GB1316831A - Supersensitised silver halide photographic emulsions - Google Patents
Supersensitised silver halide photographic emulsionsInfo
- Publication number
- GB1316831A GB1316831A GB2969370A GB2969370A GB1316831A GB 1316831 A GB1316831 A GB 1316831A GB 2969370 A GB2969370 A GB 2969370A GB 2969370 A GB2969370 A GB 2969370A GB 1316831 A GB1316831 A GB 1316831A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- halogen
- silver halide
- substituted alkyl
- unneutralised
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/28—Sensitivity-increasing substances together with supersensitising substances
- G03C1/29—Sensitivity-increasing substances together with supersensitising substances the supersensitising mixture being solely composed of dyes ; Combination of dyes, even if the supersensitising effect is not explicitly disclosed
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
1316831 Supersensitized silver halide photographic emulsions FUJI PHOTO FILM CO Ltd 18 June 1970 [19 June 1969] 29693/70 Heading G2C A photographic silver halide emulsion contains at least one sensitizing dye of the formula: wherein A is 1-4C alkyl; R<SP>3</SP> is halogen, OH, phenyl or tolyl; R<SP>4</SP> is H, halogen, phenyl, OH, aralkyl, alkyl or alkoxyl; R<SP>1</SP> and R<SP>2</SP> are each alkyl or neutralised or unneutralised sulphoalkyl; X<SP>1-</SP> is an acid anion; and n is 0 or 1, n being 0 when one of R<SP>1</SP> and R<SP>2</SP> is sulphoalkyl; and in supersensitizing combination therewith at least one sensitizing dye of the formula: - wherein R<SP>5</SP> and R<SP>6</SP> are each alkyl or substituted alkyl; R<SP>7</SP> and R<SP>8</SP> are each alkyl or substituted alkyl, at least one of R<SP>7</SP> and R<SP>8</SP> being neutralised or unneutralised sulphoalkyl or substituted alkyl having a neutralised or unneutralised sulpho group; R<SP>9</SP>, R<SP>10</SP>, R<SP>11</SP> and R<SP>12</SP> are each H, alkylsulphonyl, alkylsulphamoyl, N, N-disubstituted aminosulphonyl, alkylcarbamoyl, N, N-disubstituted carbamoyl, CN, CF 3 or halogen; X<SP>2-</SP> is an acid anion; and m is 0 or 1, m being 0 when one of R<SP>7</SP> and R<SP>8</SP> is a substituent having a sulpho group; at least one of R<SP>5</SP>, R<SP>6</SP>, R<SP>7</SP> and R<SP>8</SP> being an acetoxyalkyl, a hydroxyalkyl, a substituted alkyl having a sulpho group, or an allyl group when R<SP>9</SP>, R<SP>10</SP>, R<SP>11</SP>, and R<SP>12</SP> are all H and/or halogen; the cases (i) in which R<SP>3</SP> and R<SP>4</SP> are both phenyl and also R<SP>9</SP>, R<SP>10</SP>, R<SP>11</SP> and R<SP>12</SP> are H or Cl and (ii) in which R<SP>11</SP> and R<SP>12</SP> or R<SP>9</SP> and R<SP>10</SP> are both CN or CF 3 being excluded. Many examples of these dyes are given. In the examples the emulsion also contains as magenta coupler 1-(3-sulpho-4- phenoxyphenyl) -3-heptadecyl-pyrazol-5-one. Little colour stain is caused by these sensitizing dyes after development and the sensitivity of the emulsion in the region 500-530 mÁ is increased.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4860669A JPS4825652B1 (en) | 1969-06-19 | 1969-06-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1316831A true GB1316831A (en) | 1973-05-16 |
Family
ID=12808059
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2969370A Expired GB1316831A (en) | 1969-06-19 | 1970-06-18 | Supersensitised silver halide photographic emulsions |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS4825652B1 (en) |
BE (1) | BE752038A (en) |
DE (1) | DE2030326A1 (en) |
FR (1) | FR2046893B1 (en) |
GB (1) | GB1316831A (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49141753U (en) * | 1973-04-06 | 1974-12-06 | ||
JPS49144166U (en) * | 1973-04-11 | 1974-12-12 | ||
JPS58152347A (en) * | 1982-03-08 | 1983-09-09 | Toshiba Corp | Color picture tube |
JPS59116647A (en) | 1982-12-13 | 1984-07-05 | Konishiroku Photo Ind Co Ltd | Silver halide photosensitive material |
JPS61245151A (en) | 1985-04-23 | 1986-10-31 | Konishiroku Photo Ind Co Ltd | Silver halide photographic sensitive material |
JPS61251852A (en) | 1985-04-30 | 1986-11-08 | Konishiroku Photo Ind Co Ltd | Method for processing silver halide color photographic sensitive material |
JPS61250643A (en) | 1985-04-30 | 1986-11-07 | Konishiroku Photo Ind Co Ltd | Silver halide photographic sensitive material |
JPS61250645A (en) | 1985-04-30 | 1986-11-07 | Konishiroku Photo Ind Co Ltd | Silver halide photographic sensitive material |
DE3682128D1 (en) | 1985-07-17 | 1991-11-28 | Konishiroku Photo Ind | PHOTOGRAPHIC SILVER HALOGENID MATERIAL. |
AU591540B2 (en) | 1985-12-28 | 1989-12-07 | Konishiroku Photo Industry Co., Ltd. | Method of processing light-sensitive silver halide color photographic material |
DE69131785T2 (en) | 1990-08-20 | 2000-05-11 | Fuji Photo Film Co Ltd | Data-preserving photographic film product and method for producing a color image |
-
1969
- 1969-06-19 JP JP4860669A patent/JPS4825652B1/ja active Pending
-
1970
- 1970-06-16 BE BE752038D patent/BE752038A/en unknown
- 1970-06-18 GB GB2969370A patent/GB1316831A/en not_active Expired
- 1970-06-18 FR FR7022415A patent/FR2046893B1/fr not_active Expired
- 1970-06-19 DE DE19702030326 patent/DE2030326A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
FR2046893B1 (en) | 1973-01-12 |
JPS4825652B1 (en) | 1973-07-31 |
BE752038A (en) | 1970-12-01 |
DE2030326A1 (en) | 1971-01-07 |
FR2046893A1 (en) | 1971-03-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |