GB1337457A - Process for the preparation of saligenol by electrochemical reduction - Google Patents
Process for the preparation of saligenol by electrochemical reductionInfo
- Publication number
- GB1337457A GB1337457A GB5362771A GB5362771A GB1337457A GB 1337457 A GB1337457 A GB 1337457A GB 5362771 A GB5362771 A GB 5362771A GB 5362771 A GB5362771 A GB 5362771A GB 1337457 A GB1337457 A GB 1337457A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cosolvent
- saligenol
- salicylic acid
- nov
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1337457 Preparing saligenol RHONEPOULENC SA 18 Nov 1971 [19 Nov 1970] 53627/71 Heading C2C [Also in Division C7] Saligenol (2-hydroxy-benzyl alcohol) is prepared by electro-chemical reduction of salicylic acid in a cell having cathode and anode compartments separated by a cation exchange membrane and a catholyte initially comprising salicylic acid, water, a cosolvent and a quarternary ammonium salt. The cosolvent may be an alcohol, ether, a nitrile or an aliphatic amide or ester, preferably ethanol or isopropanol. The quaternary ammonium salt may be a tetraalkylammonium sulphate, phosphate or halide. The catholyte can be one or two liquid phases, the latter preferably being an emulsion. The cathode may be Hg or a solid (e.g. lead) amalgam. The anolyte is preferably an aqueous acid solution, e.g. of H 2 SO 4 , H 3 PO 4 , HNO 3 , HCl, H 3 BO 3 or HBF 4 . The anode may be Pb or alloy thereof, Pt, platinized Ti or graphite. The cell may contain spacers to avoid contact of the membrane with the electrodes. Bells may be grouped in series as filter-press systems. After electrolysis, the cosolvent may be removed from unreduced salicylic acid, e.g. by distillation.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7041498A FR2114195A5 (en) | 1970-11-19 | 1970-11-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1337457A true GB1337457A (en) | 1973-11-14 |
Family
ID=9064393
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5362771A Expired GB1337457A (en) | 1970-11-19 | 1971-11-18 | Process for the preparation of saligenol by electrochemical reduction |
Country Status (9)
Country | Link |
---|---|
US (1) | US3755101A (en) |
BE (1) | BE775519A (en) |
CA (1) | CA938247A (en) |
CH (1) | CH551937A (en) |
DE (1) | DE2157560A1 (en) |
FR (1) | FR2114195A5 (en) |
GB (1) | GB1337457A (en) |
NL (1) | NL7115513A (en) |
SU (1) | SU450396A3 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2407813A (en) * | 2003-05-15 | 2005-05-11 | John Henry Paul Tyman | The solvent extraction of borates by complexation with 1,3- and 1,2-diols derived by semi-synthesis and by separation from natural phenolic lipids |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2208876B2 (en) * | 1972-12-01 | 1976-06-04 | Rhone Poulenc Ind | |
CA1309375C (en) * | 1985-11-26 | 1992-10-27 | Shinji Takenaka | Process for producing m-hydroxybenzyl alcohol |
US5320816A (en) * | 1992-10-21 | 1994-06-14 | The Dow Chemical Company | Process for absorption of sulfur dioxide and nitric oxide from flue gas |
RU2567244C1 (en) * | 2014-12-30 | 2015-11-10 | Федеральное государственное бюджетное учреждение "33 Центральный научно-исследовательский испытательный институт Министерства обороны Российской Федерации" | Method of obtaining o-hydroxybenzyl alcohol (saligenin) |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US12654A (en) * | 1855-04-03 | Improved arrangement of means for freeing steam-boilers from sediments | ||
US815193A (en) * | 1905-10-11 | 1906-03-13 | Basf Ag | Production of aromatic alcohols. |
US3193480A (en) * | 1963-02-01 | 1965-07-06 | Monsanto Co | Adiponitrile process |
-
1970
- 1970-11-19 FR FR7041498A patent/FR2114195A5/fr not_active Expired
-
1971
- 1971-10-29 SU SU1709418A patent/SU450396A3/en active
- 1971-11-11 NL NL7115513A patent/NL7115513A/xx unknown
- 1971-11-18 CH CH1681771A patent/CH551937A/en not_active IP Right Cessation
- 1971-11-18 BE BE775519A patent/BE775519A/en unknown
- 1971-11-18 GB GB5362771A patent/GB1337457A/en not_active Expired
- 1971-11-18 CA CA128179A patent/CA938247A/en not_active Expired
- 1971-11-18 US US00200050A patent/US3755101A/en not_active Expired - Lifetime
- 1971-11-19 DE DE19712157560 patent/DE2157560A1/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2407813A (en) * | 2003-05-15 | 2005-05-11 | John Henry Paul Tyman | The solvent extraction of borates by complexation with 1,3- and 1,2-diols derived by semi-synthesis and by separation from natural phenolic lipids |
Also Published As
Publication number | Publication date |
---|---|
FR2114195A5 (en) | 1972-06-30 |
NL7115513A (en) | 1972-05-24 |
SU450396A3 (en) | 1974-11-15 |
US3755101A (en) | 1973-08-28 |
CH551937A (en) | 1974-07-31 |
CA938247A (en) | 1973-12-11 |
DE2157560A1 (en) | 1972-05-31 |
BE775519A (en) | 1972-03-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |