GB1338237A - Hydroformylation process - Google Patents

Hydroformylation process

Info

Publication number
GB1338237A
GB1338237A GB5962370A GB5962370A GB1338237A GB 1338237 A GB1338237 A GB 1338237A GB 5962370 A GB5962370 A GB 5962370A GB 5962370 A GB5962370 A GB 5962370A GB 1338237 A GB1338237 A GB 1338237A
Authority
GB
United Kingdom
Prior art keywords
carbon monoxide
rhodium
conducted
triorganophosphorus ligand
atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5962370A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB1338237A publication Critical patent/GB1338237A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
GB5962370A 1969-12-22 1970-12-16 Hydroformylation process Expired GB1338237A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US88737069A 1969-12-22 1969-12-22

Publications (1)

Publication Number Publication Date
GB1338237A true GB1338237A (en) 1973-11-21

Family

ID=25390999

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5962370A Expired GB1338237A (en) 1969-12-22 1970-12-16 Hydroformylation process

Country Status (7)

Country Link
JP (1) JPS511687B1 (de)
BE (1) BE760621A (de)
CA (1) CA918673A (de)
DE (1) DE2062703B2 (de)
FR (1) FR2074101A5 (de)
GB (1) GB1338237A (de)
NL (1) NL172646C (de)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2715685A1 (de) * 1976-04-08 1977-10-13 Union Carbide Corp Kontinuierliches verfahren zur herstellung von aldehyden durch hydroformylierung von alpha-olefinen
DE2730527A1 (de) * 1976-07-07 1978-01-12 Union Carbide Corp Verfahren zur hydroformylierung eines alpha-olefins
US4143075A (en) * 1976-08-12 1979-03-06 Union Carbide Corporation Control of condensation products in hydroformylation process
US4215077A (en) * 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins
EP0017183A2 (de) * 1979-03-28 1980-10-15 Union Carbide Corporation Hydroformylierungsmittel, Verfahren zu dessen Herstellung und Verwendung dieses Hydroformylierungsmittels bei der Herstellung von Aldehyden
US4242284A (en) * 1978-07-27 1980-12-30 Davy International (Oil & Chemicals) Limited Process for recovery of rhodium values and triphenylphosphine from rhodium catalyzed hydroformylation medium
US4260828A (en) * 1980-04-16 1981-04-07 Union Carbide Corporation Hydroformylation process
EP0028378A1 (de) * 1979-10-26 1981-05-13 Union Carbide Corporation Hydroformylierungsverfahren unter Verwendung eines stabilen Rhodiumkatalysators
EP0031590A1 (de) * 1979-12-28 1981-07-08 Union Carbide Corporation Hydroformylierungsverfahren unter Verwendung von Rhodiumkatalysatoren
US4287370A (en) * 1979-03-21 1981-09-01 Davy Mckee (Oil & Chemicals) Limited Hydroformylation process for the production of n-valeraldehyde
US4383125A (en) * 1979-04-11 1983-05-10 Davy Mckee (Oil & Chemicals) Limited Aldehyde-ethers
US4482749A (en) * 1982-06-11 1984-11-13 Davy Mckee (London) Limited Hydroformylation process
US4496769A (en) * 1982-06-11 1985-01-29 Davy Mckee (London) Limited Process for the preparation of aldehydes by hydroformylation of olefins
US4496768A (en) * 1982-06-11 1985-01-29 Davy Mckee Limited Process for the production of aldehydes by hydroformylation of alpha-olefins
US6756411B2 (en) 1995-06-29 2004-06-29 Sasol Technology (Proprietary) Limited Process for producing oxygenated products
US6946580B2 (en) 2001-05-30 2005-09-20 Davy Process Technology Limited Hydroformylation process with recycle of active rhodium catalyst
WO2013095766A1 (en) 2011-12-20 2013-06-27 Dow Technology Investments Llc A hydroformylation process

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2351077A1 (fr) * 1976-05-13 1977-12-09 Celanese Corp Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium
ZA78146B (en) * 1977-01-25 1978-12-27 Union Carbide Corp Improved hydroformylation process
ZA78147B (en) * 1977-01-25 1978-11-29 Union Carbide Corp Improved hydroformylation process
DE2833538C2 (de) * 1978-07-31 1984-09-20 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur Herstellung von α-methylverzweigten Aldehyden
CA2496838A1 (en) 2002-08-31 2004-03-11 Oxeno Olefinchemie Gmbh Process for the hydroformylation of olefinically unsaturated compounds, in particular olefins, in the presence of cyclic carbonic esters

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2779795A (en) * 1954-03-10 1957-01-29 Gulf Research Development Co Hydroformylation of olefins; temperature stabilization
US2790832A (en) * 1954-03-29 1957-04-30 Eastman Kodak Co Directed isomer formation in the oxo reaction
DE1036839B (de) * 1955-02-09 1958-08-21 Chemische Verwertungsgesellsch Verfahren zur Herstellung eines Katalysatorgemisches fuer die Oxo-Synthese durch Beladen von Kohlenoxyd oder Kohlenoxyd-Wasserstoff-Gemischen mit fluechtigen Kobaltcarbonylverbindungen
US2850541A (en) * 1955-09-19 1958-09-02 Standard Oil Co Production of c5 alcohols by improved oxo process
FR1223381A (fr) * 1958-12-17 1960-06-16 Ets Kuhlmann Perfectionnements au procédé de fabrication de composés oxygénés par synthèse oxo
NL146830C (de) * 1960-07-22
US3239566A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
US3290379A (en) * 1961-09-01 1966-12-06 Diamond Alkali Co Selective hydroformylation of olefinic compounds
US3310576A (en) * 1963-02-05 1967-03-21 Exxon Research Engineering Co Hydroformylation catalyst and process relating thereto
DE1518236A1 (de) * 1964-12-15 1972-06-08 Johnson Matthey Co Ltd Katalytische Verfahren
GB1138601A (en) * 1964-12-15 1969-01-01 Geoffrey Wilkinson Improvements in catalytic reactions
US3452348A (en) * 1965-06-29 1969-06-24 Rca Corp Conversion from self-clocking code to nrz code
US3487112A (en) * 1967-04-27 1969-12-30 Monsanto Co Vapor phase hydroformylation process
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
GB1228947A (de) * 1967-10-12 1971-04-21
CA1090823A (en) * 1976-04-08 1980-12-02 Everard A.V. Brewester Cyclic hydroformylation process

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2360544A1 (fr) * 1976-04-08 1978-03-03 Union Carbide Corp Procede de preparation continue d'aldehydes par hydroformylation
DE2715685A1 (de) * 1976-04-08 1977-10-13 Union Carbide Corp Kontinuierliches verfahren zur herstellung von aldehyden durch hydroformylierung von alpha-olefinen
DE2730527A1 (de) * 1976-07-07 1978-01-12 Union Carbide Corp Verfahren zur hydroformylierung eines alpha-olefins
US4143075A (en) * 1976-08-12 1979-03-06 Union Carbide Corporation Control of condensation products in hydroformylation process
US4215077A (en) * 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins
US4242284A (en) * 1978-07-27 1980-12-30 Davy International (Oil & Chemicals) Limited Process for recovery of rhodium values and triphenylphosphine from rhodium catalyzed hydroformylation medium
US4287370A (en) * 1979-03-21 1981-09-01 Davy Mckee (Oil & Chemicals) Limited Hydroformylation process for the production of n-valeraldehyde
EP0017183A2 (de) * 1979-03-28 1980-10-15 Union Carbide Corporation Hydroformylierungsmittel, Verfahren zu dessen Herstellung und Verwendung dieses Hydroformylierungsmittels bei der Herstellung von Aldehyden
EP0017183A3 (en) * 1979-03-28 1981-01-07 Union Carbide Corporation Hydroformylation medium, process of production thereof and process for producing aldehydes using the hydroformylation medium
US4383125A (en) * 1979-04-11 1983-05-10 Davy Mckee (Oil & Chemicals) Limited Aldehyde-ethers
EP0028378A1 (de) * 1979-10-26 1981-05-13 Union Carbide Corporation Hydroformylierungsverfahren unter Verwendung eines stabilen Rhodiumkatalysators
EP0031590A1 (de) * 1979-12-28 1981-07-08 Union Carbide Corporation Hydroformylierungsverfahren unter Verwendung von Rhodiumkatalysatoren
US4260828A (en) * 1980-04-16 1981-04-07 Union Carbide Corporation Hydroformylation process
US4482749A (en) * 1982-06-11 1984-11-13 Davy Mckee (London) Limited Hydroformylation process
US4496769A (en) * 1982-06-11 1985-01-29 Davy Mckee (London) Limited Process for the preparation of aldehydes by hydroformylation of olefins
US4496768A (en) * 1982-06-11 1985-01-29 Davy Mckee Limited Process for the production of aldehydes by hydroformylation of alpha-olefins
US6756411B2 (en) 1995-06-29 2004-06-29 Sasol Technology (Proprietary) Limited Process for producing oxygenated products
US6946580B2 (en) 2001-05-30 2005-09-20 Davy Process Technology Limited Hydroformylation process with recycle of active rhodium catalyst
WO2013095766A1 (en) 2011-12-20 2013-06-27 Dow Technology Investments Llc A hydroformylation process
US9067876B2 (en) 2011-12-20 2015-06-30 Dow Technology Investments Llc Hydroformylation process

Also Published As

Publication number Publication date
NL7018585A (de) 1971-06-24
NL172646C (nl) 1983-10-03
BE760621A (fr) 1971-06-21
JPS511687B1 (de) 1976-01-20
DE2062703A1 (de) 1971-07-01
DE2062703B2 (de) 1981-01-29
NL172646B (nl) 1983-05-02
CA918673A (en) 1973-01-09
FR2074101A5 (de) 1971-10-01

Similar Documents

Publication Publication Date Title
GB1338237A (en) Hydroformylation process
GB1197847A (en) Hydroformylation Process
US4277627A (en) Hydroformylation process
US4283562A (en) Hydroformylation process using stable rhodium catalyst
Schwager et al. Homogeneous olefin hydroformylation catalyzed by ligand stabilized platinum (II)-group IVB metal halide complexes
Paulik Recent developments in hydroformylation catalysis
EP0254937B1 (de) Hydroformylierung unter Verwendung von organischen löslichen Phosphinliganden mit geringer Volatilität
US3821311A (en) Production of aldehydes from olefins
Lloyd Homogeneous oxidations of alcohols with palladium (II) salts
US4052461A (en) Hydroformylation process
CA1090823A (en) Cyclic hydroformylation process
US3040090A (en) Processes of making oxygenated organic compounds
US4262142A (en) Hydroformylation of ethylene with higher olefins
US3832391A (en) Catalysis by dispersions of metal halides in molten trihalostannate (ii) and trihalogermanate (ii) salts
GB1387657A (en) Hydroformylation process
US4288380A (en) Heteronuclear-bridged rhodium clusters
JPS6277343A (ja) ２−メチルブタナ−ルの製造法
Murata et al. Applications of homogeneous water-gas-shift reaction. II. The formation of dipropyl ketones as primary products from CO and H2O in the presence of an excess amount of propene. Cobalt-based catalytic hydrocarbonylation.
US4323513A (en) Production of methyl esters and ethylene glycol esters from reaction of carbon monoxide and hydrogen in presence of ruthenium catalyst
US4244882A (en) Process for continuous production of full esters of polyols
US4592870A (en) Production of methyl esters and ethylene glycol esters from reaction of carbon monoxide and hydrogen in presence of ruthenium catalyst
US4183871A (en) Production of aldehydes and alcohols by the oxo method
US4348539A (en) Heteronuclear-bridged rhodium clusters
US2462738A (en) Synthesis of organic oxygencontaining compounds
GB1197902A (en) Low Pressure Oxo Process

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years