GB1364939A - Process for the electrolytic preparation of glycolxylic acid - Google Patents
Process for the electrolytic preparation of glycolxylic acidInfo
- Publication number
- GB1364939A GB1364939A GB3872772A GB3872772A GB1364939A GB 1364939 A GB1364939 A GB 1364939A GB 3872772 A GB3872772 A GB 3872772A GB 3872772 A GB3872772 A GB 3872772A GB 1364939 A GB1364939 A GB 1364939A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- catholyte
- ammonium
- diaphragm
- oxalic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 9
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 abstract 6
- 235000006408 oxalic acid Nutrition 0.000 abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- 229910052787 antimony Inorganic materials 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229910052709 silver Inorganic materials 0.000 abstract 2
- 239000001117 sulphuric acid Substances 0.000 abstract 2
- 235000011149 sulphuric acid Nutrition 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical class CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 abstract 1
- 229910000497 Amalgam Inorganic materials 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 238000005341 cation exchange Methods 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 125000005644 linolenyl group Chemical group 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 abstract 1
- 125000006850 spacer group Chemical group 0.000 abstract 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 abstract 1
- -1 trimethyl - lauryl Chemical group 0.000 abstract 1
- 239000002759 woven fabric Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7130396A FR2151151A5 (enrdf_load_stackoverflow) | 1971-08-20 | 1971-08-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1364939A true GB1364939A (en) | 1974-08-29 |
Family
ID=9082085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3872772A Expired GB1364939A (en) | 1971-08-20 | 1972-08-18 | Process for the electrolytic preparation of glycolxylic acid |
Country Status (13)
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2208876B2 (enrdf_load_stackoverflow) * | 1972-12-01 | 1976-06-04 | Rhone Poulenc Ind | |
| GB1589813A (en) * | 1976-12-31 | 1981-05-20 | Unilever Ltd | Hydrogenation |
| FR2587039B1 (fr) * | 1985-09-10 | 1990-06-08 | Hoechst France | Procede de fabrication d'oxyde glyoxylique par reduction electrochimique d'acide oxalique |
| DE4217336C2 (de) * | 1992-05-26 | 1994-08-04 | Hoechst Ag | Elektrochemisches Verfahren zur Herstellung von Glyoxylsäure |
| DE4217338C2 (de) * | 1992-05-26 | 1994-09-01 | Hoechst Ag | Elektrochemisches Verfahren zur Reduktion von Oxalsäure zu Glyoxylsäure |
| JP5580837B2 (ja) | 2009-01-29 | 2014-08-27 | プリンストン ユニバーシティー | 二酸化炭素の有機生成物への変換 |
| US20110114502A1 (en) * | 2009-12-21 | 2011-05-19 | Emily Barton Cole | Reducing carbon dioxide to products |
| US8721866B2 (en) | 2010-03-19 | 2014-05-13 | Liquid Light, Inc. | Electrochemical production of synthesis gas from carbon dioxide |
| US8845877B2 (en) * | 2010-03-19 | 2014-09-30 | Liquid Light, Inc. | Heterocycle catalyzed electrochemical process |
| US8500987B2 (en) | 2010-03-19 | 2013-08-06 | Liquid Light, Inc. | Purification of carbon dioxide from a mixture of gases |
| US8524066B2 (en) * | 2010-07-29 | 2013-09-03 | Liquid Light, Inc. | Electrochemical production of urea from NOx and carbon dioxide |
| US8845878B2 (en) | 2010-07-29 | 2014-09-30 | Liquid Light, Inc. | Reducing carbon dioxide to products |
| US8961774B2 (en) | 2010-11-30 | 2015-02-24 | Liquid Light, Inc. | Electrochemical production of butanol from carbon dioxide and water |
| US8568581B2 (en) | 2010-11-30 | 2013-10-29 | Liquid Light, Inc. | Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide |
| US9090976B2 (en) | 2010-12-30 | 2015-07-28 | The Trustees Of Princeton University | Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction |
| US8562811B2 (en) | 2011-03-09 | 2013-10-22 | Liquid Light, Inc. | Process for making formic acid |
| BR112014000052A2 (pt) * | 2011-07-06 | 2017-02-07 | Liquid Light Inc | redução de dióxido de carbono em ácidos carboxílicos, glicóis e carboxilatos |
| US8658016B2 (en) | 2011-07-06 | 2014-02-25 | Liquid Light, Inc. | Carbon dioxide capture and conversion to organic products |
| US8858777B2 (en) | 2012-07-26 | 2014-10-14 | Liquid Light, Inc. | Process and high surface area electrodes for the electrochemical reduction of carbon dioxide |
| US20140206896A1 (en) | 2012-07-26 | 2014-07-24 | Liquid Light, Inc. | Method and System for Production of Oxalic Acid and Oxalic Acid Reduction Products |
| US8845876B2 (en) | 2012-07-26 | 2014-09-30 | Liquid Light, Inc. | Electrochemical co-production of products with carbon-based reactant feed to anode |
| US9175407B2 (en) | 2012-07-26 | 2015-11-03 | Liquid Light, Inc. | Integrated process for producing carboxylic acids from carbon dioxide |
| US10329676B2 (en) | 2012-07-26 | 2019-06-25 | Avantium Knowledge Centre B.V. | Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode |
| US8641885B2 (en) | 2012-07-26 | 2014-02-04 | Liquid Light, Inc. | Multiphase electrochemical reduction of CO2 |
| WO2014043651A2 (en) | 2012-09-14 | 2014-03-20 | Liquid Light, Inc. | High pressure electrochemical cell and process for the electrochemical reduction of carbon dioxide |
| EP4251789A1 (en) | 2020-11-26 | 2023-10-04 | Avantium Knowledge Centre B.V. | Process and system for the electrochemical reduction of oxalic acid |
| CN114016059B (zh) * | 2021-11-15 | 2023-03-14 | 东华工程科技股份有限公司 | 一种草酸电解连续制备乙醛酸的方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US798920A (en) * | 1904-01-29 | 1905-09-05 | Emil Von Portheim | Method of reducing oxalic acid and its derivatives by electrolysis. |
| US1013502A (en) * | 1911-03-01 | 1912-01-02 | Roessler & Hasslacher Chemical | Process for the manufacture of glycolic acid. |
-
0
- BE BE787771D patent/BE787771A/xx unknown
-
1971
- 1971-08-20 FR FR7130396A patent/FR2151151A5/fr not_active Expired
-
1972
- 1972-08-11 NL NL7211022A patent/NL7211022A/xx unknown
- 1972-08-17 BR BR005613/72A patent/BR7205613D0/pt unknown
- 1972-08-17 JP JP8185972A patent/JPS5324406B2/ja not_active Expired
- 1972-08-18 DD DD165141A patent/DD98282A5/xx unknown
- 1972-08-18 GB GB3872772A patent/GB1364939A/en not_active Expired
- 1972-08-18 US US00281741A patent/US3779875A/en not_active Expired - Lifetime
- 1972-08-18 SE SE7210791A patent/SE378589B/xx unknown
- 1972-08-18 DE DE2240759A patent/DE2240759C3/de not_active Expired
- 1972-08-18 CA CA149,774A patent/CA1001991A/fr not_active Expired
- 1972-08-18 CH CH1226572A patent/CH541534A/fr not_active IP Right Cessation
- 1972-08-19 IT IT28323/72A patent/IT964102B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| DD98282A5 (enrdf_load_stackoverflow) | 1973-06-12 |
| SE378589B (enrdf_load_stackoverflow) | 1975-09-08 |
| JPS5324406B2 (enrdf_load_stackoverflow) | 1978-07-20 |
| BR7205613D0 (pt) | 1973-08-23 |
| NL7211022A (enrdf_load_stackoverflow) | 1973-02-22 |
| FR2151151A5 (enrdf_load_stackoverflow) | 1973-04-13 |
| IT964102B (it) | 1974-01-21 |
| CH541534A (fr) | 1973-09-15 |
| DE2240759A1 (de) | 1973-03-01 |
| CA1001991A (fr) | 1976-12-21 |
| DE2240759C3 (de) | 1975-04-24 |
| DE2240759B2 (enrdf_load_stackoverflow) | 1974-08-29 |
| US3779875A (en) | 1973-12-18 |
| BE787771A (fr) | 1973-02-19 |
| JPS4829721A (enrdf_load_stackoverflow) | 1973-04-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |