GB1360131A - Process for the production of non-flammable soft-elastic poly urethane foams - Google Patents

Process for the production of non-flammable soft-elastic poly urethane foams

Info

Publication number
GB1360131A
GB1360131A GB973472A GB973472A GB1360131A GB 1360131 A GB1360131 A GB 1360131A GB 973472 A GB973472 A GB 973472A GB 973472 A GB973472 A GB 973472A GB 1360131 A GB1360131 A GB 1360131A
Authority
GB
United Kingdom
Prior art keywords
groups
tolylene diisocyanate
polyether
polyurethane foams
march
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB973472A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1360131A publication Critical patent/GB1360131A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4833Polyethers containing oxyethylene units
    • C08G18/4837Polyethers containing oxyethylene units and other oxyalkylene units
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/721Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7621Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0008Foam properties flexible
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0041Foam properties having specified density
    • C08G2110/005< 50kg/m3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0083Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

1360131 Polyurethane foams BAYER AG 2 March 1972 [3 March 1971] 9734/72 Heading C3R Non-flammable, soft-elastic polyurethane foams are prepared by reacting, in a one-shot process, distilled tolylene diisocyanate which is free from polymeric isocyanates with a polyether having at least two OH groups and a M.W. of 1500 to 10,000, at least 10% by weight of whose OH groups are primary OH groups, and a cross-linking or chain-extending agent of M.W. 62 to 1500 in the presence of water and optionally an organic expanding agent and a catalyst for urethane formation, the reaction being carried out in the absence of polyether/polysiloxane foam stabilizers. Commercial isomers of tolylene diisocyanate or pure 2,4- or 2,6- tolylene diisocyanate preferably may be used. All the polyethers are preferably synthesized using ethylene oxide to introduce the primary OH groups. Suitable cross-linking or chainextending agents include aliphatic, cycloaliphatic or aromatic glycols, aminoalcohols or polyamines. Emulsifiers may also be included in the reaction mixture. In a typical example polyurethane foams are prepared from a reaction mixture comprising a polyether derived from propylene glycol, propylene oxide and ethylene oxide, water, triethylene diamine, 1,4- butane diol and a mixture of the 2,4- and 2,6- isomers of tolylene diisocyanate.
GB973472A 1971-03-03 1972-03-02 Process for the production of non-flammable soft-elastic poly urethane foams Expired GB1360131A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2110055A DE2110055C3 (en) 1971-03-03 1971-03-03 Process for the production of flame-retardant flexible polyurethane foams

Publications (1)

Publication Number Publication Date
GB1360131A true GB1360131A (en) 1974-07-17

Family

ID=5800372

Family Applications (1)

Application Number Title Priority Date Filing Date
GB973472A Expired GB1360131A (en) 1971-03-03 1972-03-02 Process for the production of non-flammable soft-elastic poly urethane foams

Country Status (7)

Country Link
BE (1) BE780186A (en)
DE (1) DE2110055C3 (en)
ES (1) ES400349A1 (en)
FR (1) FR2128562B1 (en)
GB (1) GB1360131A (en)
IT (1) IT952038B (en)
NL (1) NL7202623A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4042537A (en) 1974-05-17 1977-08-16 Bayer Aktiengesellschaft Process for the production of polyurethane foams
US4107102A (en) * 1976-01-05 1978-08-15 Bayer Aktiengesellschaft Highly elastic polyurethane foams and process for making them

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925266A (en) * 1973-06-18 1975-12-09 Gen Tire & Rubber Co Flexible polyetherurethane foams with improved resilience
GB2021604B (en) * 1978-05-08 1982-08-11 Prb Nv Method of preparing polyurea foam materials
US4296213A (en) 1979-10-17 1981-10-20 Texaco Inc. Polyurethane foams using a polyurea polymer polyol

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3098048A (en) * 1958-09-26 1963-07-16 Ind Biology Lab Inc Detergent polyurethane products
US3513491A (en) * 1968-03-13 1970-05-26 Donald W Gordon Athlete's landing pit with foam-block cushion units
GB1296981A (en) * 1969-01-29 1972-11-22

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4042537A (en) 1974-05-17 1977-08-16 Bayer Aktiengesellschaft Process for the production of polyurethane foams
US4107102A (en) * 1976-01-05 1978-08-15 Bayer Aktiengesellschaft Highly elastic polyurethane foams and process for making them

Also Published As

Publication number Publication date
IT952038B (en) 1973-07-20
FR2128562B1 (en) 1977-07-15
DE2110055A1 (en) 1972-09-28
DE2110055B2 (en) 1979-04-05
DE2110055C3 (en) 1981-12-10
NL7202623A (en) 1972-09-05
FR2128562A1 (en) 1972-10-20
BE780186A (en) 1972-09-04
ES400349A1 (en) 1975-01-01

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee