GB1293356A - Method for the electrolytic deposition of gold alloys and aqueous plating bath therefor - Google Patents
Method for the electrolytic deposition of gold alloys and aqueous plating bath thereforInfo
- Publication number
- GB1293356A GB1293356A GB57431/69A GB5743169A GB1293356A GB 1293356 A GB1293356 A GB 1293356A GB 57431/69 A GB57431/69 A GB 57431/69A GB 5743169 A GB5743169 A GB 5743169A GB 1293356 A GB1293356 A GB 1293356A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ions
- metal
- gold
- bath
- plating bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007747 plating Methods 0.000 title abstract 3
- 229910001020 Au alloy Inorganic materials 0.000 title 1
- 230000008021 deposition Effects 0.000 title 1
- 239000003353 gold alloy Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 150000002500 ions Chemical class 0.000 abstract 5
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- 229910052718 tin Inorganic materials 0.000 abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- 229910001128 Sn alloy Inorganic materials 0.000 abstract 2
- 229910052787 antimony Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- JVPLOXQKFGYFMN-UHFFFAOYSA-N gold tin Chemical compound [Sn].[Au] JVPLOXQKFGYFMN-UHFFFAOYSA-N 0.000 abstract 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 abstract 1
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 abstract 1
- DPZHKLJPVMYFCU-UHFFFAOYSA-N 2-(5-bromopyridin-2-yl)acetonitrile Chemical compound BrC1=CC=C(CC#N)N=C1 DPZHKLJPVMYFCU-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 abstract 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- OVJWUQFCQCZWHW-UHFFFAOYSA-N OC(CC(O)=O)(CC(O)=O)C(O)=O.[AsH3] Chemical compound OC(CC(O)=O)(CC(O)=O)C(O)=O.[AsH3] OVJWUQFCQCZWHW-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 238000005275 alloying Methods 0.000 abstract 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- -1 antimony glycerolate Chemical class 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 230000000536 complexating effect Effects 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- IZLAVFWQHMDDGK-UHFFFAOYSA-N gold(1+);cyanide Chemical compound [Au+].N#[C-] IZLAVFWQHMDDGK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000001508 potassium citrate Substances 0.000 abstract 1
- 229960002635 potassium citrate Drugs 0.000 abstract 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 abstract 1
- 235000011082 potassium citrates Nutrition 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000176 sodium gluconate Substances 0.000 abstract 1
- 229940005574 sodium gluconate Drugs 0.000 abstract 1
- 235000012207 sodium gluconate Nutrition 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
- C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/3235—Esters of poly(thio)phosphinic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/66—Arsenic compounds
- C07F9/70—Organo-arsenic compounds
- C07F9/74—Aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/62—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
1293356 Gold-tin alloy plating baths SEL-REX CORP 24 Nov 1969 [28 Nov 1968] 57431/69 Heading C7B An aqueous gold-tin alloy plating bath contains 1 to 30 g/l Au in the form of an alkali metal (e.g. K) gold cyanide and 0À01 to 100 g/l Sn ions, or ions of Sn and at least one other metal chosen from Groups IIb, IIIb, IVb and Vb, e.g. Sb, In, Bi, Cd, Zn, As, Ga and Pb, added as a stable compound, e.g. antimony glycerolate, arsenic citrate or lead nitrate; with at least one other metal, the bath also contains 5 to 500 g/l of at least one compound capable of complexing the ions of Sn and the or each other metal, e. g. malic, maleic, lactic, gluconic, malonic or citric acid or salt thereof such as sodium gluconate and potassium citrate. The Sn ions may be added in the form of stannous sulphate, chloride or fluorborate with the corresponding sulphuric, hydrochloride or fluorboric acid. The bath may also contain a polyalcohol e.g. glycerine or ethylene glycol. Anodes of Sn or Sn and the or each other metal are used for continuously replenishing alloying ions. The anolyte and catholyte may be separated by a diaphragm.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1771068A CH494284A (en) | 1968-11-28 | 1968-11-28 | Process for the electrolytic deposition of a gold alloy with at least one other common metal and aqueous plating bath for carrying out this process |
| US88095069A | 1969-11-28 | 1969-11-28 | |
| US23847372A | 1972-03-27 | 1972-03-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1293356A true GB1293356A (en) | 1972-10-18 |
Family
ID=27177642
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB57431/69A Expired GB1293356A (en) | 1968-11-28 | 1969-11-24 | Method for the electrolytic deposition of gold alloys and aqueous plating bath therefor |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3764489A (en) |
| AT (1) | AT301290B (en) |
| BE (1) | BE742173A (en) |
| CH (1) | CH494284A (en) |
| DE (1) | DE1960047C2 (en) |
| FR (1) | FR2032280A1 (en) |
| GB (1) | GB1293356A (en) |
| NL (1) | NL6917849A (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4013523A (en) * | 1975-12-24 | 1977-03-22 | Oxy Metal Industries Corporation | Tin-gold electroplating bath and process |
| US4168214A (en) * | 1978-06-14 | 1979-09-18 | American Chemical And Refining Company, Inc. | Gold electroplating bath and method of making the same |
| US4331518A (en) * | 1981-01-09 | 1982-05-25 | Vulcan Materials Company | Bismuth composition, method of electroplating a tin-bismuth alloy and electroplating bath therefor |
| DE3319772A1 (en) * | 1983-05-27 | 1984-11-29 | Schering AG, 1000 Berlin und 4709 Bergkamen | BATH FOR GALVANIC DEPOSITION OF GOLD ALLOYS |
| EP0168705B1 (en) * | 1984-07-05 | 1988-10-19 | Siemens Aktiengesellschaft | Bath and process for electroplating hard gold |
| DE4224012C1 (en) * | 1992-07-21 | 1993-12-02 | Heraeus Gmbh W C | Solderable electric contact element - has silver@-tin@ alloy layer below gold@-tin@ solder alloy layer |
| DE4440176C2 (en) * | 1994-02-05 | 1996-06-27 | Heraeus Gmbh W C | Bath for the electrodeposition of silver-tin alloys |
| EP0666342B1 (en) * | 1994-02-05 | 1998-05-06 | W.C. Heraeus GmbH | Bath for electroplating silver-tin alloys |
| DE4406434C1 (en) * | 1994-02-28 | 1995-08-10 | Heraeus Gmbh W C | Bright gold@-tin@ alloy electroplating bath |
| US20060237324A1 (en) * | 2003-05-21 | 2006-10-26 | Fred Hayward | Pulse plating process for deposition of gold-tin alloy |
| CN101151401A (en) * | 2004-05-11 | 2008-03-26 | 技术公司 | Electroplating solution for gold-tin eutectic alloy |
| WO2006078549A1 (en) * | 2005-01-21 | 2006-07-27 | Technic, Inc. | Pulse plating process for deposition of gold-tin alloy |
| US10260159B2 (en) * | 2013-07-05 | 2019-04-16 | The Boeing Company | Methods and apparatuses for mitigating tin whisker growth on tin and tin-plated surfaces by doping tin with gold |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1111897B (en) * | 1957-08-13 | 1961-07-27 | Sel Rex Corp | Bath for the galvanic deposition of shiny gold alloy coatings |
-
1968
- 1968-11-28 CH CH1771068A patent/CH494284A/en not_active IP Right Cessation
-
1969
- 1969-11-24 GB GB57431/69A patent/GB1293356A/en not_active Expired
- 1969-11-25 BE BE742173D patent/BE742173A/xx unknown
- 1969-11-26 DE DE1960047A patent/DE1960047C2/en not_active Expired
- 1969-11-26 AT AT1106569A patent/AT301290B/en not_active IP Right Cessation
- 1969-11-27 FR FR6940849A patent/FR2032280A1/fr not_active Withdrawn
- 1969-11-27 NL NL6917849A patent/NL6917849A/xx not_active Application Discontinuation
-
1972
- 1972-03-27 US US00238473A patent/US3764489A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AT301290B (en) | 1972-08-25 |
| DE1960047C2 (en) | 1983-04-28 |
| BE742173A (en) | 1970-05-04 |
| US3764489A (en) | 1973-10-09 |
| FR2032280A1 (en) | 1970-11-27 |
| NL6917849A (en) | 1970-06-01 |
| DE1960047A1 (en) | 1970-11-26 |
| CH494284A (en) | 1970-07-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |