GB1423928A - Method for the electrolytic deposition of copper on aluminium and its alloys and the products obtained therewith - Google Patents

Method for the electrolytic deposition of copper on aluminium and its alloys and the products obtained therewith

Info

Publication number
GB1423928A
GB1423928A GB3027574A GB3027574A GB1423928A GB 1423928 A GB1423928 A GB 1423928A GB 3027574 A GB3027574 A GB 3027574A GB 3027574 A GB3027574 A GB 3027574A GB 1423928 A GB1423928 A GB 1423928A
Authority
GB
United Kingdom
Prior art keywords
electro
plate
bath
plated
july
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3027574A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
COLALE R
Original Assignee
COLALE R
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by COLALE R filed Critical COLALE R
Publication of GB1423928A publication Critical patent/GB1423928A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • C25D5/42Pretreatment of metallic surfaces to be electroplated of light metals
    • C25D5/44Aluminium
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/38Electroplating: Baths therefor from solutions of copper
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/18Electroplating using modulated, pulsed or reversing current
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60Electroplating characterised by the structure or texture of the layers
    • C25D5/605Surface topography of the layers, e.g. rough, dendritic or nodular layers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60Electroplating characterised by the structure or texture of the layers
    • C25D5/605Surface topography of the layers, e.g. rough, dendritic or nodular layers
    • C25D5/611Smooth layers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/627Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

1423928 Electro-depositing copper on anodized aluminium R COLALE 9 July 1974 [9 July 1973] 30275/74 Heading C7B An A1 or A1 alloy body e.g. plate is electroplated with Cu by immersing the degreased and pickled body in an electrolyte bath containing Cu (and preferably K 4 ) pyrophosphate with pH between 8À2 and 9À7 and temperature between 50 and 65‹C, first as anode then as cathode by reversing polarity without withdrawing the body from the bath, the counter-electrode being at least one Cu plate or bar, and regulating the voltage so that a CD of between 1À6 and 2À4 A/dm<SP>2</SP> of body surface passes during anodizing, and of between 0À2 and 0À9 rising to a maximum of between 5 and 10 A/dm<SP>2</SP> of body surface during electro-plating, the voltage being reduced to between 0À3 and 0À7V at the end of the first stage. For offset printing, A1 cylinders electro-plated with Cu as above may be further electro-plated with Ni and/or Cr; for electronics, the Cu electro-plate may be coated with Sn-Pb soldering alloy. Degreasing may be effected in C 2 HCl 3 and etching in NaOH then HNO 3 solution. The bath may also contain inorganic salts of alkali metals, e.g. oxalates or citrates, to obtain shiny and brilliant Cu deposits.
GB3027574A 1973-07-09 1974-07-09 Method for the electrolytic deposition of copper on aluminium and its alloys and the products obtained therewith Expired GB1423928A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT26376/73A IT991079B (en) 1973-07-09 1973-07-09 PROCEDURE FOR ELECTROLYTICALLY RETURNING COPPER ON ALUMINUM AND ITS ALLOYS AND PRODUCTS OBTAINED WITH THIS PROCESS

Publications (1)

Publication Number Publication Date
GB1423928A true GB1423928A (en) 1976-02-04

Family

ID=11219353

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3027574A Expired GB1423928A (en) 1973-07-09 1974-07-09 Method for the electrolytic deposition of copper on aluminium and its alloys and the products obtained therewith

Country Status (5)

Country Link
BE (1) BE817405A (en)
DE (1) DE2432888A1 (en)
GB (1) GB1423928A (en)
IT (1) IT991079B (en)
NL (1) NL7409288A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110114517A (en) * 2016-08-17 2019-08-09 席勒斯材料科学有限公司 The method of thin functional coating is generated on light-alloy

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112601346A (en) * 2020-12-21 2021-04-02 深圳明阳电路科技股份有限公司 Manufacturing method of super-thick copper plate and super-thick copper plate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110114517A (en) * 2016-08-17 2019-08-09 席勒斯材料科学有限公司 The method of thin functional coating is generated on light-alloy
EP3500695A4 (en) * 2016-08-17 2020-03-25 Cirrus Materials Science Limited Method to create thin functional coatings on light alloys

Also Published As

Publication number Publication date
BE817405A (en) 1974-11-04
NL7409288A (en) 1975-01-13
IT991079B (en) 1975-07-30
DE2432888A1 (en) 1975-01-30

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee