GB1274718A - Metal oxide acylates - Google Patents
Metal oxide acylatesInfo
- Publication number
- GB1274718A GB1274718A GB3310969A GB3310969A GB1274718A GB 1274718 A GB1274718 A GB 1274718A GB 3310969 A GB3310969 A GB 3310969A GB 3310969 A GB3310969 A GB 3310969A GB 1274718 A GB1274718 A GB 1274718A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acylate
- metal
- carbon atoms
- metal oxide
- monocarboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910044991 metal oxide Inorganic materials 0.000 title abstract 13
- 150000004706 metal oxides Chemical class 0.000 title abstract 7
- 229910052751 metal Inorganic materials 0.000 abstract 16
- 239000002184 metal Substances 0.000 abstract 16
- 125000004432 carbon atom Chemical group C* 0.000 abstract 14
- -1 metal oxide acylate Chemical class 0.000 abstract 12
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical group CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 abstract 10
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract 10
- 125000004429 atom Chemical group 0.000 abstract 6
- 239000004411 aluminium Substances 0.000 abstract 5
- 229910052782 aluminium Inorganic materials 0.000 abstract 5
- 238000000034 method Methods 0.000 abstract 5
- 150000004703 alkoxides Chemical group 0.000 abstract 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 3
- 239000010936 titanium Substances 0.000 abstract 3
- 229910052719 titanium Inorganic materials 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 229940077746 antacid containing aluminium compound Drugs 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910001338 liquidmetal Inorganic materials 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/025—Silicon compounds without C-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
1,274,718. Metal oxide acylates. J. RINSE. 1 July, 1969 [2 July, 1968; 11 Oct., 1968], No. 33109/69. Heading C2C. [Also in Divisions C3 and C4] Metal oxide acylates are prepared by reaction of (a) at least one metal component selected from polyvalent metals and oxides, hydroxides and carbonates thereof, with (b) at least one volatile monocarboxylic acid having from 1 to 5 carbon atoms and (c) at least one monocarboxylic acid having at least 7 carbon atoms (preferably the molar ratio of metal to monocarboxylic acid having at least 7 carbon atoms is at least 1:1) to produce a metal oxide acylate, wherein at least one valency of each metal atom derived from the metal component is satisfied by an acylate group and each of the remaining valencies is satisfied either by an oxygen atom which is attached to another metal atom or by an acylate group, which process includes distilling the product at a temperature of from 100‹ to 250‹ C., and during the distillation adding a liberating agent for the volatile monocarboxylic acid whereby to liberate said volatile acid and obtain a metal oxide acylate wherein at least 55 mole per cent of the acylate content is of monocarboxylic acid having at least 7 carbon atoms, the liberating agent being selected from one or more of water, steam, a volatile alcohol, an aluminium alkoxide wherein each alkoxide group has at most four carbon atoms, a titanium alcoholate, wherein each alcoholate group has at most four carbon atoms, and a condensed titanium silicon alkoxide, wherein each alkoxide group has at most four carbon atoms, the amount of aluminium alkoxide, titanium alcoholate or condensed titanium silicon alkoxide used being not greater than 10% by weight of the metal oxide acylate product. In the above process, reactants (a) and (b) may be replaced by at least one salt of a polyvalent metal and a volatile monocarboxylic acid having from 1 to 5 carbon atoms. Novel compositions comprise a metal oxide acylate having at least two metal atoms other than aluminium bound to each other through an oxygen bridge and in which each metal atom has a valence number of at least two and is bound only to oxygen atoms and at least 55 mol. per cent of the acylate content is derived from monocarboxylic acid having at least 7 carbon atoms, the remainder of the acylate if any being derived from monocarboxylic acid having less than 7 carbon atoms, the molar ratio of metal to acylate in the composition being in excess of 1:1, and the excess metal being in a finely divided, stable, dispersed state as metal oxide are prepared by the above process if excess metal oxide (a) is used. Novel liquid (metal oxide acylate)/(metal alkoxide) reaction products, the metal oxide acylate having at least two metal atoms other than aluminium bound to each other through an oxygen bridge and in which each metal atom has a valence number of at least two and is bound only to oxygen atoms and at least 55 mol. per cent of the acylate content is derived from monocarboxylic acid having at least 7 carbon atoms, the remainder of the acylate if any being derived from monocarboxylic acid having less than 7 carbon atoms, the metal alkoxide comprising at most 10% by weight based on the weight of said metal oxide acylate and being selected from the group consisting of aluminium alcoholate, titanium alcoholate and condensed titanium silicon alkoxide are prepared by the above process when the liberating agent is other than water or an alcohol. Novel metal compounds of formulµ XMOMX, XMOM<SP>11</SP>(X) 2 OMX and (X) 2 M<SP>1</SP>OM<SP>11</SP>(X) 2 OM<SP>1</SP>(X) 2 (other than aluminium compounds), wherein each X is an acylate group, each M, M<SP>1</SP> and M<SP>11</SP> are divalent, trivalent and tetravalent metals respectively and at least 55 mol. per cent of the total acylate content of the compound is derived from a carboxylic acid having at least 7 carbon atoms, the remainder being derived from a carboxylic acid having less than 7 carbon atoms, are also claimed and are obtainable from the above process. Wood preservatives comprise liquid metal oxide acylates referred to above or solutions of the above metal oxide acylates.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74189968A | 1968-07-02 | 1968-07-02 | |
| US76697668A | 1968-10-11 | 1968-10-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1274718A true GB1274718A (en) | 1972-05-17 |
Family
ID=27113938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3310969A Expired GB1274718A (en) | 1968-07-02 | 1969-07-01 | Metal oxide acylates |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1933612C2 (en) |
| GB (1) | GB1274718A (en) |
| NL (1) | NL162627C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006109194A2 (en) * | 2005-01-27 | 2006-10-19 | Ocean Nutrition Canada Ltd. | Chromium-fatty acid compounds and methods of making and using thereof |
| US8034450B2 (en) | 2005-01-21 | 2011-10-11 | Ocean Nutrition Canada Limited | Microcapsules and emulsions containing low bloom gelatin and methods of making and using thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB825878A (en) * | 1957-07-25 | 1959-12-23 | Hardman & Holden Ltd | Improvements relating to polymeric reaction products of aluminium alkoxides |
| US3054816A (en) * | 1958-06-30 | 1962-09-18 | Agrashell Inc | Cyclic alkoxy- and phenoxy-aluminum oxide trimers and process for making same |
| DE1202275B (en) * | 1960-10-31 | 1965-10-07 | Dr Jacobus Rinse | Process for the preparation of stereotetrameric oxometal alcoholates, phenolates or acylates of metals of group IV of the Periodic Table |
| NL289227A (en) * | 1962-02-23 | 1900-01-01 | ||
| NL130971C (en) * | 1963-12-23 | 1900-01-01 |
-
1969
- 1969-07-01 GB GB3310969A patent/GB1274718A/en not_active Expired
- 1969-07-02 NL NL6910177A patent/NL162627C/en not_active IP Right Cessation
- 1969-07-02 DE DE19691933612 patent/DE1933612C2/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8034450B2 (en) | 2005-01-21 | 2011-10-11 | Ocean Nutrition Canada Limited | Microcapsules and emulsions containing low bloom gelatin and methods of making and using thereof |
| WO2006109194A2 (en) * | 2005-01-27 | 2006-10-19 | Ocean Nutrition Canada Ltd. | Chromium-fatty acid compounds and methods of making and using thereof |
| WO2006109194A3 (en) * | 2005-01-27 | 2006-12-07 | Ocean Nutrition Canada Ltd | Chromium-fatty acid compounds and methods of making and using thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| NL162627B (en) | 1980-01-15 |
| NL6910177A (en) | 1970-01-06 |
| DE1933612C2 (en) | 1984-02-09 |
| NL162627C (en) | 1980-06-16 |
| DE1933612A1 (en) | 1970-10-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLE | Entries relating assignments, transmissions, licences in the register of patents | ||
| PCNP | Patent ceased through non-payment of renewal fee |