits had totally disappeared.
Case 2: A young girl aged 15 observed on taking a bath that lice were swimming close to her. She was then treated each evening with a 0.8% lindane powder, she was covered with a bonnet all night and was then washed with an ordinary shampoo each morning and combed with a tooth comb. After five days, nits were still in her hair.
A single shampooing with the product indicated for case 1 was sufficient to clear her hair of all parasites and allow the previous fastidious and disagreeable treatment to be discontinued.
Case 3. A small 5 year old girl had been suffering from nits for three weeks and had been treated each evening with a powder comprising 0.4% lindane and 10% D.D.T. The insecticides were protected all night in her hair with a bonnet, and she was given an ordinary shampoo in the morning followed by combing with a tooth comb.
This little blonde girl had particularly fine hair, and the numerous nits were fixed very firmly thereto.
An initial treatment with the product of case 1 gave only a partial result. Two further applications of the product were necessary to totally eliminate the nits.
Second Example: treatment of fleas, lice and ticks on dogs.
A shampoo was used containing 6% of acetic acid, 1.5% of citronella, 1.5% of clove essence and 91% of Texapant (R) diluted to 30% (pH adjusted to 2).
An adult Teckel dog infested with fleas was treated.
A wash with a shampoo of the above veterinary formula was carried out at 8 o'clock in the morning. By 12 o'clock the dog was free from fleas and contained no further fleas during the next three days in spite of an unfavourable environment.
A preservation treatment consisting of spraying a lotion in the form of a solution of 25% thyme decoction, 73% cider vinegar and 2% citronella, together with a wetting agent
enabled any return of the parasites to be prevented until the environment (premises and
fabrics) had been completely disinfected with the products of Example 3.
Third Example: treatment of premises and fabrics.
A shampoo was used composed of 10% acetic acid, 2% citronella essence and 2% camphor (pH adjusted to 1.8).
A proliferation of fleas had been noticed in a poorly closed room which had been
unoccupied for some time, and contained various objects and fabrics.
After arranging the objects the carpet covering part of the floor plus the tiling were
sprayed with the shampoo diluted to twice its volume with water. Two hours later, the fleas gave no further sign of life.
In a like manner, coats, blankets and dog baskets were successfully treated with solutions of 5 cm3 of shampoo per litre of water.
Generally, the method of using the products according to the invention is as follows: the parts to be treated are shampooed with the compositions described heretofore, the products are left to act for a time generally between one and ten minutes in the case of animals and five to twenty minutes in the case of objects.
Abundant rinsing is then carried out to wash away the acetic acids or its equivalents, together with the insects and parasites.
After washing, it is found that the products repulsive to insects remain in sufficient quantity to give protection against new infection.
However, in numerous cases, it is of advantage to continue treatment by means of successive washes at time intervals until the larva completely disappears, and to use a preservative treatment in the form of sprays of the various essences of insecticide or parasiticide products given heretofore, with or without camphor, but preferably without acetic acid, i.e. citronella, essence of clove, lavender, peppermint, origanum, rosemary, lime, juniper, lemon, thyme, Datura Stramonium, pyrethrum or essential oil of Ceylon cinnamon.
Such sprays protect the subject at length between each shampoo.
In addition, the insecticide action of the shampoo used in Case 1 of Example 1 was compared with a powder preparation containing 15% by weight of lindane in the following manner:
1. Test on the adult louse:
5 cm3 of pure shampoo were placed in a dish, and five lice (pediculus humanus) were then placed therein. Death was immediate. In order to be certain of the result, a further test was carried out leaving the lice for only 10 seconds in the shampoo and withdrawing them with a wooden rod. They were then viewed under a lens and it was found that the lice were
effectively dead.
The same test was carried out with shampoo diluted to 50%, then to 25%, so as to give
concentrations varying from 25 to 100%.
The death of the lice was slower with the two dilutions, and the recovery test for the lice
showed that after 30 seconds, the lice no longer returned to life.
The same tests were carried out on the phtirius pubis species with the same 100%
mortality after 30 seconds. These tests are compared with a 15% lindane powder
preparation.
The table given hereinafter summarises the results obtained:
Tests on adult pediculus humanus:
MORTALITY PERCENTAGE: After 10 After 30 After 2
seconds seconds hours
Pure R.S. 206 100% 100% 100%
R.S. 206 Diluted to 50% 20% 100% 100%
R.S. 206 diluted to 25% 0% 100% 100%
15% lindane powder 0% 0% 50%
The same test was carried out on phtirius pubis adults with identical results.
2. Tests on thepediculus humanus nit:
It was very difficult to know if the nits had been properly killed by the product, because in
order to be certain of their death it was necessary to wait two to five weeks. The fact of
having separated the nit from the hair to which it was attached could have been the factor
leading to its destruction.
The following test was carried out: ten hairs carrying nits were taken from a child and
placed in dishes with the test products or water for time of 15 minutes, after which they
were preserved at a temperature of 22".
Some nits separated from the hair in the shampoo, whereas others remained attached.
Observations were made over five weeks and the results were as follows:
OBSERVATIONS ON THE HATCHING
OF NITS: 1st 2nd 3rd 4th 5th week
Pure R.S. 206 0 0 0 0 0 R.S. 206 diluted to 50% 0 0 0 0 0 15% lindane powder 0 0 0 0 0
The same test was carried out on phtirius pubis nits with identical results.
The product is thus more active than a 15% lindane formulation;
0.4 and 0.8% lindane formulations have insufficient action for use as a comparison element.
The bacteriostatic action of the products according to the invention was also verified even though they contain none of the normally used bactericides such as methyl paraoxybenzoate, and various tests have shown that no bacteria develops in the pure or 50% diluted product.
The test to check whether the preparation was free from bacteria was carried out because of the interesting results to be obtained.
The method employed was the following, using the shampoo of Example 1: 1 Insemination on ordinary agar.
2 Preservation in a drying cupboard at 370C for 48 hours and for seven days.
Results: After 48 hours After 7 days
Pure shampoo 0 colonies 0 colonies
Shampoo diluted to 50% 0 colonies 0 colonies
After insemination with escherichia coli:
After 48 hours After 7 days
Pure shampoo 0 colonies 0 colonies
Shampoo diluted to 50% 0 colonies 0 colonies
Other applications and modifications of the invention will be easily conceived by the expert of the art without departing from the scope of the invention, in particular by substituting equivalents for various products described heretofore, for example by replacing acetic acid with homologous acids; however it has been found that the results obtained may be substantially inferior, in particular with propionic and caprylic acid.
Finally, the determined toxicity may vary substantially, and this reinforces the advantage of acetic acid associated synergically with a wetting agent to give it an increased insecticide powder while maintaining its toxicity within limits entirely compatible with its use when in contact with sensitivie epidermis.
In this respect, the P.O. toxicity obtained by administering the shampoo of Example 1 to male RIVER mice of an average weight of 25 grams shows the maximum tolerated dose to be 24 ml/kg and the lethal 100 does to be 40 ml/kg.
The results do not enable a lethal 50 dose to be evaluated. By comparison, the lethal 50 dose for lindane observed with aqueous preparations administered orally to mice is approximately 300 mg/kg.
Finally, a study of local cutaneous tolerance showed a primary irritation index of 0.3, a low value, and repeated application tests on the ears of mice gave the conclusion that the shampoo is not an irritant. In addition, repeated applications on rabbits skin have shown an excellent tolerance.
Only tests in which eyes were involved suggest that the shampoo could be an irritant, but this irritating action is very weak when the product is used in its required dilution.
In any method claimed herein of utilizing the composition according to the invention, we disclaim any such method of medical treatment of the human body to cure or prevent disease.
Subject to the foregoing disclaimer,
WHAT WE CLAIM IS:
1. An insecticide composition for use in the form of a shampoo, which comprises a wetting agent and 1 to 25% by volume of at least one organic carboxylic acid having 2 to 8 carbon atoms such that the pH of the composition is less than 3.5
**WARNING** end of DESC field may overlap start of CLMS **.
Claims (12)
1. An insecticide composition for use in the form of a shampoo, which comprises a wetting agent and 1 to 25% by volume of at least one organic carboxylic acid having 2 to 8 carbon atoms such that the pH of the composition is less than 3.5
2. An insecticide composition as claimed in Claim 1, which comprises 2 to 12% by volume of acetic acid such that the pH of the composition is less than 3.2.
3. An insecticide composition as claimed in Claim 1 or 2, which further comprises 0.5 to 20% by volume of at least one natural or synthetic insecticide or parasiticide selected from extracts or essences of clove, lavender, peppermint, origanum, rosemary, lime, juniper, lemon, citronella, thyme, Datura Stramonium, pine, pyrethrum and pyrethrin, and essential essences of peel or Ceylon cinnamon leaves.
4. An insecticide composition as claimed in Claim 3, which comprises 0.5 to 3% by volume of citronella.
5. An insecticide composition as claimed in any of Claims 1 to 4, which comprises an insecticide and healing substance of synthetic or natural camphor, in an amount of 0.5 to 5% by volume.
6. An insecticide composition as claimed in Claim 5, which comprises 0.5 to 1.5% by volume of camphor.
7. An insecticide composition as claimed in any one of Claims 1 to 6, wherein the wetting agent is sodium lauryl sulphate.
8. A method of destroying or repelling from a mammal insects of the louse and flea type, which comprises shampooing infested parts of the mammal with a composition as claimed in any one of Claims 1 to 7.
9. A method of destroying or repelling insects from premises or fabrics, which comprises
applying a composition as claimed in any one of Claims 1 to 7 to infested regions.
10. A method of preventing insect infestation, which comprises applying to the region to be protected an insecticide or parasiticide selected from extracts or essences of clove, lavender, peppermint, origanum, rosemary, lime, juniper, lemon, citronella, thyme, Datura Stramonium, pine, pyrethrum and pyrethrin, and essential essences of peel of Ceylond cinnamon leaves, and shampooing the said region with an insecticide composition which comprises a wetting agent and 1 to 25% by volume of at least one organic carboxylic acid having 2 to 8 carbon atoms such that the pH of the composition is less than 3.5.
11. An insecticide composition as claimed in Claim 1, substantially as herein particularly described in any Example or Test.
12. A method of destroying or repelling insects as claimed in Claim 8 or 9, or of preventing insect infestation as claimed in Claim 10, substantially as herein described in any
Example or Test.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7635121A FR2371190A1 (en) | 1976-11-22 | 1976-11-22 | INSECTIVE COMPLEXES |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1593601A true GB1593601A (en) | 1981-07-22 |
Family
ID=9180154
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB48564/77A Expired GB1593601A (en) | 1976-11-22 | 1977-11-22 | Insecticide composition |
Country Status (20)
Country | Link |
---|---|
JP (1) | JPS54119035A (en) |
AT (1) | AT362617B (en) |
AU (1) | AU518341B2 (en) |
BE (1) | BE861000A (en) |
CA (1) | CA1096771A (en) |
CH (1) | CH625121A5 (en) |
DE (1) | DE2752140C2 (en) |
DK (1) | DK146112C (en) |
ES (1) | ES464354A1 (en) |
FR (1) | FR2371190A1 (en) |
GB (1) | GB1593601A (en) |
GR (1) | GR70301B (en) |
LU (1) | LU78565A1 (en) |
NL (1) | NL188555C (en) |
NO (1) | NO149718C (en) |
NZ (1) | NZ185745A (en) |
OA (1) | OA08256A (en) |
PT (1) | PT67304B (en) |
SE (1) | SE7713126L (en) |
ZA (1) | ZA776910B (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0191236A1 (en) * | 1985-01-16 | 1986-08-20 | Ataron Development (1985) Ltd. | Insecticidal compositions |
US5288483A (en) * | 1990-04-18 | 1994-02-22 | The Procter & Gamble Company | Anti-lice treatment compositions |
US5292504A (en) * | 1990-04-18 | 1994-03-08 | The Procter & Gamble Company | Anti-lice treatment compositions |
GB2347082A (en) * | 1999-02-24 | 2000-08-30 | Margaret Mary Seale | Treatment or prevention of parasitic infection using acetic acid |
GB2355404A (en) * | 1999-08-20 | 2001-04-25 | Polyatomic Apheresis Res Ltd | Vinegar for treating parasites |
WO2001032133A2 (en) * | 1999-11-05 | 2001-05-10 | Nature Plus Inc. | Improved nit removal product |
WO2001060163A2 (en) | 2000-02-17 | 2001-08-23 | Ecosmart Technologies, Inc. | Plant essential oils cointaining pediculicidal compositions |
WO2003045145A1 (en) * | 2001-10-12 | 2003-06-05 | Natalie Fresia Lubric | Method and composition for treating vermin |
WO2007056813A1 (en) * | 2005-11-18 | 2007-05-24 | Wild Child | Pediculicide/ovicide composition |
EP2603077A1 (en) * | 2010-06-08 | 2013-06-19 | Sequent Scientific Limited | Herbal topical formulation |
US8877219B2 (en) | 1998-07-28 | 2014-11-04 | Ecosmart Technologies, Inc. | Pesticidal compositions containing rosemary oil and wintergreen oil |
WO2020091606A1 (en) * | 2018-11-02 | 2020-05-07 | Inakva As | Composition and method to remove parasites from fish and to prevent or treat infestation or infection of parasites on fish |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2553664A1 (en) * | 1983-10-25 | 1985-04-26 | Charnay Sylvie | Composition based on essential oils from plants, for destroying lice and nits |
AU602144B2 (en) * | 1986-05-08 | 1990-10-04 | R & C Products Pty Limited | Animal repellant composition and method |
JPH01149402U (en) * | 1988-04-07 | 1989-10-17 | ||
JPH0211105U (en) * | 1988-07-04 | 1990-01-24 | ||
JPH02115107A (en) * | 1988-10-22 | 1990-04-27 | Matsushita Electric Works Ltd | Antibiotic agent |
US5227163A (en) * | 1991-01-18 | 1993-07-13 | Clilco, Ltd. | Lice-repellant compositions |
AU659625B2 (en) * | 1991-01-18 | 1995-05-25 | Clilco, Ltd. | Lice-repellant compositions |
WO1994016665A2 (en) * | 1993-01-25 | 1994-08-04 | Seleznev, Alexandr Georgievich | Agent to combat lice infestation |
FR2732591B1 (en) * | 1995-04-07 | 1997-06-13 | Benwaiche Joseph | PEST CONTROL SHAMPOO |
DE19631596A1 (en) * | 1996-08-05 | 1998-02-12 | Henkel Kgaa | Washing process |
FR2759546A1 (en) * | 1997-02-19 | 1998-08-21 | Soc Et De Rech De Travaux D Or | Use of citronella components as insecticides |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1589866A (en) * | 1924-11-17 | 1926-06-22 | Siegler Edouard Horace | Insecticide and process of preparing the same |
US2788308A (en) * | 1953-07-07 | 1957-04-09 | Irving L Ochs | Topical non-aqueous acetic compositions |
DE1105549B (en) * | 1957-07-06 | 1961-04-27 | Johannes Roedger Dr Med | Disinfecting detergents and cleaning agents |
NL279632A (en) * | 1962-02-09 | 1964-11-25 | ||
US3650964A (en) * | 1968-05-13 | 1972-03-21 | Basf Wyandotte Corp | Low foam anionic acid sanitizer compositions |
GB1249674A (en) * | 1968-11-28 | 1971-10-13 | Exxon Research Engineering Co | Novel agricultural compositions and leaf-desiccating method |
GB1438945A (en) * | 1972-06-15 | 1976-06-09 | Nat Res Dev | Control of fungi |
GB1438946A (en) * | 1972-06-15 | 1976-06-09 | Nat Res Dev | Control of fungi |
DD111633A1 (en) * | 1974-01-16 | 1975-03-05 | ||
US3969258A (en) * | 1974-10-10 | 1976-07-13 | Pennwalt Corporation | Low foaming acid-anionic surfactant sanitizer compositions |
-
1976
- 1976-11-22 FR FR7635121A patent/FR2371190A1/en active Granted
-
1977
- 1977-11-18 ZA ZA00776910A patent/ZA776910B/en unknown
- 1977-11-21 BE BE1008527A patent/BE861000A/en not_active IP Right Cessation
- 1977-11-21 PT PT67304A patent/PT67304B/en unknown
- 1977-11-21 GR GR54846A patent/GR70301B/el unknown
- 1977-11-21 SE SE7713126A patent/SE7713126L/en not_active Application Discontinuation
- 1977-11-21 NO NO773986A patent/NO149718C/en unknown
- 1977-11-22 JP JP13952777A patent/JPS54119035A/en active Granted
- 1977-11-22 CA CA291,442A patent/CA1096771A/en not_active Expired
- 1977-11-22 GB GB48564/77A patent/GB1593601A/en not_active Expired
- 1977-11-22 DK DK517577A patent/DK146112C/en not_active IP Right Cessation
- 1977-11-22 CH CH1425377A patent/CH625121A5/en not_active IP Right Cessation
- 1977-11-22 NL NLAANVRAGE7712875,A patent/NL188555C/en not_active IP Right Cessation
- 1977-11-22 LU LU78565A patent/LU78565A1/xx unknown
- 1977-11-22 NZ NZ185745A patent/NZ185745A/en unknown
- 1977-11-22 AU AU30837/77A patent/AU518341B2/en not_active Expired
- 1977-11-22 DE DE2752140A patent/DE2752140C2/en not_active Expired - Lifetime
- 1977-11-22 AT AT834877A patent/AT362617B/en not_active IP Right Cessation
- 1977-11-22 ES ES464354A patent/ES464354A1/en not_active Expired
- 1977-11-23 OA OA56323A patent/OA08256A/en unknown
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0191236A1 (en) * | 1985-01-16 | 1986-08-20 | Ataron Development (1985) Ltd. | Insecticidal compositions |
US5288483A (en) * | 1990-04-18 | 1994-02-22 | The Procter & Gamble Company | Anti-lice treatment compositions |
US5292504A (en) * | 1990-04-18 | 1994-03-08 | The Procter & Gamble Company | Anti-lice treatment compositions |
US9497974B2 (en) | 1998-07-28 | 2016-11-22 | Kittrich Corporation | Pesticidal compositions and methods for using same |
US9247751B2 (en) | 1998-07-28 | 2016-02-02 | Kittrich Corporation | Pesticidal compositions containing rosemary oil and wintergreen oil |
US8877219B2 (en) | 1998-07-28 | 2014-11-04 | Ecosmart Technologies, Inc. | Pesticidal compositions containing rosemary oil and wintergreen oil |
GB2347082A (en) * | 1999-02-24 | 2000-08-30 | Margaret Mary Seale | Treatment or prevention of parasitic infection using acetic acid |
GB2355404A (en) * | 1999-08-20 | 2001-04-25 | Polyatomic Apheresis Res Ltd | Vinegar for treating parasites |
WO2001032133A2 (en) * | 1999-11-05 | 2001-05-10 | Nature Plus Inc. | Improved nit removal product |
WO2001032133A3 (en) * | 1999-11-05 | 2001-11-01 | Nature Plus Inc | Improved nit removal product |
US6969522B2 (en) | 2000-02-17 | 2005-11-29 | Ecosmart Technologies, Inc. | Pesticidal compositions containing plant essential oils against human body louse |
US6974584B2 (en) | 2000-02-17 | 2005-12-13 | Ecosmart Technologies, Inc. | Pesticidal compositions containing plant essential oils against human body louse |
WO2001060163A3 (en) * | 2000-02-17 | 2002-02-07 | Ecosmart Technologies Inc | Plant essential oils cointaining pediculicidal compositions |
WO2001060163A2 (en) | 2000-02-17 | 2001-08-23 | Ecosmart Technologies, Inc. | Plant essential oils cointaining pediculicidal compositions |
WO2003045145A1 (en) * | 2001-10-12 | 2003-06-05 | Natalie Fresia Lubric | Method and composition for treating vermin |
WO2007056813A1 (en) * | 2005-11-18 | 2007-05-24 | Wild Child | Pediculicide/ovicide composition |
AU2006315084B2 (en) * | 2005-11-18 | 2013-01-24 | Symbion Pty Ltd | Pediculicide/ovicide composition |
US9955695B2 (en) | 2005-11-18 | 2018-05-01 | Wild Child | Pediculicide/ovicide composition |
EP2603077A1 (en) * | 2010-06-08 | 2013-06-19 | Sequent Scientific Limited | Herbal topical formulation |
EP2603077A4 (en) * | 2010-06-08 | 2014-03-19 | Sequent Scient Ltd | Herbal topical formulation |
WO2020091606A1 (en) * | 2018-11-02 | 2020-05-07 | Inakva As | Composition and method to remove parasites from fish and to prevent or treat infestation or infection of parasites on fish |
GB2593319A (en) * | 2018-11-02 | 2021-09-22 | Inakva As | Composition and method to remove parasites from fish and to prevent or treat infestation or infection of parasites on fish |
GB2593319B (en) * | 2018-11-02 | 2023-02-15 | Inakva As | Composition and method to remove parasites from fish and to prevent or treat infestation or infection of parasites on fish |
Also Published As
Publication number | Publication date |
---|---|
FR2371190A1 (en) | 1978-06-16 |
AU3083777A (en) | 1979-05-31 |
AU518341B2 (en) | 1981-09-24 |
NO149718C (en) | 1984-06-13 |
BE861000A (en) | 1978-05-22 |
LU78565A1 (en) | 1978-04-20 |
ZA776910B (en) | 1978-09-27 |
NO149718B (en) | 1984-03-05 |
PT67304A (en) | 1977-12-01 |
OA08256A (en) | 1987-10-30 |
NL188555B (en) | 1992-03-02 |
GR70301B (en) | 1982-09-06 |
DK146112C (en) | 1983-11-28 |
JPS6113443B2 (en) | 1986-04-14 |
ES464354A1 (en) | 1978-12-01 |
AT362617B (en) | 1981-06-10 |
DE2752140C2 (en) | 1994-02-10 |
PT67304B (en) | 1979-04-20 |
JPS54119035A (en) | 1979-09-14 |
CA1096771A (en) | 1981-03-03 |
CH625121A5 (en) | 1981-09-15 |
NO773986L (en) | 1978-05-23 |
NZ185745A (en) | 1980-08-26 |
DK146112B (en) | 1983-07-04 |
NL188555C (en) | 1992-08-03 |
DK517577A (en) | 1978-05-23 |
ATA834877A (en) | 1980-10-15 |
SE7713126L (en) | 1978-05-23 |
FR2371190B1 (en) | 1981-06-19 |
DE2752140A1 (en) | 1978-05-24 |
NL7712875A (en) | 1978-05-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
429A | Application made for amendment of specification (sect. 29/1949) | ||
429H | Application (made) for amendment of specification now open to opposition (sect. 29/1949) | ||
429D | Case decided by the comptroller ** specification amended (sect. 29/1949) | ||
PS | Patent sealed [section 19, patents act 1949] | ||
SP | Amendment (slips) printed | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19971121 |