GB1456031A - Process for the thermal conversion of metal chlorides to metal oxides - Google Patents

Process for the thermal conversion of metal chlorides to metal oxides

Info

Publication number
GB1456031A
GB1456031A GB5623673A GB5623673A GB1456031A GB 1456031 A GB1456031 A GB 1456031A GB 5623673 A GB5623673 A GB 5623673A GB 5623673 A GB5623673 A GB 5623673A GB 1456031 A GB1456031 A GB 1456031A
Authority
GB
United Kingdom
Prior art keywords
bed
metal
oxides
chlorides
dec
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5623673A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
Original Assignee
Metallgesellschaft AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallgesellschaft AG filed Critical Metallgesellschaft AG
Publication of GB1456031A publication Critical patent/GB1456031A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/51Particles with a specific particle size distribution
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Compounds Of Iron (AREA)
  • Treating Waste Gases (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Silicon Compounds (AREA)

Abstract

1456031 Conversion of metal chlorides to metal oxides METALLGESELLSCHAFT AG 4 Dec 1973 [14 Dec 1972] 56236/73 Heading C1A Metal chlorides are converted to oxides by forming a bed of the metal oxide particles at least 350 mm. deep (when static) fluidized by introducing a free-O 2 -containing gas and fuel so that the velocity of all the gases traversing the bed is determined by the equation 0À34 #<SP>0À9</SP># W G #0À56 #<SP>0À9</SP> where W G is the velocity calculated on the cross-section of the chamber in the absence of the bed and # is the density of the metal oxide, the pressure drop across the bed being 1200-2400 mm. of water, the metal chloride being introduced at least 250 mm. above the grate, the bed temperature being between that at which the chloride reacts or the fuel ignites and that at which the oxides sinter, and withdrawing oxide granules below the entry point of the chlorides. The bed may be kept at a substantially constant level and at 800-1100‹ C. The feed may be a used pickle bath. When Fe 2 O 3 is the product W G may be 1À5-2À5 m/sec., the bed height 350-750 mm. and its temperature 800‹ C. The effluent gas may be passed through a cyclone to remove fine particles, which may be re-cycled to the bed, then through a venturi scrubber in contact with the feed liquor and finally through a washer to absorb HCl. NiO is also exemplified.
GB5623673A 1972-12-14 1973-12-04 Process for the thermal conversion of metal chlorides to metal oxides Expired GB1456031A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2261083A DE2261083C3 (en) 1972-12-14 1972-12-14 Process for the thermal cracking of metal chlorides

Publications (1)

Publication Number Publication Date
GB1456031A true GB1456031A (en) 1976-11-17

Family

ID=5864351

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5623673A Expired GB1456031A (en) 1972-12-14 1973-12-04 Process for the thermal conversion of metal chlorides to metal oxides

Country Status (12)

Country Link
JP (1) JPS5644004B2 (en)
BE (1) BE808643A (en)
BR (1) BR7309510D0 (en)
CA (1) CA1008636A (en)
DE (1) DE2261083C3 (en)
ES (1) ES420737A1 (en)
FR (1) FR2210439B1 (en)
GB (1) GB1456031A (en)
IT (1) IT1002220B (en)
SE (1) SE402448B (en)
SU (1) SU518120A3 (en)
ZA (1) ZA737992B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2524541C2 (en) * 1975-06-03 1986-08-21 Aluminium Pechiney, Lyon Process for the thermal cracking of aluminum chloride hydrate
US4086321A (en) * 1976-06-21 1978-04-25 Carl A. Holley Producing pure iron oxides
DE2636854C2 (en) * 1976-08-16 1986-08-21 Aluminium Pechiney, Lyon Process for the thermal cracking of aluminum chloride hydrate
DE2636855C2 (en) * 1976-08-16 1986-08-21 Aluminium Pechiney, Lyon Process for the thermal cracking of aluminum chloride hydrate
DE2730646C3 (en) * 1977-07-07 1982-04-01 Metallgesellschaft Ag, 6000 Frankfurt Process for the thermal cleavage of metal chlorides of bivalent or polyvalent metals
DE2805906C2 (en) * 1978-02-13 1986-08-14 Aluminium Pechiney, Lyon Process for the thermal cracking of aluminum chloride hydrate
DE3900181A1 (en) * 1989-01-05 1990-07-12 Atzger Juergen Method for the thermal processing of residual products of flue gas purification plants and fluidised-bed combustion plants, producing utilisable feedstocks
JPH0675205U (en) * 1993-04-02 1994-10-25 五ツ星産業株式会社 Athletic shoes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB860301A (en) * 1958-03-21 1961-02-01 British Titan Products Improvements in or relating to exothermic reactions
US3440009A (en) * 1966-07-19 1969-04-22 Little Inc A Processing of spent hydrochloric acid pickle liquor

Also Published As

Publication number Publication date
ZA737992B (en) 1974-11-27
AU6142573A (en) 1975-04-17
FR2210439B1 (en) 1978-03-10
DE2261083B2 (en) 1978-10-05
FR2210439A1 (en) 1974-07-12
DE2261083A1 (en) 1974-07-11
DE2261083C3 (en) 1979-05-31
BR7309510D0 (en) 1974-08-29
ES420737A1 (en) 1976-04-01
CA1008636A (en) 1977-04-19
IT1002220B (en) 1976-05-20
JPS5644004B2 (en) 1981-10-16
SE402448B (en) 1978-07-03
SU518120A3 (en) 1976-06-15
BE808643A (en) 1974-06-14
JPS4996997A (en) 1974-09-13

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19921204