GB1298401A - Curing cationic sensitive monomers with latent bis(fluoroalkylsulphonyl)methane catalysts - Google Patents

Curing cationic sensitive monomers with latent bis(fluoroalkylsulphonyl)methane catalysts

Info

Publication number
GB1298401A
GB1298401A GB1230770A GB1230770A GB1298401A GB 1298401 A GB1298401 A GB 1298401A GB 1230770 A GB1230770 A GB 1230770A GB 1230770 A GB1230770 A GB 1230770A GB 1298401 A GB1298401 A GB 1298401A
Authority
GB
United Kingdom
Prior art keywords
salt
bis
monomers
clathrate
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1230770A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of GB1298401A publication Critical patent/GB1298401A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/028—Polyamidoamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4064—Curing agents not provided for by the groups C08G59/42 - C08G59/66 sulfur containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/44—Amides
    • C08G59/444—Sulfonamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/687—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2648—Alkali metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669—Non-metals or compounds thereof
    • C08G65/2684—Halogens or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerization Catalysts (AREA)
  • Epoxy Resins (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

1298401 Polymerization catalysts MINNESOTA MINING & MFG CO 13 March 1970 [14 March 1969 (2)] 12307/70 Headings C3B C3P and C3R [Also in Division C2] Monomers which polymerize by ring opening of cyclic groups containing a hetero oxygen or nitrogen atom or which are ethylenically unsaturated and have an oxygen or nitrogen atom attached to one of the carbon atoms of the C=C double bond are polymerized using as catalyst a metal, amine or ammonium salt of a bis-(fluoralkylsulphonyl)methane or a clathrate of I. The salt may have the formula in which R f is perfluoroalkyl, R is H, Br, Cl, alkyl, aryl, alkaryl or R<SP>1</SP>Y in which R<SP>1</SP> is alkylene and Y is OH, CH : CH 2 , COOH, Br, Cl or OCOCR<SP>11</SP>CH 2 where R<SP>11</SP> is H or CH 3 . M is an amino or ammonium cation or mono- or poly-valent metal cation of valency n. Examples of suitable catalysts are (CF 3 SO 2 ) 2 CBrAg, a guinidine or morpholine salt of (CF 3 SO 2 )CH 2 and a clathrate of Dianins compound and (CF 3 SO 2 ) 2 CH 2 . The metal salt may be used in conjunction with an aromatic halide sensitizer and the mixture of monomer, catalyst and sensitizer subjected to U.V. radiation prior to polymerization at elevated temperature. The guidine salt may be used in conjunction with a phenyl carbanilate. Examples of monomers polymerized are hydroxybutyl vinyl ether, diethyleneglycol divinyl ether, N-vinyl-N-methyloctane sulphoxamide, N-vinylpyrollidone, a vinyl ether of a novolak resin, diepoxides, e.g. diglycidyl ethers of bisphenol A, polyglycidyl ethers of novolak resins and cycloaliphatic diepoxides, trioxane and N-(carbethoxymethyl)- aziridine. Specification 1,192,611 and copending Application 12309/70 are referred to.
GB1230770A 1969-03-14 1970-03-13 Curing cationic sensitive monomers with latent bis(fluoroalkylsulphonyl)methane catalysts Expired GB1298401A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US80740769A 1969-03-14 1969-03-14
US80740969A 1969-03-14 1969-03-14

Publications (1)

Publication Number Publication Date
GB1298401A true GB1298401A (en) 1972-12-06

Family

ID=27123011

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1230770A Expired GB1298401A (en) 1969-03-14 1970-03-13 Curing cationic sensitive monomers with latent bis(fluoroalkylsulphonyl)methane catalysts

Country Status (4)

Country Link
CH (1) CH543547A (en)
DE (1) DE2012013C3 (en)
FR (1) FR2038085A1 (en)
GB (1) GB1298401A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2341608A1 (en) * 1976-02-20 1977-09-16 Minnesota Mining & Mfg SOLVENTS TO GIVE A LATENT CHARACTER TO EPOXY SYSTEMS
GB2120263A (en) * 1982-05-17 1983-11-30 Ciba Geigy Ag A process for curing acid-curable abrasive compositions
EP3650486A1 (en) * 2018-11-06 2020-05-13 3M Innovative Properties Company Acid-curable composition

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2479236A1 (en) * 1980-03-27 1981-10-02 France Etat NOVEL HOMOGENEOUS CATIONIC POLYMERIZATION CATALYSTS
JP5696465B2 (en) * 2010-12-17 2015-04-08 セントラル硝子株式会社 Compound having bis (trifluoromethanesulfonyl) ethyl group, acid catalyst, and production method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2341608A1 (en) * 1976-02-20 1977-09-16 Minnesota Mining & Mfg SOLVENTS TO GIVE A LATENT CHARACTER TO EPOXY SYSTEMS
GB2120263A (en) * 1982-05-17 1983-11-30 Ciba Geigy Ag A process for curing acid-curable abrasive compositions
EP3650486A1 (en) * 2018-11-06 2020-05-13 3M Innovative Properties Company Acid-curable composition
WO2020095170A1 (en) * 2018-11-06 2020-05-14 3M Innovative Properties Company Acid-curable composition

Also Published As

Publication number Publication date
DE2012013A1 (en) 1970-10-08
CH543547A (en) 1973-10-31
DE2012013C3 (en) 1980-09-18
DE2012013B2 (en) 1980-01-24
FR2038085A1 (en) 1971-01-08

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years