GB1408398A - Silver halide supersensitized photographic emulsions - Google Patents
Silver halide supersensitized photographic emulsionsInfo
- Publication number
- GB1408398A GB1408398A GB5450672A GB5450672A GB1408398A GB 1408398 A GB1408398 A GB 1408398A GB 5450672 A GB5450672 A GB 5450672A GB 5450672 A GB5450672 A GB 5450672A GB 1408398 A GB1408398 A GB 1408398A
- Authority
- GB
- United Kingdom
- Prior art keywords
- optionally substituted
- formula
- represent
- silver halide
- alkoxycarbonyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/28—Sensitivity-increasing substances together with supersensitising substances
- G03C1/29—Sensitivity-increasing substances together with supersensitising substances the supersensitising mixture being solely composed of dyes ; Combination of dyes, even if the supersensitising effect is not explicitly disclosed
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
- C09B23/06—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups three >CH- groups, e.g. carbocyanines
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
1408398 Supersensitizing silver halide emulsions FUJI PHOTO FILM CO Ltd 24 Nov 1972 [24 Nov 1971] 54506/72 Heading G2C A silver halide photographic emulsion comprises a supersensitizing combination of at least one dye of Formula I in which A<SP>1</SP> and A<SP>2</SP> each represent H, halogen, OH, alkoxy, optionally substituted amino, acylamido, acyloxy, carbalkoxy, alkoxycarbonylamino, CN, CF 3 , alkoxycarbonyl, alkylsulphonyl, sulphamyl, alkylaminosulphonyl, morpholinosulphonyl, morpholinocarbonyl, piperidinosulphonyl, carbamoyl, alkybarbamoyl, or alkylcarbonyl; A<SP>3</SP> and A<SP>4</SP> each represent H, halogen, alkyl (1-4C) alkoxy, OH, optionally substituted phenyl, carboxyl, alkoxycarbonyl, CN, CF 3 , optionally substituted amino, acyl, acylamido, acyloxy, alkoxycarbonyl, alkoxycarbonylamino or carbalkoxy; R, R<SP>1</SP> and R<SP>2</SP> each represent optionally substituted alkyl, at least one of R<SP>1</SP> and R<SP>2</SP> being a substituted alkyl group comprising a sulpho or carboxy group X<SP>1</SP> is an anion and n is 0 or 1, together with a dye of Formula. in which B<SP>1</SP>, B<SP>2</SP>, B<SP>3</SP> and B<SP>4</SP> each have the same meaning as A<SP>3</SP> and A<SP>4</SP>; R<SP>3</SP> and R<SP>4</SP> each represent optionally substituted alkyl, at least one R<SP>3</SP> and R<SP>4</SP> being a substituted alkyl group comprising a sulpho or carboxy group; R<SP>5</SP> represents H, alkyl or aryl; X<SP>2</SP> is an anion and n is 0 or 1. The dyes sensitize the emulsion to the green region of the spectrum and are resistant to stripping by magenta colour couplers, examples of which are given. The emulsion may also include a water-soluble iodide and/ or a water-soluble bromide. The preferred dyes of Formula I are substituted by a halogen atom in at least one of the 5- or 6-positions of the benzimidazole nucleus and those of Formula II are substituted by a halogen atom at the 5-position of the benzoxazole nucleus.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9426671A JPS5514411B2 (en) | 1971-11-24 | 1971-11-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1408398A true GB1408398A (en) | 1975-10-01 |
Family
ID=14105463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5450672A Expired GB1408398A (en) | 1971-11-24 | 1972-11-24 | Silver halide supersensitized photographic emulsions |
Country Status (6)
Country | Link |
---|---|
US (1) | US3832189A (en) |
JP (1) | JPS5514411B2 (en) |
CA (1) | CA992790A (en) |
DE (1) | DE2257751A1 (en) |
FR (1) | FR2161053B1 (en) |
GB (1) | GB1408398A (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3973969A (en) * | 1972-06-21 | 1976-08-10 | Fuji Photo Film Co., Ltd. | Silver halide photographic emulsion |
US4172730A (en) * | 1975-03-18 | 1979-10-30 | Fuji Photo Film Co., Ltd. | Radiographic silver halide sensitive materials |
US4026707A (en) * | 1975-08-15 | 1977-05-31 | Konishiroku Photo Industry Co., Ltd. | Silver halide photographic emulsion sensitized with a mixture of oxacarbocyanine dyes |
JPS5850324B2 (en) * | 1980-06-30 | 1983-11-10 | 富士写真フイルム株式会社 | silver halide photographic emulsion |
JPS5972444A (en) * | 1982-10-19 | 1984-04-24 | Konishiroku Photo Ind Co Ltd | Method for processing silver halide color photographic sensitive material |
JPS60108838A (en) * | 1983-11-17 | 1985-06-14 | Fuji Photo Film Co Ltd | Photographic silver halide emulsion |
JPH06105342B2 (en) * | 1986-12-01 | 1994-12-21 | 富士写真フイルム株式会社 | Silver halide light-sensitive material sensitized with a luminescent dye |
JPH0711685B2 (en) * | 1986-12-01 | 1995-02-08 | 富士写真フイルム株式会社 | Silver halide photosensitive material |
JP2561826B2 (en) * | 1986-12-27 | 1996-12-11 | 富士写真フイルム株式会社 | Silver halide photographic emulsion |
US4908303A (en) * | 1987-02-12 | 1990-03-13 | Fuji Photo Film Co., Ltd. | Silver halide photographic materials spectrally sensitized with luminous dye |
JPS6484244A (en) * | 1987-09-28 | 1989-03-29 | Fuji Photo Film Co Ltd | Silver halide photosensitive material |
JPH01147539A (en) * | 1987-12-04 | 1989-06-09 | Konica Corp | Silver halide photographic sensitive material |
US5316904A (en) * | 1992-11-19 | 1994-05-31 | Eastman Kodak Company | Amide substituted dye compounds and silver halide photographic elements containing such dyes |
US5354651A (en) * | 1992-11-19 | 1994-10-11 | Eastman Kodak Company | Hydroxyarylacyl dye compounds and silver halide photographic elements containing such dyes |
DE69327635T2 (en) * | 1992-11-19 | 2000-08-10 | Eastman Kodak Co., Rochester | Dye compounds and photographic elements containing them |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3397060A (en) * | 1964-10-19 | 1968-08-13 | Eastman Kodak Co | Supersensitization of green-sensitive silver halide emulsions |
BE760773A (en) * | 1969-12-24 | 1971-05-27 | Fuji Photo Film Co Ltd | PHOTOGRAPHIC MATERIALS PHOTOSENSITIVE TO SILVER HALOGENIDES |
-
1971
- 1971-11-24 JP JP9426671A patent/JPS5514411B2/ja not_active Expired
-
1972
- 1972-11-24 US US00309531A patent/US3832189A/en not_active Expired - Lifetime
- 1972-11-24 FR FR7241840A patent/FR2161053B1/fr not_active Expired
- 1972-11-24 DE DE2257751A patent/DE2257751A1/en not_active Withdrawn
- 1972-11-24 CA CA157,394A patent/CA992790A/en not_active Expired
- 1972-11-24 GB GB5450672A patent/GB1408398A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CA992790A (en) | 1976-07-13 |
JPS5514411B2 (en) | 1980-04-16 |
JPS4859828A (en) | 1973-08-22 |
FR2161053A1 (en) | 1973-07-06 |
DE2257751A1 (en) | 1973-05-30 |
FR2161053B1 (en) | 1975-03-28 |
US3832189A (en) | 1974-08-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PE20 | Patent expired after termination of 20 years |