GB1358836A - Treatment of fibres and the fibres thus treated - Google Patents

Treatment of fibres and the fibres thus treated

Info

Publication number
GB1358836A
GB1358836A GB3224070A GB3224070A GB1358836A GB 1358836 A GB1358836 A GB 1358836A GB 3224070 A GB3224070 A GB 3224070A GB 3224070 A GB3224070 A GB 3224070A GB 1358836 A GB1358836 A GB 1358836A
Authority
GB
United Kingdom
Prior art keywords
alkyl
curing
catalysts
polythiol
denotes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3224070A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ciba Geigy UK Ltd
Original Assignee
Ciba Geigy UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy UK Ltd filed Critical Ciba Geigy UK Ltd
Priority to GB3224070A priority Critical patent/GB1358836A/en
Priority to AR23658371A priority patent/AR204605A1/en
Priority to CA116,266A priority patent/CA956755A/en
Priority to ZA714159A priority patent/ZA714159B/en
Priority to CH952471D priority patent/CH952471A4/xx
Priority to CH952471A priority patent/CH547893A/xx
Priority to DE19712132501 priority patent/DE2132501A1/en
Priority to PL14914771A priority patent/PL71574B1/pl
Priority to ES392805A priority patent/ES392805A1/en
Priority to FR7124052A priority patent/FR2104769B1/fr
Priority to AT570471A priority patent/AT318536B/en
Priority to NL7109107A priority patent/NL7109107A/xx
Priority to BE769409A priority patent/BE769409A/en
Priority to US360874A priority patent/US3874848A/en
Publication of GB1358836A publication Critical patent/GB1358836A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/63—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing sulfur in the main chain, e.g. polysulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/334—Polymers modified by chemical after-treatment with organic compounds containing sulfur
    • C08G65/3342—Polymers modified by chemical after-treatment with organic compounds containing sulfur having sulfur bound to carbon and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

1358836 Polyether polythiol textile-treating compositions CIBA-GEIGY (UK) Ltd 14 June 1971 [2 July 1970] 32240/70 Heading C3R [Also in Division D1] Compositions for application to cellulosic fibres comprise polyether polythiols obtained by end-capping polyol-alkylene oxide condensation products with mercapto-carboxylic acids or with epihalohydrin and sodium hydrosulphide, in admixture with aminoplasts free from ethylenic unsaturation. The aminoplast preferably contains at least two -CH 2 OR<SP>4</SP> groups linked to amidic or thioamidic nitrogen, where R<SP>4</SP> is hydrogen, C 1 -C 4 alkyl or acetyl, and may be based on urea, thiourea, or cyclic ureas of Formula I in which Y denotes either a group of Formula II or a C 2 -C 4 divalent group which may be substituted by methyl, methoxy and hydroxy groups, and may be interrupted by -CO-, -O-, or where R<SP>5</SP> denotes an alkyl or hydroxy alkyl group (1-4 C), Q denotes oxygen or sulphur. Further aminoplasts may be based on carbamates and dicarbamates of aliphatic monohydric and dihydric alcohols, and melamine. Curing may take place spontaneously or in the presence of catalysts and under conditions of elevated temperature, which accelerate the curing process. Curing catalysts for the polythiol include: siccatives, e.g. metal naphthenates, oxidizing agents; sulphur; sulphurcontaining compounds, e.g. mercaptobenzothiazoles, dithiocarbamates, thiuram sulphides, thioureas, alkyl xanthates, alkyl xanthogen disulphides and other disulphides; organic bases, e.g. mono- and polyamines; inorganic bases, e.g. sodium hydroxide, phosphate, tetraborate or carbonate; free radical catalysts, e.g. azodiisobutyronitrile, peroxides and hydroperoxides; and heavy metal salts and chelates. Curing catalysts for the aminoplast include latent acid compounds in the form of metal or ammonium salts, strong acids in solution or gaseous form, and organic or inorganic bases. Curing of the polythiol is assisted by high humidities and a pH in the range 7À5-12.
GB3224070A 1970-07-02 1970-07-02 Treatment of fibres and the fibres thus treated Expired GB1358836A (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
GB3224070A GB1358836A (en) 1970-07-02 1970-07-02 Treatment of fibres and the fibres thus treated
AR23658371A AR204605A1 (en) 1970-07-02 1971-01-01 PROCEDURE TO MODIFY CELLULOSE FIBERS AND MATERIALS OBTAINED BY SAID PROCEDURE
CA116,266A CA956755A (en) 1970-07-02 1971-06-22 Process for modifying cellulosic fibres
ZA714159A ZA714159B (en) 1970-07-02 1971-06-25 Treatment of fibres
CH952471D CH952471A4 (en) 1970-07-02 1971-06-29
CH952471A CH547893A (en) 1970-07-02 1971-06-29
DE19712132501 DE2132501A1 (en) 1970-07-02 1971-06-30 Treatment of cellulose fibers
PL14914771A PL71574B1 (en) 1970-07-02 1971-06-30
ES392805A ES392805A1 (en) 1970-07-02 1971-07-01 Procedure to modify the cellulosic fibers. (Machine-translation by Google Translate, not legally binding)
FR7124052A FR2104769B1 (en) 1970-07-02 1971-07-01
AT570471A AT318536B (en) 1970-07-02 1971-07-01 Process for refining cellulose-containing fiber materials
NL7109107A NL7109107A (en) 1970-07-02 1971-07-01
BE769409A BE769409A (en) 1970-07-02 1971-07-02 CELLULOSIC FIBER TREATMENT
US360874A US3874848A (en) 1970-07-02 1973-05-16 Process for treating non-kerations material with a polythiol resin and an aminoplast and the product obtained

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB3224070A GB1358836A (en) 1970-07-02 1970-07-02 Treatment of fibres and the fibres thus treated
US15605271A 1971-06-23 1971-06-23
US360874A US3874848A (en) 1970-07-02 1973-05-16 Process for treating non-kerations material with a polythiol resin and an aminoplast and the product obtained

Publications (1)

Publication Number Publication Date
GB1358836A true GB1358836A (en) 1974-07-03

Family

ID=27259033

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3224070A Expired GB1358836A (en) 1970-07-02 1970-07-02 Treatment of fibres and the fibres thus treated

Country Status (9)

Country Link
US (1) US3874848A (en)
AT (1) AT318536B (en)
BE (1) BE769409A (en)
CA (1) CA956755A (en)
CH (2) CH547893A (en)
DE (1) DE2132501A1 (en)
FR (1) FR2104769B1 (en)
GB (1) GB1358836A (en)
NL (1) NL7109107A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4403011A (en) 1980-12-18 1983-09-06 Ciba-Geigy Corporation Process for the treatment of wool containing material

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1423341A (en) * 1971-12-09 1976-02-04 Iws Nominee Co Ltd Polymer treatmen5 of fibrous and filamentary materials
US8389608B2 (en) 2010-09-09 2013-03-05 Chevron Phillips Chemical Company Lp Aminoplast-polythiol compositions and articles produced therefrom

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3351622A (en) * 1963-09-30 1967-11-07 Stevens & Co Inc J P Polymers and textile materials treated therewith
BE755576A (en) * 1969-09-02 1971-03-01 Ciba Geigy KERATIC FIBER AND TISSUE TREATMENT
ZA71790B (en) * 1970-02-26 1971-10-27 Ciba Geigy Ag Treatment of keratinous fibres and fabrics

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4403011A (en) 1980-12-18 1983-09-06 Ciba-Geigy Corporation Process for the treatment of wool containing material

Also Published As

Publication number Publication date
CH547893A (en) 1974-04-11
CH952471A4 (en) 1973-08-15
US3874848A (en) 1975-04-01
FR2104769B1 (en) 1974-09-06
CA956755A (en) 1974-10-29
DE2132501A1 (en) 1972-01-13
NL7109107A (en) 1972-01-04
BE769409A (en) 1972-01-03
FR2104769A1 (en) 1972-04-21
AT318536B (en) 1974-10-25

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees