GB1286591A - Process for coating surfaces with resins having a modified polyester base which is polymerizable and hardenable by irradiation and coatings obtained by means of said process - Google Patents

Process for coating surfaces with resins having a modified polyester base which is polymerizable and hardenable by irradiation and coatings obtained by means of said process

Info

Publication number
GB1286591A
GB1286591A GB329170A GB329170A GB1286591A GB 1286591 A GB1286591 A GB 1286591A GB 329170 A GB329170 A GB 329170A GB 329170 A GB329170 A GB 329170A GB 1286591 A GB1286591 A GB 1286591A
Authority
GB
United Kingdom
Prior art keywords
polyester
unsaturated
jan
coated
esterifying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB329170A
Inventor
Marie-Francoise Blin
Gilbert Gaussens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA filed Critical Commissariat a lEnergie Atomique CEA
Publication of GB1286591A publication Critical patent/GB1286591A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C09D167/07—Unsaturated polyesters having carbon-to-carbon unsaturation having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
    • C08F299/028—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight photopolymerisable compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
    • C08F299/0485—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters from polyesters with side or terminal unsaturations
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
    • C08F299/0485—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters from polyesters with side or terminal unsaturations
    • C08F299/0492—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters from polyesters with side or terminal unsaturations the unsaturation being in acrylic or methacrylic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
    • C08F299/065—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes from polyurethanes with side or terminal unsaturations
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Polymerisation Methods In General (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

1286591 Coating surfaces COMMISSARIAT A L'ENERGIE ATOMIQUE 23 Jan 1970 [31 Jan 1969] 3291/70 Heading C3P Surfaces are coated by preparing a saturated or unsaturated polyester by esterifying saturated or unsaturated dibasic acids or the corresponding anhydrides with polyhydric alcohols, esterifying all or part of the hydroxyl groups remaining in the polyester chain with unsaturated monocarboxylic acids, mixing the polyester as thus modified with at least one ethylenically unsaturated monomer(s) which is/are copolymerizable under the action of ionizing radiation and which is/are added in a proportion by weight of between 10 and 60% of the mixture, applying the mixture to the surface to be coated in a layer having a thickness of between 10 and 500 Á, and curing the coating by copolymerization of the modified polyester and of the monomer(s) and under the action of ionizing radiation at a dose of between 0À1 and 100 Mrads. In the examples polyesters are prepared from phthalic anhydride, maleic anhydride, glycerol and succinic acid and are esterified with methacrylic acid in the presence of hydroquinone and copolymerized with ethyl acrylate or styrene in the presence of titanium dioxide using an electron beam on wood, metal or concrete panels.
GB329170A 1969-01-31 1970-01-23 Process for coating surfaces with resins having a modified polyester base which is polymerizable and hardenable by irradiation and coatings obtained by means of said process Expired GB1286591A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR6902225A FR2030505A5 (en) 1969-01-31 1969-01-31

Publications (1)

Publication Number Publication Date
GB1286591A true GB1286591A (en) 1972-08-23

Family

ID=9028496

Family Applications (3)

Application Number Title Priority Date Filing Date
GB329170A Expired GB1286591A (en) 1969-01-31 1970-01-23 Process for coating surfaces with resins having a modified polyester base which is polymerizable and hardenable by irradiation and coatings obtained by means of said process
GB329470A Expired GB1302515A (en) 1969-01-31 1970-01-23
GB1256823D Expired GB1256823A (en) 1969-01-31 1970-01-23

Family Applications After (2)

Application Number Title Priority Date Filing Date
GB329470A Expired GB1302515A (en) 1969-01-31 1970-01-23
GB1256823D Expired GB1256823A (en) 1969-01-31 1970-01-23

Country Status (11)

Country Link
JP (3) JPS4944567B1 (en)
BE (3) BE745038A (en)
CA (1) CA977482A (en)
CH (4) CH526597A (en)
DE (4) DE2003819A1 (en)
ES (4) ES375935A1 (en)
FR (1) FR2030505A5 (en)
GB (3) GB1286591A (en)
LU (4) LU60252A1 (en)
NL (3) NL155875C (en)
SU (1) SU378020A3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49120981A (en) * 1973-03-22 1974-11-19

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5921909B2 (en) 1974-10-31 1984-05-23 東レ株式会社 Radiation curable coating composition
JPS52100757U (en) * 1976-01-27 1977-07-30
JPS547473A (en) * 1977-06-20 1979-01-20 Konishiroku Photo Ind Method of treating surface of plastic material
US4537811A (en) * 1978-04-24 1985-08-27 Energy Sciences, Inc. Electron beam irradiating process for rendering rough or topographically irregular surface substrates smooth; and coated substrates produced thereby
US4273633A (en) * 1979-06-11 1981-06-16 Union Carbide Corporation Radiation curable dispersions containing high molecular weight essentially nonpolymerizable vinyl resins
BE888519A (en) * 1981-04-22 1981-10-22 Gni I P Institutlakokrasochnoi COMPOSITION FOR PAINTS AND VARNISHES
AU2188383A (en) * 1982-12-30 1984-07-05 Valspar Corporation, The Acrylic grafted pvc polymers
DE3721849A1 (en) * 1987-07-02 1989-01-12 Bayer Ag SHEET DUROPLAST COMPONENTS, METHOD FOR THEIR PRODUCTION AND THEIR USE IN THE CONSTRUCTION OF VEHICLES
DE4228401A1 (en) * 1992-08-26 1994-03-03 Basf Lacke & Farben Powder coatings

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3252935A (en) * 1960-06-20 1966-05-24 Dow Chemical Co Vinyl chloride polymer composition and method of coating therewith
FR1510477A (en) * 1961-03-20 1968-01-19 Ford Motor Co New coating process
FR1437795A (en) * 1964-05-15 1966-05-06 Gen Motors Corp Polymerizable coating composition, and coatings obtained
FR1485874A (en) * 1965-06-30 1967-06-23 Berger Johann Process for the production of a stabilized surface coating
GB1159119A (en) * 1965-08-13 1969-07-23 Ford Motor Co Polymerisable Paint Binders and a Coating Method Employing such Binders
FR1549956A (en) * 1967-03-02 1968-12-13

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49120981A (en) * 1973-03-22 1974-11-19
JPS5430431B2 (en) * 1973-03-22 1979-10-01

Also Published As

Publication number Publication date
BE745038A (en) 1970-07-01
ES375936A1 (en) 1973-03-16
ES375938A1 (en) 1973-03-16
SU378020A3 (en) 1973-04-17
CH526597A (en) 1972-08-15
ES375935A1 (en) 1973-03-16
DE2003817C3 (en) 1982-06-16
BE745037A (en) 1970-07-01
JPS4944567B1 (en) 1974-11-29
JPS4944568B1 (en) 1974-11-29
LU60253A1 (en) 1970-04-01
LU60251A1 (en) 1970-04-01
DE2003819A1 (en) 1970-08-06
CA977482A (en) 1975-11-04
CH520187A (en) 1972-03-15
CH526623A (en) 1972-08-15
DE2003818A1 (en) 1970-08-06
DE2003820A1 (en) 1970-08-06
NL7001331A (en) 1970-08-04
LU60254A1 (en) 1970-04-01
GB1302515A (en) 1973-01-10
NL7001328A (en) 1970-08-04
BE745036A (en) 1970-07-01
NL155875C (en) 1980-10-15
CH520186A (en) 1972-03-15
NL155875B (en) 1978-02-15
DE2003820B2 (en) 1974-12-12
ES375937A1 (en) 1973-03-16
DE2003817B2 (en) 1978-05-24
NL7001329A (en) 1970-08-04
LU60252A1 (en) 1970-04-01
DE2003817A1 (en) 1970-08-06
FR2030505A5 (en) 1970-11-13
GB1256823A (en) 1971-12-15
JPS5015252B1 (en) 1975-06-03

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee