GB1571209A - Isotope separation process - Google Patents
Isotope separation process Download PDFInfo
- Publication number
- GB1571209A GB1571209A GB19896/78A GB1989678A GB1571209A GB 1571209 A GB1571209 A GB 1571209A GB 19896/78 A GB19896/78 A GB 19896/78A GB 1989678 A GB1989678 A GB 1989678A GB 1571209 A GB1571209 A GB 1571209A
- Authority
- GB
- United Kingdom
- Prior art keywords
- laser
- compound
- isotope
- molecules
- excited molecules
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 68
- 230000008569 process Effects 0.000 title claims description 67
- 238000005372 isotope separation Methods 0.000 title claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 39
- -1 uranyl compound Chemical class 0.000 claims description 38
- 230000005855 radiation Effects 0.000 claims description 26
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 22
- 239000003446 ligand Substances 0.000 claims description 20
- 238000000926 separation method Methods 0.000 claims description 20
- 230000009102 absorption Effects 0.000 claims description 19
- 238000010521 absorption reaction Methods 0.000 claims description 19
- 229910052770 Uranium Inorganic materials 0.000 claims description 17
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 17
- 239000012808 vapor phase Substances 0.000 claims description 13
- 230000007704 transition Effects 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 230000001678 irradiating effect Effects 0.000 claims description 10
- 238000000862 absorption spectrum Methods 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- 230000000155 isotopic effect Effects 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- 230000008016 vaporization Effects 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 230000003993 interaction Effects 0.000 claims description 2
- 230000002441 reversible effect Effects 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims 1
- 125000005289 uranyl group Chemical group 0.000 description 40
- 241000894007 species Species 0.000 description 11
- WYICGPHECJFCBA-UHFFFAOYSA-N dioxouranium(2+) Chemical compound O=[U+2]=O WYICGPHECJFCBA-UHFFFAOYSA-N 0.000 description 9
- 230000005284 excitation Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 150000003671 uranium compounds Chemical class 0.000 description 3
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 229910052768 actinide Inorganic materials 0.000 description 2
- 150000001255 actinides Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 238000003682 fluorination reaction Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- 0 *CCC*CCC*=NCNC* Chemical compound *CCC*CCC*=NCNC* 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 240000007591 Tilia tomentosa Species 0.000 description 1
- 150000001224 Uranium Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 229910001632 barium fluoride Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- MXCPYJZDGPQDRA-UHFFFAOYSA-N dialuminum;2-acetyloxybenzoic acid;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3].CC(=O)OC1=CC=CC=C1C(O)=O MXCPYJZDGPQDRA-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000005594 diketone group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940093499 ethyl acetate Drugs 0.000 description 1
- 235000019439 ethyl acetate Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 238000005369 laser isotope separation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- ILVXOBCQQYKLDS-UHFFFAOYSA-N pyridine N-oxide Chemical compound [O-][N+]1=CC=CC=C1 ILVXOBCQQYKLDS-UHFFFAOYSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- TXBBUSUXYMIVOS-UHFFFAOYSA-N thenoyltrifluoroacetone Chemical compound FC(F)(F)C(=O)CC(=O)C1=CC=CS1 TXBBUSUXYMIVOS-UHFFFAOYSA-N 0.000 description 1
- 229910002007 uranyl nitrate Inorganic materials 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 239000013598 vector Substances 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/34—Separation by photochemical methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/77—Preparation of chelates of aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biophysics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lasers (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH746977A CH618956A5 (en) | 1978-01-01 | 1978-01-01 | A composition containing a uranyl ion |
| FR7815866A FR2413120A2 (fr) | 1978-01-01 | 1978-05-26 | Procede de separation d'isotopes d'uranium et compose utilise dans ce procede |
| NL7805776A NL7805776A (nl) | 1978-01-01 | 1978-05-26 | Werkwijze voor het scheiden van isotopen; uranylverbindingen; werkwijze voor de bereiding van uranylverbindingen. |
| AU36548/78A AU526806B2 (en) | 1978-01-01 | 1978-05-26 | Isotope separation process |
| GB19896/78A GB1571209A (en) | 1978-01-01 | 1978-05-31 | Isotope separation process |
| BE2057025A BE867647A (nl) | 1978-01-01 | 1978-05-31 | Werkwijze voor het scheiden van isotopen, uranylverbindingen, werkwijze voor de bereiding van uranylverbindingen |
| DE19782826226 DE2826226A1 (de) | 1978-01-01 | 1978-06-15 | Isotopentrennverfahren |
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH746977A CH618956A5 (en) | 1978-01-01 | 1978-01-01 | A composition containing a uranyl ion |
| FR7815866A FR2413120A2 (fr) | 1978-01-01 | 1978-05-26 | Procede de separation d'isotopes d'uranium et compose utilise dans ce procede |
| NL7805776A NL7805776A (nl) | 1978-01-01 | 1978-05-26 | Werkwijze voor het scheiden van isotopen; uranylverbindingen; werkwijze voor de bereiding van uranylverbindingen. |
| AU36548/78A AU526806B2 (en) | 1978-01-01 | 1978-05-26 | Isotope separation process |
| GB19896/78A GB1571209A (en) | 1978-01-01 | 1978-05-31 | Isotope separation process |
| BE2057025A BE867647A (nl) | 1978-01-01 | 1978-05-31 | Werkwijze voor het scheiden van isotopen, uranylverbindingen, werkwijze voor de bereiding van uranylverbindingen |
| DE19782826226 DE2826226A1 (de) | 1978-01-01 | 1978-06-15 | Isotopentrennverfahren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1571209A true GB1571209A (en) | 1980-07-09 |
Family
ID=27560559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB19896/78A Expired GB1571209A (en) | 1978-01-01 | 1978-05-31 | Isotope separation process |
Country Status (7)
| Country | Link |
|---|---|
| AU (1) | AU526806B2 (me) |
| BE (1) | BE867647A (me) |
| CH (1) | CH618956A5 (me) |
| DE (1) | DE2826226A1 (me) |
| FR (1) | FR2413120A2 (me) |
| GB (1) | GB1571209A (me) |
| NL (1) | NL7805776A (me) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU6011980A (en) * | 1979-12-21 | 1981-06-25 | Exxon Research And Engineering Company | Separation of isotopes |
| US4357307A (en) * | 1979-12-21 | 1982-11-02 | Exxon Research And Engineering Company | Method of separating isotopes in which a compounding of selectivity is achieved by limiting the timing of the collection step |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3951768A (en) * | 1971-02-05 | 1976-04-20 | Karl Gurs | Method of separating isotopes |
| US4097384A (en) * | 1976-03-22 | 1978-06-27 | Northwestern University | Process for uranium isotope separation |
| DE2726979C2 (de) * | 1977-06-15 | 1985-03-07 | Exxon Research and Engineering Co., Linden, N.J. | Verfahren zur Trennung von Uranisotopen und flüchtige Uranylverbindungen zu dessen Durchführung |
-
1978
- 1978-01-01 CH CH746977A patent/CH618956A5/de not_active IP Right Cessation
- 1978-05-26 NL NL7805776A patent/NL7805776A/xx not_active Application Discontinuation
- 1978-05-26 AU AU36548/78A patent/AU526806B2/en not_active Expired
- 1978-05-26 FR FR7815866A patent/FR2413120A2/fr active Granted
- 1978-05-31 GB GB19896/78A patent/GB1571209A/en not_active Expired
- 1978-05-31 BE BE2057025A patent/BE867647A/xx unknown
- 1978-06-15 DE DE19782826226 patent/DE2826226A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| FR2413120B2 (me) | 1983-05-27 |
| NL7805776A (nl) | 1979-11-28 |
| FR2413120A2 (fr) | 1979-07-27 |
| DE2826226A1 (de) | 1979-12-20 |
| AU3654878A (en) | 1979-01-04 |
| CH618956A5 (en) | 1980-08-29 |
| AU526806B2 (en) | 1983-02-03 |
| BE867647A (nl) | 1978-11-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| 746 | Register noted 'licences of right' (sect. 46/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19940531 |