GB1496927A - Regeneration of ruthenium catalyst - Google Patents
Regeneration of ruthenium catalystInfo
- Publication number
- GB1496927A GB1496927A GB6452/77A GB645277A GB1496927A GB 1496927 A GB1496927 A GB 1496927A GB 6452/77 A GB6452/77 A GB 6452/77A GB 645277 A GB645277 A GB 645277A GB 1496927 A GB1496927 A GB 1496927A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- zeolite
- regenerated
- aug
- polyhydric alcohols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title abstract 2
- 230000008929 regeneration Effects 0.000 title 1
- 238000011069 regeneration method Methods 0.000 title 1
- 229910052707 ruthenium Inorganic materials 0.000 title 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 abstract 1
- 229940084778 1,4-sorbitan Drugs 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229920002261 Corn starch Polymers 0.000 abstract 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract 1
- 229930195725 Mannitol Natural products 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 150000001720 carbohydrates Chemical class 0.000 abstract 1
- 235000014633 carbohydrates Nutrition 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000008120 corn starch Substances 0.000 abstract 1
- 239000000413 hydrolysate Substances 0.000 abstract 1
- 239000000594 mannitol Substances 0.000 abstract 1
- 235000010355 mannitol Nutrition 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000000600 sorbitol Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/90—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/068—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/26—Hexahydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/06—Glucose; Glucose-containing syrups obtained by saccharification of starch or raw materials containing starch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/12—Noble metals
- B01J29/126—Y-type faujasite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49896974A | 1974-08-20 | 1974-08-20 | |
| US05/520,926 US3963788A (en) | 1974-08-20 | 1974-11-05 | Polyhydric alcohol production using ruthenium zeolite catalyst |
| BE837201 | 1975-12-30 | ||
| BE163217A BE837201A (fr) | 1974-08-20 | 1975-12-30 | Procede de production de polyol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1496927A true GB1496927A (en) | 1978-01-05 |
Family
ID=27424651
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6452/77A Expired GB1496927A (en) | 1974-08-20 | 1975-08-19 | Regeneration of ruthenium catalyst |
| GB34429/75A Expired GB1496926A (en) | 1974-08-20 | 1975-08-19 | Polyhydric alcohol production using ruthenium zeolite catalyst |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB34429/75A Expired GB1496926A (en) | 1974-08-20 | 1975-08-19 | Polyhydric alcohol production using ruthenium zeolite catalyst |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3963788A (enExample) |
| JP (1) | JPS5143707A (enExample) |
| BE (1) | BE837201A (enExample) |
| BR (1) | BR7505206A (enExample) |
| CA (1) | CA1054160A (enExample) |
| CH (1) | CH614185A5 (enExample) |
| DE (1) | DE2536416A1 (enExample) |
| FR (1) | FR2282418A1 (enExample) |
| GB (2) | GB1496927A (enExample) |
| NL (1) | NL7509668A (enExample) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4177166A (en) * | 1976-11-05 | 1979-12-04 | Phillips Petroleum Company | Hydroalkylation composition and process for producing said composition |
| US4118434A (en) * | 1976-11-05 | 1978-10-03 | Phillips Petroleum Company | Hydroalkylation using multimetallic zeolite catalyst |
| US4173514A (en) * | 1977-06-02 | 1979-11-06 | Ici Americas Inc. | High mannitol process (enzymatic isomerization) |
| DE2831659A1 (de) * | 1978-07-19 | 1980-02-07 | Bayer Ag | Verfahren zur herstellung von polyalkoholen |
| EP0037137B1 (fr) * | 1980-03-18 | 1984-05-02 | Université de Liège | Procédé de réactivation d'un catalyseur, à base de métaux du groupe du platine, pour l'hydrogénation des sucres |
| DE3144320A1 (de) * | 1981-11-07 | 1983-05-19 | Henkel KGaA, 4000 Düsseldorf | "verfahren zur kontinuierlichen herstellung von mehrwertigen alkoholen" |
| US4430253A (en) | 1982-02-11 | 1984-02-07 | Ethyl Corporation | Sulfide-modified ruthenium catalyst |
| US4380680A (en) * | 1982-05-21 | 1983-04-19 | Uop Inc. | Method for hydrogenating aqueous solutions of carbohydrates |
| US4466907A (en) * | 1982-08-23 | 1984-08-21 | Shell Oil Company | Zeolite-ruthenium-borane catalyst composition |
| US4405499A (en) * | 1982-08-23 | 1983-09-20 | Shell Oil Company | Zeolite-ruthenium-borane catalyst composition |
| US4413152A (en) * | 1982-08-25 | 1983-11-01 | Uop Inc. | Hydrogenation in aqueous solutions |
| US4459419A (en) * | 1982-09-02 | 1984-07-10 | Ethyl Corporation | Hydrogenation process using cationic ruthenium-containing zeolite |
| US4510339A (en) * | 1983-01-12 | 1985-04-09 | Uop Inc. | Increasing catalyst lifetime in hydrogenation of a carbohydrate in aqueous solution |
| US4503274A (en) * | 1983-08-08 | 1985-03-05 | Uop Inc. | Ruthenium hydrogenation catalyst with increased activity |
| EP0137063B1 (en) * | 1983-10-08 | 1987-07-22 | Union Carbide Corporation | Bulk separation of polyhydric alcohols by selective adsorption on zeolitic molecular sieves |
| WO1986001743A1 (en) * | 1984-09-12 | 1986-03-27 | Commonwealth Scientific And Industrial Research Or | Composite catalyst of ruthenium on zeolite and a group vi and/or group viii metal on refractory |
| EP0329923B1 (en) * | 1988-02-22 | 1993-04-21 | Fina Research S.A. | Single-step catalytic process for the direct conversion of polysaccharides to polyhydric alcohols |
| US5026927A (en) * | 1989-11-16 | 1991-06-25 | The United States Of America As Represented By The United States Department Of Energy | Hydrocracking of carbohydrates making glycerol, glycols and other polyols |
| DE4023255A1 (de) * | 1990-07-21 | 1992-01-23 | Basf Ag | Verfahren zur herstellung von glykolen, insbesondere propylenglykol aus formaldehyd |
| FR2727980A1 (fr) * | 1994-12-07 | 1996-06-14 | Agrichimie Sa | Procede de fabrication d'une solution pure de sucres simples par hydrolyse d'au moins un sucre compose en presence d'un adsorbant selectif |
| US5866101A (en) * | 1997-07-22 | 1999-02-02 | Colgate Palmolive Company | Color stable anticalculus compostion |
| US6919446B1 (en) | 1998-01-20 | 2005-07-19 | Grain Processing Corp. | Reduced malto-oligosaccharides |
| KR100485358B1 (ko) * | 1998-01-20 | 2005-04-25 | 그레인 프로세싱 코포레이션 | 환원된 말토-올리고사카라이드 |
| US6780990B1 (en) | 1998-03-26 | 2004-08-24 | Spi Polyols, Inc. | Hydrogenated starch hydrolysate |
| US6380379B1 (en) | 1999-08-20 | 2002-04-30 | Grain Processing Corporation | Derivatized reduced malto-oligosaccharides |
| DE60029300D1 (de) | 1999-10-20 | 2006-08-24 | Grain Processing Corp | Zusammensetzungen, die reduziertes malto-oligosaccharid als konservierungsmittel enthalten |
| WO2001029164A1 (en) | 1999-10-20 | 2001-04-26 | Grain Processing Corporation | Reduced malto-oligosaccharide cleansing compositions |
| DE10128205A1 (de) * | 2001-06-11 | 2002-12-12 | Basf Ag | Ruthenium-Katalysatoren |
| DE10128203A1 (de) * | 2001-06-11 | 2002-12-12 | Basf Ag | Verfahren zur Herstellung von Sorbit |
| AU2003288219A1 (en) * | 2002-12-11 | 2004-06-30 | Basf Aktiengesellschaft | Continuous method for the production of sugar alcohols |
| WO2005021475A1 (en) * | 2003-09-03 | 2005-03-10 | Sk Corporation | Method for preparing sugar alcohols by catalytic hydrogenation of sugars |
| US20050096212A1 (en) * | 2003-10-31 | 2005-05-05 | Hiroshi Takeda | Catalyst for the conversion of carbon monoxide |
| US20050096211A1 (en) * | 2003-10-31 | 2005-05-05 | Hiroshi Takeda | Catalyst for the conversion of carbon monoxide |
| US8945309B2 (en) | 2006-03-01 | 2015-02-03 | National University Corporation Hokkaido University | Catalyst for cellulose hydrolysis and/or reduction of cellulose hydrolysis products and method of producing sugar alcohols from cellulose |
| GB2437517A (en) | 2006-04-27 | 2007-10-31 | Danisco Sweeteners Oy | Catalytic hydrogenation of sugar to sugar alcohol, using increasing reaction temperature and/or addition of monocarboxylic acid to maintain catalyst activity |
| CN101121643B (zh) * | 2007-08-09 | 2010-05-19 | 厦门大学 | 六元醇的制备方法 |
| DE102008015406A1 (de) * | 2008-03-22 | 2009-09-24 | Bayer Materialscience Ag | Verfahren zur Regeneration eines mit Schwefel in Form von Schwefelverbindungen vergifteten, Ruthenium oder Rutheniumverbindungen enthaltenden Katalysators |
| WO2010144558A2 (en) * | 2009-06-09 | 2010-12-16 | University Of Kansas | Nano-metal catalysts for polyol hydrogenolysis |
| US20120315366A1 (en) * | 2009-12-23 | 2012-12-13 | Evonik Degussa Gmbh | Sweetener and method of production thereof |
| KR101332303B1 (ko) * | 2011-04-19 | 2013-11-22 | 한국화학연구원 | 당류의 촉매 수소화에 의한 당알코올류의 제조방법 |
| KR101359446B1 (ko) * | 2011-04-19 | 2014-02-11 | 한국화학연구원 | 당류의 촉매 수소화에 의해 당알코올류를 제조하기 위한 담지촉매 및 이의 제조방법 |
| WO2012141523A2 (ko) * | 2011-04-14 | 2012-10-18 | 한국화학연구원 | 당류의 촉매 수소화에 의해 당알코올류를 제조하기 위한 담지촉매, 이의 제조방법 및 이를 이용한 당알코올류의 제조방법 |
| CA2937511C (en) | 2014-01-21 | 2022-07-05 | Council Of Scientific & Industrial Research | An improved process for the preparation of 2,5-dimethylfuran and furfuryl alcohol over ruthenium supported catalysts |
| PL3849991T3 (pl) | 2018-09-11 | 2026-02-09 | Südzucker AG | Sposób polepszonego wytwarzania izomaltu |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2868847A (en) * | 1956-10-05 | 1959-01-13 | Engelhard Ind Inc | Hydrogenation of mono-and disaccharides to polyols |
| US3055840A (en) * | 1958-01-13 | 1962-09-25 | Engelhard Ind Inc | Ruthenium-containing catalysts and methods of making said catalysts and increasing their activity |
-
1974
- 1974-11-05 US US05/520,926 patent/US3963788A/en not_active Expired - Lifetime
-
1975
- 1975-07-08 CA CA230,970A patent/CA1054160A/en not_active Expired
- 1975-08-13 NL NL7509668A patent/NL7509668A/xx not_active Application Discontinuation
- 1975-08-14 CH CH1063775A patent/CH614185A5/xx not_active IP Right Cessation
- 1975-08-14 FR FR7525395A patent/FR2282418A1/fr active Granted
- 1975-08-14 DE DE19752536416 patent/DE2536416A1/de not_active Withdrawn
- 1975-08-14 BR BR7505206*A patent/BR7505206A/pt unknown
- 1975-08-15 JP JP50098647A patent/JPS5143707A/ja active Pending
- 1975-08-19 GB GB6452/77A patent/GB1496927A/en not_active Expired
- 1975-08-19 GB GB34429/75A patent/GB1496926A/en not_active Expired
- 1975-12-30 BE BE163217A patent/BE837201A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2282418A1 (fr) | 1976-03-19 |
| GB1496926A (en) | 1978-01-05 |
| NL7509668A (nl) | 1976-02-24 |
| CA1054160A (en) | 1979-05-08 |
| BR7505206A (pt) | 1976-08-03 |
| JPS5143707A (enExample) | 1976-04-14 |
| AU8366975A (en) | 1977-02-10 |
| US3963788A (en) | 1976-06-15 |
| CH614185A5 (enExample) | 1979-11-15 |
| DE2536416A1 (de) | 1976-03-04 |
| BE837201A (fr) | 1976-06-30 |
| FR2282418B1 (enExample) | 1980-04-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19950818 |