GB825878A - Improvements relating to polymeric reaction products of aluminium alkoxides - Google Patents

Improvements relating to polymeric reaction products of aluminium alkoxides

Info

Publication number
GB825878A
GB825878A GB20971/56A GB2097156A GB825878A GB 825878 A GB825878 A GB 825878A GB 20971/56 A GB20971/56 A GB 20971/56A GB 2097156 A GB2097156 A GB 2097156A GB 825878 A GB825878 A GB 825878A
Authority
GB
United Kingdom
Prior art keywords
acids
reaction
acid
oil
aluminium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20971/56A
Inventor
Samuel Edward Harson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borax Europe Ltd
Original Assignee
Hardman and Holden Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hardman and Holden Ltd filed Critical Hardman and Holden Ltd
Publication of GB825878A publication Critical patent/GB825878A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M5/00—Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/10—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/105—Silica
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/22—Acids obtained from polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/102—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/09—Complexes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/06—Groups 3 or 13
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy

Abstract

Polymeric organic aluminium compounds suitable for use in lubricating oils and greases are prepared by heating aluminium alkoxides with water and, if desired, with monocarboxylic acids, alcohols and/or phenols, the reaction being continued until two mols. of alkoxide alcohol have been removed per mol. of water added. The reaction may be effected with the reactants specified in any order or simultaneously. The mono-carboxylic acids may be aliphatic, particularly short branched chain acids, cycloaliphatic, aromatic or substituted aromatic. Up to 20% of the mono-carboxylic acid may be replaced by di- or poly-carboxylic acids or other acidic materials such as halogenated acids, sulphur-treated fatty acids, phosphatidic acids, silicic acids, medium ot high molecular weight phosphonic acids, sulphonic acids, dimerized fatty acids having 11 or more carbon atoms, still bottom residues, or polyester resins. Convenient forms of aluminium alkoxide for use as starting material are aluminium isopropoxide and butoxides, but alkoxides derived from halogenated or substituted alcohols or alcohols having 11 or more carbon atoms may be used. The reaction may be carried out in an inert diluent, e.g. a medium boiling solvent such as benzene or toluene, a lubricating oil, or an aromatic solvent of minimum boiling point 200 DEG C. depending on the use to be made of the reaction products. The aluminium alkoxide starting material may be prepared in situ. The products may be cyclic, possibly of formula <FORM:0825878/III/1> or linear, of possible formula <FORM:0825878/III/2> where each X is acyl, alkoxy or phenoxy. The primary polymeric products may be reacted with further acid, alcohol or phenol, which may be different from those used in the first step. Thus reaction of a cyclic structure with further acid HY could give successively <FORM:0825878/III/3> and then <FORM:0825878/III/4> Hydrolysis with water of the primary products will produce soaps AlX2OH and AlX(OH)2 (when HX is an acid). Many examples are given of the production of polymers starting from aluminium isopropoxide and sec.-butoxide in spindle oil, an aromatic petroleum fraction, a naphthenic blended base oil, or toluene, by reaction with water, other reactants or modifiers being one or two materials selected from stearic, lauric, myristic, behenic, oleic, isooctanoic acids; tall oil, coconut oil, hydrogenated fish oil, hydrogenated castor oil and montan wax acids; sebacic, adipic and azelaic acid dimerized fatty acid, terephthalic acid, dimerized rosin, run Congo resin, non-drying alkyd resin; 2-ethyl-hexanol, cetyl alcohol; o- and m-cresol and o-phenylphenol; p-toluenesulphonic acid; and precipitated silica. The products, when prepared or dissolved in lubricating oils, serve as oils and greases. Known additives such as anti-wear and anti-corrosion additives may be added.ALSO:Polymeric organic aluminium compounds are prepared by heating aluminium alkoxides with water and, if desired, with monocarboxylic acids, alcohols and/or phenols, the reaction being continued until two mols. of alkoxide alcohol have been removed per mol. of water added. The reaction may be effected with the reactants specified in any order or simultaneously. The mono-carboxylic acids may be aliphatic, particularly short branched chain acids, cycloaliphatic, aromatic or substituted aromatic. Up to 20% of the mono-carboxylic acid may be replaced by di- or poly-carboxylic acids or other acidic materials such as halogenated acids, sulphur treated fatty acids, phosphatidic acids, silicic acids, medium to high molecular weight phosphonic acids, sulphonic acids, dimerized fatty acids having 11 or more carbon atoms, still bottom residues, or polyester resins. Convenient forms of aluminium alkoxide for use as starting material are aluminium isopropoxide and butoxides, but alkoxides derived from halogenated or substituted alcohols or alcohols having 11 or more carbon atoms may be used. The reaction may be carried out in an inert diluent, e.g. a medium boiling solvent such as benzene or toluene, a lubricating oil, or an aromatic solvent of minimum boiling point 200 DEG C., depending on the use to be made of the reaction products. The aluminium alkoxide starting material may be prepared in situ. The products may be cyclic, possibly of formula <FORM:0825878/IV (b)/1> or linear, of possible formula <FORM:0825878/IV (b)/2> where each X is acyl, alkoxy or phenoxy. The primary polymeric products may be reacted with further acid, alcohol or phenol, which may be different from those used in the first step. Thus reaction of a cyclic structure with further acid HY could give successively <FORM:0825878/IV (b)/3> and then <FORM:0825878/IV (b)/4> and <FORM:0825878/IV (b)/5> Hydrolysis with water of the primary products will produce soaps AlX2OH and AlX(OH)2 (when HX is an acid). Many examples are given of the production of polymers starting from aluminium isopropoxide and sec.-butoxide in spindle oil, an aromatic petroleum fraction, a naphthenic blended base oil, or toluene, by reaction with water, other reactants being one or two materials selected from stearic, lauric, myristic, behenic, oleic, iso-octanoic acids; tall oil, coconut oil, hydrogenated fish oil, hydrogenated castor oil and montan wax acids; sebacic, adipic and azelaic acids; dimerized fatty acid, terephthalic acid, dimerex resin, run Congo resin, non-drying alkyd resin; 2-ethylhexanol, cetyl alcohol; o- and m-cresol and o-phenylphenol; p-toluenesulphonic acid; and precipitated silica.ALSO:Polymeric organic aluminium compounds are prepared by heating aluminium alkoxides with water and, if desired, with mono-carboxylic acids, alcohols and/or phenols, the reaction being continued until two mols. of alkoxide alcohol have been removed per mol. of water added. The reaction may be effected with the reactants specified in any order or simultaneously. The mono-carboxylic acids may be aliphatic, particularly short-branched chain acids, cycloaliphatic, aromatic or substituted aromatic. Up to 20% of the mono-carboxylic acid may be replaced by di- or poly-carboxylic acids or other acidic materials such as halogenated acids, sulphur treated fatty acids, phosphatidic acids, silicic acids, medium to high molecular weight phosphonic acids, sulphonic acids, dimerized fatty acids having 11 or more carbon atoms, still bottom residues, or polyester resins. Convenient forms of aluminium alkoxide for use as starting material are alumnium isopropoxide and butoxides, but alkoxides derived from halogenated or substituted alcohols or alcohols having 11 or more carbon atoms may be used. The reaction may be carried out in an inert diluent, e.g. a medium boiling solvent such as benzene or toluene, a lubricating oil, or an aromatic solvent of minimum boiling point 200 DEG C., depending on the use to be made of the reaction products. The alcohol corresponding to the Al alkoxide may also be present as a volatile diluent. The aluminium alkoxide starting material may be prepared in situ, using mercuric chloride as catalyst. The products may be cyclic, possibly of formula <FORM:0825878/IV (a)/1> or linear, of possible formula <FORM:0825878/IV (a)/2> where each X is acyl, alkoxy or phenoxy. The primary polymeric products may be reacted with further acid, alcohol or phenol, which may be different from those used in the first step. Thus reaction of a cyclic structure with further acid HY could give successively <FORM:0825878/IV (a)/3> and then <FORM:0825878/IV (a)/4> and <FORM:0825878/IV (a)/5> Hydrolysis with water of the primary products will produce soaps AlX2OH and AlX(OH)2 (when HX is an acid). Many examples are given of the production of polymers starting from p aluminium isopropoxide and sec.-butoxide in spindle oil, an aromatic petroleum fraction, a naphthenic blended base oil, or toluene, by reaction with water, other reactants being one or two materials selected from benzoic, stearic, lauric, myristic, behenic, oleic, iso-octanoic acids; tall oil, coconut oil, hydrogenated fish oil, hydrogenated castor oil and montan wax acids; sebacic, adipic and azelaic acids; dimerized fatty acid, terephthalic acid, dimerex resin, run Congo resin, non-drying alkyd resin; 2 - ethyl - hexanol, cetyl alcohol; o - and m-cresol and o-phenylphenol; p-toluenesulphonic acid; and precipitated silica. Other reagents mentioned but not exemplified include phenol, alkyl phenols of C4 or more alkyl groups, higher alcohols of at least C8, and halogenated alcohols. The resins may be compounded with: bitumens, asphalts, waxes, natural oils, fats, hydrogenated castor oil, finely-divided silica, dimerized rosin, chlorinated polyesters, the mineral oils exemplified, xylene, toluene, chlorinated diphenyl, chlorinated paraffin wax, aromatic oils, sebacate phthalate and phosphate esters of monohydric alcohols, polyglycols, polyalkylene oxide esters of monocarboxylic acids, polyalkylene oxide ethers of monohydric alcohols and the oligomeric and monomeric compounds indicated in the formul above. Uses.-Lubricating greases; thickeners; paints; inks; putties; lutings; linoleum.
GB20971/56A 1957-07-25 1956-07-06 Improvements relating to polymeric reaction products of aluminium alkoxides Expired GB825878A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEH0030727 1957-07-25

Publications (1)

Publication Number Publication Date
GB825878A true GB825878A (en) 1959-12-23

Family

ID=7151457

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20971/56A Expired GB825878A (en) 1957-07-25 1956-07-06 Improvements relating to polymeric reaction products of aluminium alkoxides

Country Status (2)

Country Link
DE (1) DE1420505A1 (en)
GB (1) GB825878A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3089853A (en) * 1959-10-14 1963-05-14 British Petroleum Co Lubricating oil compositions and the operation of internal combustion engines
US3113054A (en) * 1960-03-18 1963-12-03 British Petroleum Co Quenching oil and method of quenching metals
DE1173472B (en) * 1959-04-13 1964-07-09 Hardman & Holden Ltd Process for the preparation of organic aluminum compounds useful as medicinal products
DE1265901B (en) * 1962-01-17 1968-04-11 British Petroleum Co Cutting oil
US3518287A (en) * 1967-07-05 1970-06-30 Jacobus Rinse Metal oxide acylates and their process of preparation
DE1933612A1 (en) * 1968-07-02 1970-10-01 Rinse Dr Jacobus Metal oxide acylates and processes for their preparation
US3625934A (en) * 1968-07-02 1971-12-07 Jacobus Rinse Oligomers of mixed tetravalent element oxides
FR2156682A1 (en) * 1971-10-01 1973-06-01 Unilever Emery
EP0029589A2 (en) * 1979-11-23 1981-06-03 Chattem, Inc. Process for making grease compositions
US4280917A (en) 1979-11-23 1981-07-28 Chattem, Inc. Grease compositions and oxyaluminum acylate intermediate compositions useful in the preparation thereof
US4303538A (en) * 1980-11-04 1981-12-01 Chattem, Inc. Grease compositions and oxyaluminum acylate intermediate compositions useful in the preparation thereof
US4324670A (en) * 1979-11-23 1982-04-13 Chattem, Inc. Process for making a mixed oxyaluminum acylate composition useful in grease manufacture
EP0121241A1 (en) * 1983-03-30 1984-10-10 Idemitsu Kosan Company Limited Process for the production of high molecular weight organoaluminum polymers
EP0207787A2 (en) * 1985-07-01 1987-01-07 Minnesota Mining And Manufacturing Company Industrial gelling agent for hydrophobic organic liquids
DE4011783A1 (en) * 1989-05-03 1990-11-08 Komaromi Koeolajipari Vallalat Aluminium oxide carboxylate polymer prodn. - by reaction of aluminium alcoholate, mono:carboxylic acid and water to give lower ester content
US4981608A (en) * 1988-04-22 1991-01-01 Minnesota Mining And Manufacturing Company Industrial gelling agent for hydrophobic organic liquids
CN112661179A (en) * 2019-10-16 2021-04-16 中国石油化工股份有限公司 Preparation method of high-purity alumina

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018780B1 (en) * 1979-04-30 1983-08-03 Manchem Limited An aluminium complex, method for its preparation and air-drying compositions containing it

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1173472B (en) * 1959-04-13 1964-07-09 Hardman & Holden Ltd Process for the preparation of organic aluminum compounds useful as medicinal products
US3089853A (en) * 1959-10-14 1963-05-14 British Petroleum Co Lubricating oil compositions and the operation of internal combustion engines
US3113054A (en) * 1960-03-18 1963-12-03 British Petroleum Co Quenching oil and method of quenching metals
DE1270064B (en) * 1960-03-18 1968-06-12 British Petroleum Co Oil for quenching heat-treated metal alloys
DE1265901B (en) * 1962-01-17 1968-04-11 British Petroleum Co Cutting oil
US3518287A (en) * 1967-07-05 1970-06-30 Jacobus Rinse Metal oxide acylates and their process of preparation
DE1933612A1 (en) * 1968-07-02 1970-10-01 Rinse Dr Jacobus Metal oxide acylates and processes for their preparation
US3625934A (en) * 1968-07-02 1971-12-07 Jacobus Rinse Oligomers of mixed tetravalent element oxides
FR2156682A1 (en) * 1971-10-01 1973-06-01 Unilever Emery
US4280917A (en) 1979-11-23 1981-07-28 Chattem, Inc. Grease compositions and oxyaluminum acylate intermediate compositions useful in the preparation thereof
EP0029589A2 (en) * 1979-11-23 1981-06-03 Chattem, Inc. Process for making grease compositions
EP0029589A3 (en) * 1979-11-23 1982-03-03 Chattem, Inc. Grease compositions, oxyaluminum acylate intermediate compositions useful in the preparation thereof, and process for making such
US4324670A (en) * 1979-11-23 1982-04-13 Chattem, Inc. Process for making a mixed oxyaluminum acylate composition useful in grease manufacture
US4303538A (en) * 1980-11-04 1981-12-01 Chattem, Inc. Grease compositions and oxyaluminum acylate intermediate compositions useful in the preparation thereof
EP0121241A1 (en) * 1983-03-30 1984-10-10 Idemitsu Kosan Company Limited Process for the production of high molecular weight organoaluminum polymers
EP0207787A2 (en) * 1985-07-01 1987-01-07 Minnesota Mining And Manufacturing Company Industrial gelling agent for hydrophobic organic liquids
EP0207787A3 (en) * 1985-07-01 1988-08-10 Minnesota Mining And Manufacturing Company Industrial gelling agent for hydrophobic organic liquids
AU602463B2 (en) * 1985-07-01 1990-10-11 Minnesota Mining And Manufacturing Company Organoaluminium gelling agent
US4981608A (en) * 1988-04-22 1991-01-01 Minnesota Mining And Manufacturing Company Industrial gelling agent for hydrophobic organic liquids
DE4011783A1 (en) * 1989-05-03 1990-11-08 Komaromi Koeolajipari Vallalat Aluminium oxide carboxylate polymer prodn. - by reaction of aluminium alcoholate, mono:carboxylic acid and water to give lower ester content
US5075473A (en) * 1989-05-03 1991-12-24 Komaromi Koolajipari V. Process for the preparation of aluminum oxide carboxylate polymers containing at most two percent by weight of ester
CN112661179A (en) * 2019-10-16 2021-04-16 中国石油化工股份有限公司 Preparation method of high-purity alumina

Also Published As

Publication number Publication date
DE1420505A1 (en) 1968-10-24

Similar Documents

Publication Publication Date Title
GB825878A (en) Improvements relating to polymeric reaction products of aluminium alkoxides
US2599553A (en) Complex aluminum soap
US2621195A (en) Polymeric titanium compounds
US2621193A (en) Polymeric titanium compounds
US3296242A (en) Metal-acyloxy compounds and method of preparing same
US3027325A (en) Oil-soluble calcium carbonate dispersions and method of preparation
US2844551A (en) Aluminum compounds and the process of preparing them
EP0609260B1 (en) Improved overbased carboxylates
US2681922A (en) Polymeric zirconium compounds and method of preparing same
US2979497A (en) Cyclic aluminum oxide acylates, alkoxides, and phenoxides
EP0118203A2 (en) Polyborate esters and their use in lubricants
DE60309060T2 (en) METHOD FOR ALKYLATING SALICYLIC ACID
US2925430A (en) Polymeric basic aluminum compounds of organic acids
US2779737A (en) Complex calcium salts of oxidized petroleum oils and process for preparing the same
US3035069A (en) Treatment of epoxy fatty compositions
US3461146A (en) Metal-organic compounds
US2252665A (en) Metal salts of alkyl substituted aryl ether acids and method of making them
US2252663A (en) Alkyl substituted aryl metal hydroxylate and method of making it
US4056479A (en) Magnesium carboxylate-sulfonate complexes
US3383395A (en) Stabilization of organic materials with biphenyltriols
US2626939A (en) Alkyds and varnishes comprising same
US2948743A (en) Oxo-aluminum acylates, alkoxides and phenoxides
US2307885A (en) Lubricating product
US3277128A (en) Reaction product of a polymerized 1, 2-alkylene imine and an epoxy, thioethoxy or hydroxy aromatic compound, each containing an oleophilic group of at least 10 carbon atoms
GB692172A (en) Oleaginous compositions suitable for use as hydraulic fluids and lubricants