GB1444048A - Random copolymers - Google Patents

Random copolymers

Info

Publication number
GB1444048A
GB1444048A GB1156974A GB1156974A GB1444048A GB 1444048 A GB1444048 A GB 1444048A GB 1156974 A GB1156974 A GB 1156974A GB 1156974 A GB1156974 A GB 1156974A GB 1444048 A GB1444048 A GB 1444048A
Authority
GB
United Kingdom
Prior art keywords
vinyl
copolymer
phthalimide
vinylcarbazole
vinylamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1156974A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xerox Corp
Original Assignee
Xerox Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xerox Corp filed Critical Xerox Corp
Publication of GB1444048A publication Critical patent/GB1444048A/en
Expired legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02—Charge-receiving layers
    • G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/07—Polymeric photoconductive materials
    • G03G5/071—Polymeric photoconductive materials obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G5/072—Polymeric photoconductive materials obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising pending monoamine groups
    • G03G5/073—Polymeric photoconductive materials obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising pending monoamine groups comprising pending carbazole groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F26/12—N-Vinyl-carbazole

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1444048 Copolymers of N-vinyl carbazole XEROX CORP 15 March 1974 [19 March 1973] 11569/74 Heading C3P A random copolymer is derived from components comprising at least first and second components respectively corresponding to (i) N-vinyl carbazole and (ii) at least one monomer selected from N-vinyl phthalimide, N-vinylamine and an electron acceptor other than N- vinyl phthalimide or N-vinylamine. The N- vinyl carbazole/N-vinyl phthalimide copolymer may be prepared in solution in benzene using a catalyst such as azobisisobutyronitrile. The resulting copolymer may be treated with hydrazine hydrate to yeild an N-vinyl carbazole/ vinylamine copolymer which is subsequently reacted with (a) a tetrahalophthalic anhydride to form N - vinylcarbazole/tetrabromotetrachloro- or tetraiodo-phthalimide copolymer, (b) 2,4 - dinitrofluorobenzene to form N- vinylcarbazole/N - vinyl - 2,4 - dinitroaniline copolymer or (c) 1-fluoro-4-nitrobenzene to form N - vinylcarbazole/N - vinyl - 4 - nitroaniline copolymer. Solutions of the copolymers may be applied to a conductive substrate, e.g. aluminized polyester film substrate, optionally coated with a barrier layer to form the photoconductive layer of an electrophotographic imaging member.
GB1156974A 1973-03-19 1974-03-15 Random copolymers Expired GB1444048A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US342646A US3877936A (en) 1973-03-19 1973-03-19 Photoconductive copolymer of N-vinylcarbazole and N-vinylphthalimide

Publications (1)

Publication Number Publication Date
GB1444048A true GB1444048A (en) 1976-07-28

Family

ID=23342683

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1156974A Expired GB1444048A (en) 1973-03-19 1974-03-15 Random copolymers

Country Status (11)

Country Link
US (1) US3877936A (en)
JP (1) JPS5233495B2 (en)
BE (1) BE812436A (en)
BR (1) BR7402072D0 (en)
CA (1) CA1024696A (en)
DE (1) DE2409108A1 (en)
ES (1) ES424411A1 (en)
FR (1) FR2223400B1 (en)
GB (1) GB1444048A (en)
IT (1) IT1010697B (en)
NL (1) NL7403708A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4898915A (en) * 1983-08-24 1990-02-06 University Of Akron Alternating copolymerization of donor monomers having protected amine groups with acceptor monomers
US5326661A (en) * 1991-11-13 1994-07-05 Hoechst Celanese Corp. Photorefractive polymers containing discrete photoconductive and electrooptical units
US5958288A (en) * 1996-11-26 1999-09-28 Cabot Corporation Composition and slurry useful for metal CMP
US7732116B2 (en) * 2007-09-27 2010-06-08 Eastman Kodak Company Photoconductors containing N-arylphthalimides

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3155503A (en) * 1959-02-26 1964-11-03 Gevaert Photo Prod Nv Electrophotographic material
BE592557A (en) * 1959-07-01
US3073785A (en) * 1959-07-02 1963-01-15 Electrically conductive polymeric
US3287122A (en) * 1961-07-24 1966-11-22 Azoplate Corp Process for the sensitization of photoconductors
US3418116A (en) * 1963-02-21 1968-12-24 Matsushita Electric Ind Co Ltd Electrophotographic materials comprising polymeric intramolecular charge transfer complexes
US3697264A (en) * 1970-03-02 1972-10-10 Richard M Podhajny Novel photoconductive carbazole polymers and photoconductive elements embodying same

Also Published As

Publication number Publication date
NL7403708A (en) 1974-09-23
US3877936A (en) 1975-04-15
JPS50111189A (en) 1975-09-01
BE812436A (en) 1974-07-15
AU6663774A (en) 1975-09-18
BR7402072D0 (en) 1974-12-24
IT1010697B (en) 1977-01-20
FR2223400B1 (en) 1977-06-17
ES424411A1 (en) 1976-11-01
FR2223400A1 (en) 1974-10-25
JPS5233495B2 (en) 1977-08-29
DE2409108A1 (en) 1974-09-26
CA1024696A (en) 1978-01-17

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee