GB1407705A - Recovery of metal catalyst - Google Patents

Recovery of metal catalyst

Info

Publication number
GB1407705A
GB1407705A GB5673572A GB5673572A GB1407705A GB 1407705 A GB1407705 A GB 1407705A GB 5673572 A GB5673572 A GB 5673572A GB 5673572 A GB5673572 A GB 5673572A GB 1407705 A GB1407705 A GB 1407705A
Authority
GB
United Kingdom
Prior art keywords
extract
separating
cobalt
manganese
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5673572A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of GB1407705A publication Critical patent/GB1407705A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/0009—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/06—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Abstract

1407705 Recovering cobalt and manganese STANDARD OIL CO 8 Dec 1972 [10 Dec 1971] 56735/72 Heading C1A [Also in Division C2] Cobalt and/or manganese are recovered from catalyst residues also containing iron and which result from the production of aromatic carboxylic acids by (1) extracting the residue with dilute sulphuric acid at a temperature of at least 120‹ F., (2) separating the extract solution from insoluble materials, (3) adding ammonium, an alkali metal or an alkaline earth metal hydroxide to the extract to decrease its pH to 5À0 to 5À5 whereby iron hydroxide is precipitated. (4) separating the iron precipitate from the extract, (5) adding an alkali metal carbonate or bicarbonate to the resulting extract to increase its pH to at least 8À0 whereby cobalt and/or manganese carbonate is precipitated and (6) separating these carbonates from the mother liquor.
GB5673572A 1971-12-10 1972-12-08 Recovery of metal catalyst Expired GB1407705A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US20688471A 1971-12-10 1971-12-10

Publications (1)

Publication Number Publication Date
GB1407705A true GB1407705A (en) 1975-09-24

Family

ID=22768386

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5673572A Expired GB1407705A (en) 1971-12-10 1972-12-08 Recovery of metal catalyst

Country Status (5)

Country Link
JP (1) JPS4866089A (en)
BE (1) BE792519A (en)
DE (1) DE2260498A1 (en)
FR (1) FR2162572B1 (en)
GB (1) GB1407705A (en)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7273559B2 (en) 2004-10-28 2007-09-25 Eastman Chemical Company Process for removal of impurities from an oxidizer purge stream
US7282151B2 (en) 2003-06-05 2007-10-16 Eastman Chemical Company Process for removal of impurities from mother liquor in the synthesis of carboxylic acid using pressure filtration
US7291270B2 (en) 2004-10-28 2007-11-06 Eastman Chemical Company Process for removal of impurities from an oxidizer purge stream
US7351396B2 (en) 2003-06-05 2008-04-01 Eastman Chemical Company Extraction process for removal of impurities from an aqueous mixture
US7381386B2 (en) 2003-06-05 2008-06-03 Eastman Chemical Company Extraction process for removal of impurities from mother liquor in the synthesis of carboxylic acid
US7402694B2 (en) 2005-08-11 2008-07-22 Eastman Chemical Company Process for removal of benzoic acid from an oxidizer purge stream
US7410632B2 (en) 2003-06-05 2008-08-12 Eastman Chemical Company Extraction process for removal of impurities from mother liquor in the synthesis of carboxylic acid
US7452522B2 (en) 2003-06-05 2008-11-18 Eastman Chemical Company Extraction process for removal of impurities from an oxidizer purge stream in the synthesis of carboxylic acid
US7494641B2 (en) 2003-06-05 2009-02-24 Eastman Chemical Company Extraction process for removal of impurities from an oxidizer purge stream in the synthesis of carboxylic acid
US7556784B2 (en) 2004-09-02 2009-07-07 Eastman Chemical Company Optimized production of aromatic dicarboxylic acids
US7569722B2 (en) 2005-08-11 2009-08-04 Eastman Chemical Company Process for removal of benzoic acid from an oxidizer purge stream
US7759516B2 (en) 2006-03-01 2010-07-20 Eastman Chemical Company Versatile oxidation byproduct purge process
US7863481B2 (en) 2006-03-01 2011-01-04 Eastman Chemical Company Versatile oxidation byproduct purge process
US7880032B2 (en) 2006-03-01 2011-02-01 Eastman Chemical Company Versatile oxidation byproduct purge process
US7888530B2 (en) 2004-09-02 2011-02-15 Eastman Chemical Company Optimized production of aromatic dicarboxylic acids
US7897810B2 (en) 2004-09-02 2011-03-01 Eastman Chemical Company Optimized production of aromatic dicarboxylic acids
US7897808B2 (en) 2006-03-01 2011-03-01 Eastman Chemical Company Versatile oxidation byproduct purge process
CN103627904A (en) * 2013-11-29 2014-03-12 湖南邦普循环科技有限公司 Method for recovering cobalt manganese from cobalt manganese catalyst wastes
CN105417584A (en) * 2015-12-09 2016-03-23 西南科技大学 Method for recycling manganese from electrolyzed manganese ore residues
CN106031883A (en) * 2015-03-19 2016-10-19 北京飞潮世辰环境工程技术有限公司 Recovery apparatus and recovery method of cobalt-manganese catalyst by wet method

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1595974A (en) * 1977-04-07 1981-08-19 Ici Ltd Recovering catalyst values
GB8428028D0 (en) * 1984-11-06 1984-12-12 Ici Plc Recovery of metal catalyst residues
JP4788023B2 (en) * 2000-06-27 2011-10-05 三菱瓦斯化学株式会社 Method for recovering catalyst components from liquid phase oxidation reaction mother liquor
KR101189798B1 (en) * 2011-08-17 2012-10-10 한국지질자원연구원 Method for producing cobalt-manganese-acetic acid(cma) catalyst from spent cobalt-manganese-bromine (cmb) catalyst

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB818379A (en) * 1954-10-12 1959-08-19 Electrolytic Metal Corp Propri Treatment of manganese solutions

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7410632B2 (en) 2003-06-05 2008-08-12 Eastman Chemical Company Extraction process for removal of impurities from mother liquor in the synthesis of carboxylic acid
US7470370B2 (en) 2003-06-05 2008-12-30 Eastman Chemical Company Process for removal of impurities from mother liquor in the synthesis of carboxylic acid using pressure filtration
US7494641B2 (en) 2003-06-05 2009-02-24 Eastman Chemical Company Extraction process for removal of impurities from an oxidizer purge stream in the synthesis of carboxylic acid
US7351396B2 (en) 2003-06-05 2008-04-01 Eastman Chemical Company Extraction process for removal of impurities from an aqueous mixture
US7381386B2 (en) 2003-06-05 2008-06-03 Eastman Chemical Company Extraction process for removal of impurities from mother liquor in the synthesis of carboxylic acid
US7452522B2 (en) 2003-06-05 2008-11-18 Eastman Chemical Company Extraction process for removal of impurities from an oxidizer purge stream in the synthesis of carboxylic acid
US7282151B2 (en) 2003-06-05 2007-10-16 Eastman Chemical Company Process for removal of impurities from mother liquor in the synthesis of carboxylic acid using pressure filtration
US7888530B2 (en) 2004-09-02 2011-02-15 Eastman Chemical Company Optimized production of aromatic dicarboxylic acids
US7556784B2 (en) 2004-09-02 2009-07-07 Eastman Chemical Company Optimized production of aromatic dicarboxylic acids
US7959879B2 (en) 2004-09-02 2011-06-14 Grupo Petrotemex, S.A. De C.V. Optimized production of aromatic dicarboxylic acids
US7897810B2 (en) 2004-09-02 2011-03-01 Eastman Chemical Company Optimized production of aromatic dicarboxylic acids
US7291270B2 (en) 2004-10-28 2007-11-06 Eastman Chemical Company Process for removal of impurities from an oxidizer purge stream
US7273559B2 (en) 2004-10-28 2007-09-25 Eastman Chemical Company Process for removal of impurities from an oxidizer purge stream
US7402694B2 (en) 2005-08-11 2008-07-22 Eastman Chemical Company Process for removal of benzoic acid from an oxidizer purge stream
US7569722B2 (en) 2005-08-11 2009-08-04 Eastman Chemical Company Process for removal of benzoic acid from an oxidizer purge stream
US7759516B2 (en) 2006-03-01 2010-07-20 Eastman Chemical Company Versatile oxidation byproduct purge process
US7880032B2 (en) 2006-03-01 2011-02-01 Eastman Chemical Company Versatile oxidation byproduct purge process
US7897808B2 (en) 2006-03-01 2011-03-01 Eastman Chemical Company Versatile oxidation byproduct purge process
US7902395B2 (en) 2006-03-01 2011-03-08 Eastman Chemical Company Versatile oxidation byproduct purge process
US7956215B2 (en) 2006-03-01 2011-06-07 Grupo Petrotemex, S.A. De C.V. Versatile oxidation byproduct purge process
US7863481B2 (en) 2006-03-01 2011-01-04 Eastman Chemical Company Versatile oxidation byproduct purge process
CN103627904A (en) * 2013-11-29 2014-03-12 湖南邦普循环科技有限公司 Method for recovering cobalt manganese from cobalt manganese catalyst wastes
CN106031883A (en) * 2015-03-19 2016-10-19 北京飞潮世辰环境工程技术有限公司 Recovery apparatus and recovery method of cobalt-manganese catalyst by wet method
CN105417584A (en) * 2015-12-09 2016-03-23 西南科技大学 Method for recycling manganese from electrolyzed manganese ore residues

Also Published As

Publication number Publication date
JPS4866089A (en) 1973-09-11
BE792519A (en) 1973-06-08
FR2162572A1 (en) 1973-07-20
FR2162572B1 (en) 1976-06-04
DE2260498A1 (en) 1973-06-14

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years

Effective date: 19921207