GB1413470A - Zeolites - Google Patents
ZeolitesInfo
- Publication number
- GB1413470A GB1413470A GB4604871A GB4604871A GB1413470A GB 1413470 A GB1413470 A GB 1413470A GB 4604871 A GB4604871 A GB 4604871A GB 4604871 A GB4604871 A GB 4604871A GB 1413470 A GB1413470 A GB 1413470A
- Authority
- GB
- United Kingdom
- Prior art keywords
- quaternary ammonium
- sio
- reacting
- silica
- particle size
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010457 zeolite Substances 0.000 title abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract 2
- 229910004298 SiO 2 Inorganic materials 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 abstract 2
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 238000000634 powder X-ray diffraction Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/14—Type A
- C01B39/16—Type A from aqueous solutions of an alkali metal aluminate and an alkali metal silicate excluding any other source of alumina or silica but seeds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/30—Erionite or offretite type, e.g. zeolite T
- C01B39/305—Erionite or offretite type, e.g. zeolite T using at least one organic template directing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
1413470 1À1 0À4 M 2 O :Al 2 O 3 : 8 4 SiO 2 IMPERIAL CHEMICAL INDUSTRIES Ltd 14 Sept 1972 [4 Oct 1971] 46048/71 Heading C1A [Also in Division C5] Zeolite AG2, 1À1 0À4 M 2 O : Al 2 O 3 : 8 4 SiO 2 , where M is a quaternary ammonium ion with potassium (with or without Na), having a specified X-ray powder diffraction pattern is made either by reacting at least one Al-containing compound, at least one Si-containing compound, at least one alkali component and at least one quaternary ammonium compound, in aqueous medium, the major silicon component comprising silica of colloidal particle size as defined, the reaction mixture having oxide molar ratios in the following ranges:- where R = quaternary ammonium compound and M 2 O = R 2 O + K 2 O + Na 2 O, or by reacting the above components where the major silicon component is silica of colloidal particle size as defined, an alkali silicate, a quaternary ammonium silicate or any combination thereof and, the oxide molar ratios are in the following ranges:-- R and M 2 O being as defined above. The cations of AG2 may be exchanged with H+ or metal ions.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE789628D BE789628A (en) | 1971-10-04 | ZEOLITES | |
| GB4604871A GB1413470A (en) | 1971-10-04 | 1971-10-04 | Zeolites |
| FR7235053A FR2156001B3 (en) | 1971-10-04 | 1972-10-03 | |
| IT30020/72A IT968568B (en) | 1971-10-04 | 1972-10-03 | METHOD OF PREPARATION OF SYNTHETIC ZEOLITES AND RELATIVE ZEOLITES |
| SE7212757A SE380241B (en) | 1971-10-04 | 1972-10-03 | ZEOLIT AG2 AND SET FOR ITS MANUFACTURE |
| JP47099122A JPS4861399A (en) | 1971-10-04 | 1972-10-04 | |
| DE19722248626 DE2248626A1 (en) | 1971-10-04 | 1972-10-04 | ZEOLITE, ITS PRODUCTION AND ITS USE |
| NL7213408A NL7213408A (en) | 1971-10-04 | 1972-10-04 | |
| SE7507021A SE7507021L (en) | 1971-10-04 | 1975-06-18 | WAY TO PRODUCE A ZEOLITE |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4604871A GB1413470A (en) | 1971-10-04 | 1971-10-04 | Zeolites |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1413470A true GB1413470A (en) | 1975-11-12 |
Family
ID=10439649
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4604871A Expired GB1413470A (en) | 1971-10-04 | 1971-10-04 | Zeolites |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS4861399A (en) |
| BE (1) | BE789628A (en) |
| DE (1) | DE2248626A1 (en) |
| FR (1) | FR2156001B3 (en) |
| GB (1) | GB1413470A (en) |
| IT (1) | IT968568B (en) |
| NL (1) | NL7213408A (en) |
| SE (2) | SE380241B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4390414A (en) | 1981-12-16 | 1983-06-28 | Exxon Research And Engineering Co. | Selective dewaxing of hydrocarbon oil using surface-modified zeolites |
| US4554146A (en) * | 1983-11-10 | 1985-11-19 | Exxon Research And Engineering Co. | Process for preparing a zeolite of the L type using organic templates |
| GB2160188A (en) * | 1984-06-07 | 1985-12-18 | Inst Francais Du Petrole | Synthetic zeolites |
| US4834961A (en) * | 1983-03-07 | 1989-05-30 | Centre National De La Recherche Scientifique | Aluminosilicate zeolite having an offretite structure |
| US4931266A (en) * | 1986-10-22 | 1990-06-05 | Union Oil Company Of California | Crystalline galliosilicate with the erionite-type structure |
| US4961836A (en) * | 1986-05-23 | 1990-10-09 | Exxon Research And Engineering Company | Synthesis of transition metal alumino-silicate IOZ-5 and use of it for hydrocarbon conversion |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ185397A (en) * | 1976-11-04 | 1979-12-11 | Mobil Oil Corp | Crystalline aluminosilicate zeolites and use as catalysts |
-
0
- BE BE789628D patent/BE789628A/en unknown
-
1971
- 1971-10-04 GB GB4604871A patent/GB1413470A/en not_active Expired
-
1972
- 1972-10-03 IT IT30020/72A patent/IT968568B/en active
- 1972-10-03 SE SE7212757A patent/SE380241B/en unknown
- 1972-10-03 FR FR7235053A patent/FR2156001B3/fr not_active Expired
- 1972-10-04 NL NL7213408A patent/NL7213408A/xx unknown
- 1972-10-04 DE DE19722248626 patent/DE2248626A1/en active Pending
- 1972-10-04 JP JP47099122A patent/JPS4861399A/ja active Pending
-
1975
- 1975-06-18 SE SE7507021A patent/SE7507021L/en unknown
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4390414A (en) | 1981-12-16 | 1983-06-28 | Exxon Research And Engineering Co. | Selective dewaxing of hydrocarbon oil using surface-modified zeolites |
| US4834961A (en) * | 1983-03-07 | 1989-05-30 | Centre National De La Recherche Scientifique | Aluminosilicate zeolite having an offretite structure |
| US4554146A (en) * | 1983-11-10 | 1985-11-19 | Exxon Research And Engineering Co. | Process for preparing a zeolite of the L type using organic templates |
| GB2160188A (en) * | 1984-06-07 | 1985-12-18 | Inst Francais Du Petrole | Synthetic zeolites |
| US4961836A (en) * | 1986-05-23 | 1990-10-09 | Exxon Research And Engineering Company | Synthesis of transition metal alumino-silicate IOZ-5 and use of it for hydrocarbon conversion |
| US4931266A (en) * | 1986-10-22 | 1990-06-05 | Union Oil Company Of California | Crystalline galliosilicate with the erionite-type structure |
Also Published As
| Publication number | Publication date |
|---|---|
| SE7507021L (en) | 1975-06-18 |
| DE2248626A1 (en) | 1973-06-07 |
| NL7213408A (en) | 1973-04-06 |
| FR2156001B3 (en) | 1975-10-31 |
| BE789628A (en) | 1973-04-03 |
| JPS4861399A (en) | 1973-08-28 |
| SE380241B (en) | 1975-11-03 |
| IT968568B (en) | 1974-03-20 |
| FR2156001A1 (en) | 1973-05-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |