GB1561530A - Photoluminescent materials - Google Patents
Photoluminescent materials Download PDFInfo
- Publication number
- GB1561530A GB1561530A GB45374/76A GB4537476A GB1561530A GB 1561530 A GB1561530 A GB 1561530A GB 45374/76 A GB45374/76 A GB 45374/76A GB 4537476 A GB4537476 A GB 4537476A GB 1561530 A GB1561530 A GB 1561530A
- Authority
- GB
- United Kingdom
- Prior art keywords
- substance
- material according
- fluorescent
- phosphorescent
- phosphorescent substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title claims description 102
- 239000000126 substance Substances 0.000 claims description 115
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 63
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 43
- 239000005083 Zinc sulfide Substances 0.000 claims description 42
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 22
- 239000011230 binding agent Substances 0.000 claims description 19
- 239000000945 filler Substances 0.000 claims description 18
- 230000002085 persistent effect Effects 0.000 claims description 18
- 238000001228 spectrum Methods 0.000 claims description 17
- 238000000862 absorption spectrum Methods 0.000 claims description 16
- 238000000295 emission spectrum Methods 0.000 claims description 16
- 230000005540 biological transmission Effects 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 238000005424 photoluminescence Methods 0.000 claims description 9
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 9
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical group [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 claims description 8
- 229910052980 cadmium sulfide Inorganic materials 0.000 claims description 8
- 238000009472 formulation Methods 0.000 claims description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- SLIUAWYAILUBJU-UHFFFAOYSA-N pentacene Chemical compound C1=CC=CC2=CC3=CC4=CC5=CC=CC=C5C=C4C=C3C=C21 SLIUAWYAILUBJU-UHFFFAOYSA-N 0.000 claims description 6
- VUPXKQHLZATXTR-UHFFFAOYSA-N 2,4-diphenyl-1,3-oxazole Chemical compound C=1OC(C=2C=CC=CC=2)=NC=1C1=CC=CC=C1 VUPXKQHLZATXTR-UHFFFAOYSA-N 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- 230000005284 excitation Effects 0.000 claims description 5
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 5
- 229940043267 rhodamine b Drugs 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 4
- NJDNXYGOVLYJHP-UHFFFAOYSA-L disodium;2-(3-oxido-6-oxoxanthen-9-yl)benzoate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=CC(=O)C=C2OC2=CC([O-])=CC=C21 NJDNXYGOVLYJHP-UHFFFAOYSA-L 0.000 claims description 4
- 229920000609 methyl cellulose Polymers 0.000 claims description 4
- 239000001923 methylcellulose Substances 0.000 claims description 4
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005286 illumination Methods 0.000 claims description 3
- 230000003595 spectral effect Effects 0.000 claims description 3
- ACNUVXZPCIABEX-UHFFFAOYSA-N 3',6'-diaminospiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(N)C=C1OC1=CC(N)=CC=C21 ACNUVXZPCIABEX-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 230000009471 action Effects 0.000 claims description 2
- 230000008033 biological extinction Effects 0.000 claims description 2
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims description 2
- QSQIGGCOCHABAP-UHFFFAOYSA-N hexacene Chemical compound C1=CC=CC2=CC3=CC4=CC5=CC6=CC=CC=C6C=C5C=C4C=C3C=C21 QSQIGGCOCHABAP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 150000001491 aromatic compounds Chemical class 0.000 claims 3
- 239000006185 dispersion Substances 0.000 claims 1
- 125000005582 pentacene group Chemical group 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 229920003002 synthetic resin Polymers 0.000 claims 1
- 239000000057 synthetic resin Substances 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 description 12
- 239000004753 textile Substances 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000000470 constituent Substances 0.000 description 5
- 230000002688 persistence Effects 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000001429 visible spectrum Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- AGVJBLHVMNHENQ-UHFFFAOYSA-N Calcium sulfide Chemical compound [S-2].[Ca+2] AGVJBLHVMNHENQ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 206010034960 Photophobia Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- JJUVIJNHXOLHTM-UHFFFAOYSA-N [Zn].C1=CC=CC2=CC3=CC=CC=C3C=C21 Chemical compound [Zn].C1=CC=CC2=CC3=CC=CC=C3C=C21 JJUVIJNHXOLHTM-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 125000005577 anthracene group Chemical group 0.000 description 1
- ILNYDHOAOJZFFP-UHFFFAOYSA-N anthracene naphthalene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C12.C1=CC=CC2=CC3=CC=CC=C3C=C12.C1=CC=CC2=CC=CC=C12 ILNYDHOAOJZFFP-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- FRLJSGOEGLARCA-UHFFFAOYSA-N cadmium sulfide Chemical class [S-2].[Cd+2] FRLJSGOEGLARCA-UHFFFAOYSA-N 0.000 description 1
- CEKJAYFBQARQNG-UHFFFAOYSA-N cadmium zinc Chemical compound [Zn].[Cd] CEKJAYFBQARQNG-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 208000013469 light sensitivity Diseases 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- -1 polycyclic hydrocarbon Chemical class 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- XXCMBPUMZXRBTN-UHFFFAOYSA-N strontium sulfide Chemical compound [Sr]=S XXCMBPUMZXRBTN-UHFFFAOYSA-N 0.000 description 1
- IFLREYGFSNHWGE-UHFFFAOYSA-N tetracene Chemical compound C1=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C21 IFLREYGFSNHWGE-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/56—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing sulfur
- C09K11/562—Chalcogenides
- C09K11/565—Chalcogenides with zinc cadmium
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Luminescent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Electroluminescent Light Sources (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7533317A FR2329736A1 (fr) | 1975-10-31 | 1975-10-31 | Perfectionnement aux produits photoluminescents dans leur masse |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1561530A true GB1561530A (en) | 1980-02-20 |
Family
ID=9161863
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB45374/76A Expired GB1561530A (en) | 1975-10-31 | 1976-11-01 | Photoluminescent materials |
Country Status (16)
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4874188A (en) * | 1986-10-10 | 1989-10-17 | B.R.I.C.-Bureau De Recherche Pour L' Innovation Et La Convergence & Banque De France | Fiduciary or security object enabling visual or optical authentification |
| US5925287A (en) * | 1995-05-11 | 1999-07-20 | Cleanosol Ab | Fluorescing covering for roads, parking areas, etc. which fluoresces on illumination with ultra-violet light |
| WO2000027908A3 (en) * | 1998-11-10 | 2000-10-12 | M A Hannacolor A Division Of M | Daylight/nightglow colored phosphorescent plastic compositions and articles |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2908770A1 (de) * | 1979-03-06 | 1980-10-02 | Siemens Ag | Verfahren zur sammlung von licht und vorrichtung zur durchfuehrung eines solchen verfahrens |
| DE3434971A1 (de) * | 1984-09-24 | 1986-03-27 | Wakita Nenshi Co., Ltd., Bisai, Aichi | Lumineszierende faser |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3518205A (en) * | 1967-05-23 | 1970-06-30 | Sherwin Williams Co | Fluorescent pigment |
| FR2209005A2 (en) * | 1972-12-04 | 1974-06-28 | Gravisse Philippe | Textile materials rendered luminescent - by impregnating with clear and luminescent particles |
-
1975
- 1975-10-31 FR FR7533317A patent/FR2329736A1/fr active Granted
-
1976
- 1976-02-06 BE BE2054806A patent/BE838306A/xx not_active IP Right Cessation
- 1976-10-27 IT IT28767/76A patent/IT1121735B/it active
- 1976-10-28 NL NL7611969A patent/NL7611969A/xx not_active Application Discontinuation
- 1976-10-28 SE SE7612004A patent/SE427285B/xx unknown
- 1976-10-29 MX MX166851A patent/MX150155A/es unknown
- 1976-10-29 OA OA55970A patent/OA05469A/xx unknown
- 1976-10-29 NO NO763691A patent/NO146287C/no unknown
- 1976-10-29 GR GR52028A patent/GR61713B/el unknown
- 1976-10-29 CH CH1368276A patent/CH617958A5/fr not_active IP Right Cessation
- 1976-10-29 DE DE19762649686 patent/DE2649686A1/de active Granted
- 1976-10-29 CA CA264,745A patent/CA1086936A/fr not_active Expired
- 1976-10-29 DK DK490376A patent/DK490376A/da not_active Application Discontinuation
- 1976-10-29 BR BR7607276A patent/BR7607276A/pt unknown
- 1976-11-01 JP JP51131562A patent/JPS5257088A/ja active Pending
- 1976-11-01 GB GB45374/76A patent/GB1561530A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4874188A (en) * | 1986-10-10 | 1989-10-17 | B.R.I.C.-Bureau De Recherche Pour L' Innovation Et La Convergence & Banque De France | Fiduciary or security object enabling visual or optical authentification |
| US5925287A (en) * | 1995-05-11 | 1999-07-20 | Cleanosol Ab | Fluorescing covering for roads, parking areas, etc. which fluoresces on illumination with ultra-violet light |
| WO2000027908A3 (en) * | 1998-11-10 | 2000-10-12 | M A Hannacolor A Division Of M | Daylight/nightglow colored phosphorescent plastic compositions and articles |
| US6375864B1 (en) | 1998-11-10 | 2002-04-23 | M.A. Hannacolor, A Division Of M.A. Hanna Company | Daylight/nightglow colored phosphorescent plastic compositions and articles |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2649686C2 (enrdf_load_stackoverflow) | 1988-06-16 |
| FR2329736B1 (enrdf_load_stackoverflow) | 1980-08-08 |
| BE838306A (fr) | 1976-05-28 |
| DK490376A (da) | 1977-05-01 |
| GR61713B (en) | 1978-12-28 |
| SE427285B (sv) | 1983-03-21 |
| FR2329736A1 (fr) | 1977-05-27 |
| CH617958A5 (en) | 1980-06-30 |
| BR7607276A (pt) | 1977-09-13 |
| JPS5257088A (en) | 1977-05-11 |
| SE7612004L (sv) | 1977-05-01 |
| NL7611969A (nl) | 1977-05-03 |
| NO146287C (no) | 1982-09-01 |
| CA1086936A (fr) | 1980-10-07 |
| MX150155A (es) | 1984-03-29 |
| OA05469A (fr) | 1981-03-31 |
| DE2649686A1 (de) | 1977-05-05 |
| NO763691L (enrdf_load_stackoverflow) | 1977-05-03 |
| NO146287B (no) | 1982-05-24 |
| IT1121735B (it) | 1986-04-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |