GB1579934A - Skin-care cosmetic products - Google Patents

Skin-care cosmetic products Download PDF

Info

Publication number
GB1579934A
GB1579934A GB42686/76A GB4268676A GB1579934A GB 1579934 A GB1579934 A GB 1579934A GB 42686/76 A GB42686/76 A GB 42686/76A GB 4268676 A GB4268676 A GB 4268676A GB 1579934 A GB1579934 A GB 1579934A
Authority
GB
United Kingdom
Prior art keywords
oil
water
polymer
care product
skin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB42686/76A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beecham Group PLC
Original Assignee
Beecham Group PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beecham Group PLC filed Critical Beecham Group PLC
Priority to GB42686/76A priority Critical patent/GB1579934A/en
Priority to ES456212A priority patent/ES456212A1/en
Priority to ZA00773115A priority patent/ZA773115B/en
Priority to DE19772723682 priority patent/DE2723682A1/en
Priority to IT49596/77A priority patent/IT1079696B/en
Priority to AU25676/77A priority patent/AU514893B2/en
Priority to FR7717003A priority patent/FR2367486A1/en
Priority to CA281,584A priority patent/CA1099644A/en
Publication of GB1579934A publication Critical patent/GB1579934A/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241Containing particulates characterized by their shape and/or structure
    • A61K8/025Explicitly spheroidal or spherical shape
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8117Homopolymers or copolymers of aromatic olefines, e.g. polystyrene; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60Particulates further characterized by their structure or composition
    • A61K2800/65Characterized by the composition of the particulate/core
    • A61K2800/654The particulate/core comprising macromolecular material

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Description

(54) SKIN-CARE COSMETIC PRODUCTS (71) We, BEECHAM GROUP LIMITED, a British Company of Beecham House, Great West Road, Brentford, Middlesex, do hereby declare the invention for which we pray that a patent may be granted to us and the method by which it is to be performed, to be particularly described in and by the following statement:- This invention relates to a skin-care product of cream-like or lotion consistency, having a high water content and containing tiny polymer particles.
The product may be used as a moisturising cream or lotion and has the advantage of leaving the skin with a smooth feel.
Moisturising creams and lotions are widely used as skin cosmetics. They are generally unpigmented perfumed oil-in-water emulsions (or, less commonly, waterin-oil emulsions) with a relatively high water content of from about 6(w90% by weight. Such creams are absorbed by the upper layers of skin cells, swelling them to some extent, but otherwise leaving essentially no residual effect on the skin other than a slight perfume. They differ from so-called vanishing creams in that they contain essentially no free fatty acid.
Powder products have traditionally been used for skin smoothing purposes, the powder filling pores and fine wrinkles on the skin surface. With the advent of polymer technology, proposals were made to substitute polymer particles for the powders, such as talc, used in these products. Specifications 774029, 818425, 1059970, 1093108, 1141994 and 1202796 all refer to the possible use of polymer particles in cosmetics.
During the course of our investigations into the use of polymer particles in moisturising creams or lotions we found that spherical or substantially spherical particles in the range 5 to 15 microns could be incorporated in amounts from about 3% to about 10% by weight of the cream or lotion without adversely affecting the stability and other desirable properties. Moreover, despite the very small amount of polymer present, the resulting product rendered the skin particularly smooth and silky.
Accordingly, the present invention provides a skin-care product comprising an unpigmented oil-in-water (or water-in-oil) emulsion containing from 6090% by weight of water and having dispersed therein from 3 to 10% by weight of substantially spherical synthetic polymer or copolymer particles having an average particle size in the range 5 to 15 microns, the oil being a non-volatile oil, as herein defined.
As used herein, the term "non volatile oil" means an oil (including viscous or semi-solid liquids) which, when applied as a thin film on a surface maintained at 370C, does not evaporate to an extent greater than 10% by weight of the applied quantity in a period of 3 hours. Examples include mineral oil and petroleum jelly.
Preferably the product should contain a perfume, and preferably there should be substantially no free fatty acid present.
Usually the product will contain from 3 to 5% by weight of the polymer or copolymer particles.
Preferably the polymer or copolymer particles shall have an average size of from 5 to 7 microns.
Preferably, substantially none of the polymer or copolymer particles should exceed about 50 microns, and best results are achieved when there are substantially no particles of a size greater than 15 microns.
The polymer or copolymer particles should preferably not swell to any great extent in water or the oil used in the product. Within this limitation cross-linked polystyrene or polymethyl methacrylate microspheres would be suitable. However, the preferred polymer is polyethylene.
The following are Examples of the formulae of certain moisturising creams and lotions according to the invention: Moisturising Lotion (oil-in-water) Formula % w/w % w/w Mineral Oil 20.00 20.00 Stearic Acid 4.00 4.00 Triethanolamine 1.30 1.30 Preservatives qs qs Fragrance qs qs Distilled water 71.70 65.70 *Polymist B-6 3.00 9.00 100.00 100.00 Moisturising Cream (water-in-oil) Formula % w/w % w/w Mineral Oil 22.00 22.00 Beeswax 5.00 5.00 Petroleum jelly 10.00 10.00 Cetyl alcohol 2.00 2.00 Borax 0.50 0.50 Magnesium Sulphate 0.20 0.20 Preservatives qs qs Fragrance qs qs *Polymist B-12 3.00 9.00 Distilled water 57.30 51.30 100.00 100.00 *Polymist is a Trade Mark of Allied Chemicals; Station House, Stamford New Road, Altrincham, Cheshire WA16 IEP, England.
Polymist B-6 and B-12 are high density (0.96 gm/cc by ASTM D-1505) polyethylene microspheres having an average particle size of 6y and 12,u respectively, a particle size range of from 212y and 224y respectively with less than 2% and about 50% respectively of the particles larger than 10,u.
WHAT WE CLAIM IS: 1. A skin-care product comprising an unpigmented oil-in-water (or water-inoil) emulsion containing from 60-90% by weight of water and having dispersed therein from 3 to 10% by weight of substantially spherical synthetic polymer or copolymer particles having an average particle size in the range 5 to 15 microns, the oil being a non-volatile oil as herein defined.
2. A skin care product as claimed in claim 1 including a perfume and containing substantially no free fatty acid.
3. A skin care product as claimed in claim 1 or claim 2 containing from 3 to 5% by weight of the polymer or copolymer particles.
4. A skin care product as claimed in any one of the preceding claims wherein substantially none of the polymer or copolymer particles have a particle size greater than 15 microns.
5. A skin care product as claimed in any one of the preceding claims wherein the polymer or copolymer particles are polyethylene, or cross-linked polystyrene or polymethylmethacrylate microspheres.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (5)

**WARNING** start of CLMS field may overlap end of DESC **. extent in water or the oil used in the product. Within this limitation cross-linked polystyrene or polymethyl methacrylate microspheres would be suitable. However, the preferred polymer is polyethylene. The following are Examples of the formulae of certain moisturising creams and lotions according to the invention: Moisturising Lotion (oil-in-water) Formula % w/w % w/w Mineral Oil 20.00 20.00 Stearic Acid 4.00 4.00 Triethanolamine 1.30 1.30 Preservatives qs qs Fragrance qs qs Distilled water 71.70 65.70 *Polymist B-6 3.00 9.00 100.00 100.00 Moisturising Cream (water-in-oil) Formula % w/w % w/w Mineral Oil 22.00 22.00 Beeswax 5.00 5.00 Petroleum jelly 10.00 10.00 Cetyl alcohol 2.00 2.00 Borax 0.50 0.50 Magnesium Sulphate 0.20 0.20 Preservatives qs qs Fragrance qs qs *Polymist B-12 3.00 9.00 Distilled water 57.30 51.30 100.00 100.00 *Polymist is a Trade Mark of Allied Chemicals; Station House, Stamford New Road, Altrincham, Cheshire WA16 IEP, England. Polymist B-6 and B-12 are high density (0.96 gm/cc by ASTM D-1505) polyethylene microspheres having an average particle size of 6y and 12,u respectively, a particle size range of from 212y and 224y respectively with less than 2% and about 50% respectively of the particles larger than 10,u. WHAT WE CLAIM IS:
1. A skin-care product comprising an unpigmented oil-in-water (or water-inoil) emulsion containing from 60-90% by weight of water and having dispersed therein from 3 to 10% by weight of substantially spherical synthetic polymer or copolymer particles having an average particle size in the range 5 to 15 microns, the oil being a non-volatile oil as herein defined.
2. A skin care product as claimed in claim 1 including a perfume and containing substantially no free fatty acid.
3. A skin care product as claimed in claim 1 or claim 2 containing from 3 to 5% by weight of the polymer or copolymer particles.
4. A skin care product as claimed in any one of the preceding claims wherein substantially none of the polymer or copolymer particles have a particle size greater than 15 microns.
5. A skin care product as claimed in any one of the preceding claims wherein the polymer or copolymer particles are polyethylene, or cross-linked polystyrene or polymethylmethacrylate microspheres.
GB42686/76A 1976-10-14 1976-10-14 Skin-care cosmetic products Expired GB1579934A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
GB42686/76A GB1579934A (en) 1976-10-14 1976-10-14 Skin-care cosmetic products
ES456212A ES456212A1 (en) 1976-10-14 1977-02-23 Skin-care cosmetic products
ZA00773115A ZA773115B (en) 1976-10-14 1977-05-24 Cosmetic creams
DE19772723682 DE2723682A1 (en) 1976-10-14 1977-05-25 SKIN CARE PRODUCTS
IT49596/77A IT1079696B (en) 1976-10-14 1977-05-27 SKIN CARE PRODUCT
AU25676/77A AU514893B2 (en) 1976-10-14 1977-05-31 Cosmetic creams
FR7717003A FR2367486A1 (en) 1976-10-14 1977-06-03 COSMETIC CREAM
CA281,584A CA1099644A (en) 1976-10-14 1977-06-28 Oil-water (or water-oil) emulsion containing synthetic polymer particles as skin care product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB42686/76A GB1579934A (en) 1976-10-14 1976-10-14 Skin-care cosmetic products

Publications (1)

Publication Number Publication Date
GB1579934A true GB1579934A (en) 1980-11-26

Family

ID=10425530

Family Applications (1)

Application Number Title Priority Date Filing Date
GB42686/76A Expired GB1579934A (en) 1976-10-14 1976-10-14 Skin-care cosmetic products

Country Status (8)

Country Link
AU (1) AU514893B2 (en)
CA (1) CA1099644A (en)
DE (1) DE2723682A1 (en)
ES (1) ES456212A1 (en)
FR (1) FR2367486A1 (en)
GB (1) GB1579934A (en)
IT (1) IT1079696B (en)
ZA (1) ZA773115B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5223559A (en) * 1991-02-28 1993-06-29 L'oreal Cosmetic composition capable of blurring skin defects
US5523079A (en) * 1990-12-13 1996-06-04 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Hair styling composition
WO2000007548A1 (en) * 1998-08-01 2000-02-17 Beiersdorf Ag Finely dispersed emulsifier-free systems of the oil-in-water and water-in-oil type
WO2001062224A1 (en) * 2000-02-21 2001-08-30 Block Drug Company, Inc. Stabilized emulsion compositions
US6843982B1 (en) 1994-01-26 2005-01-18 L'oreal Anhydrous cosmetic or dermatological composition containing the combination of a silicone oil and a wax made from an ethylene homopolymer or copolymer
US6924256B2 (en) 2002-11-08 2005-08-02 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Liquid cleansing composition having simultaneous exfoliating and moisturizing properties
US20160067166A1 (en) * 2013-05-16 2016-03-10 Dsm Ip Assets B.V. Cosmetic composition comprising a natural organic oil and polymethylmethacrylate particles

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1579935A (en) * 1976-12-09 1980-11-26 Beecham Group Ltd Cosmetic products for treating the skin
LU78001A1 (en) * 1977-08-22 1979-05-23 Oreal NEW COSMETIC COMPOSITIONS IN THE FORM OF WATER-IN-OIL OR OIL-IN-WATER EMULSIONS
US4255452A (en) * 1979-03-19 1981-03-10 Veney Ruby G Cosmetic composition
LU85746A1 (en) * 1985-01-28 1986-08-04 Oreal COSMETIC FILTERING COMPOSITION CONTAINING A UV FILTER ASSOCIATED WITH A POLYMER OBTAINED BY SEQUENTIAL EMULSION POLYMERIZATION AND ITS USE FOR THE PROTECTION OF THE HUMAN SKIN AGAINST ULTRAVIOLET RADIATION
US5194262A (en) * 1990-10-22 1993-03-16 Revlon Consumer Products Corporation Encapsulated antiperspirant salts and deodorant/antiperspirants
US5176903A (en) * 1990-12-13 1993-01-05 Revlon Consumer Products Corporation Antiperspirant/deodorant containing microcapsules
JPH04295417A (en) * 1991-01-16 1992-10-20 Estee Lauder Inc Cosmetic composition containing styrene/ethylene/ propylene copolymer and method of using same

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB774029A (en) * 1954-03-31 1957-05-01 Bofors Ab Method of producing a base material for powders and liniments to be used on human skin
DE1492101A1 (en) * 1964-12-18 1969-04-03 Pfizer & Co C Cosmetic preparation
FR1489256A (en) * 1965-06-21 1967-07-21 Ici Ltd Cosmetic preparation
GB1093108A (en) * 1965-06-21 1967-11-29 Ici Ltd Cosmetic polyester preparation
GB1141994A (en) * 1966-02-07 1969-02-05 Permutit Co Ltd Powder-containing preparations for application to the human skin
GB1110240A (en) * 1967-07-27 1968-04-18 Pfizer & Co C Cosmetic preparation
GB1202796A (en) * 1968-04-01 1970-08-19 Ici Ltd Compacted linear polyester powder
LU57903A1 (en) * 1969-02-04 1970-08-04
BE754514A (en) * 1969-08-07 1971-01-18 Blendax Werke Schneider Co COSMETIC MIDDELS
GB1351903A (en) * 1971-06-11 1974-05-01 Fmc Corp Cosmetic and pharmaceutical compositions
FR2208642A1 (en) * 1972-12-05 1974-06-28 Shiseido Co Ltd Two-phase liquid cosmetic preparation - contg. oil water, a water- and oil-miscible organic liquid and finely divided insoluble solid particles

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5523079A (en) * 1990-12-13 1996-06-04 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Hair styling composition
US5223559A (en) * 1991-02-28 1993-06-29 L'oreal Cosmetic composition capable of blurring skin defects
US6843982B1 (en) 1994-01-26 2005-01-18 L'oreal Anhydrous cosmetic or dermatological composition containing the combination of a silicone oil and a wax made from an ethylene homopolymer or copolymer
WO2000007548A1 (en) * 1998-08-01 2000-02-17 Beiersdorf Ag Finely dispersed emulsifier-free systems of the oil-in-water and water-in-oil type
US6620407B1 (en) 1998-08-01 2003-09-16 Beiersdorf Ag Finely dispersed emulsifier-free systems of the oil-in-water and water-in-oil type
WO2001062224A1 (en) * 2000-02-21 2001-08-30 Block Drug Company, Inc. Stabilized emulsion compositions
US6924256B2 (en) 2002-11-08 2005-08-02 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Liquid cleansing composition having simultaneous exfoliating and moisturizing properties
US20160067166A1 (en) * 2013-05-16 2016-03-10 Dsm Ip Assets B.V. Cosmetic composition comprising a natural organic oil and polymethylmethacrylate particles

Also Published As

Publication number Publication date
AU2567677A (en) 1978-12-07
CA1099644A (en) 1981-04-21
ES456212A1 (en) 1978-05-01
FR2367486B1 (en) 1981-05-08
IT1079696B (en) 1985-05-13
DE2723682C2 (en) 1987-04-09
FR2367486A1 (en) 1978-05-12
DE2723682A1 (en) 1978-04-20
ZA773115B (en) 1978-04-26
AU514893B2 (en) 1981-02-05

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19930603