GB1274545A - DERIVATIVES OF 4,4'-BIS(s-TRIAZINYLAMINO)-STILBENE-2,2'-DISULPHONIC ACID, AND PROCESSES FOR THEIR MANUFACTURE AND USE AS OPTICAL BRIGHTENERS - Google Patents
DERIVATIVES OF 4,4'-BIS(s-TRIAZINYLAMINO)-STILBENE-2,2'-DISULPHONIC ACID, AND PROCESSES FOR THEIR MANUFACTURE AND USE AS OPTICAL BRIGHTENERSInfo
- Publication number
- GB1274545A GB1274545A GB35888/69A GB3588869A GB1274545A GB 1274545 A GB1274545 A GB 1274545A GB 35888/69 A GB35888/69 A GB 35888/69A GB 3588869 A GB3588869 A GB 3588869A GB 1274545 A GB1274545 A GB 1274545A
- Authority
- GB
- United Kingdom
- Prior art keywords
- paper
- alkyl
- triazinylamino
- stilbene
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
- C07D251/68—Triazinylamino stilbenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Wood Science & Technology (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
- Detergent Compositions (AREA)
Abstract
1,274,545. Optically brightening cellulosic materials. FARBWERKE HOECHST A.G. 16 July, 1969 [22 July, 1968], No. 35888/69. Heading D1P. [Also in Division C2] . Fibrous materials, e.g. paper or cotton, are optically brightened by treatment with a 4, 4'- bis-(s-triazinylamino)-stilbene-2, 2'-disulphonic acid derivative of the general formula: wherein A and A' are each a bivalent C 2-8 hydrocarbon radical which may be substituted by non-chromophoric radicals, R<SP>1</SP> and R<SP>2</SP> are each a hydrogen atom or a C 1-5 alkyl group, R<SP>3</SP>, R<SP>4</SP>, R<SP>5</SP> and R<SP>6</SP> are each a C 1-5 alkyl, cycloalkyl, aralkyl or aryl group, or R<SP>3</SP> and R<SP>4</SP> and/or R<SP>5</SP> and R<SP>6</SP>, together with the nitrogen atom to which they are attached, form a saturated heterocyclic ring, R<SP>7</SP> and R<SP>8</SP> are each a hydrogen atom or a C 1-5 alkyl or benzyl group and X- is a colourless anion. The brighteners may be added, in liquid form or dissolved in water, to paper pulp, optionally before the addition of auxiliary agents such as rosin size or aluminium sulphate and the pulp is thoroughly mixed before forming sheets; or alternatively they may be used in coating mixtures for paper. They may be used together with cationic softening agents for fabrics and knitted fabrics of cellulose fibres and fibres of regenerated cellulose; or they may be used together with auxiliary agents for the crease-proofing of cellulose fibres.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1095368A CH525991A (en) | 1968-07-22 | 1968-07-22 | Process for the optical brightening of textile materials, especially made of natural or regenerated cellulose |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1274545A true GB1274545A (en) | 1972-05-17 |
Family
ID=4368547
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB35888/69A Expired GB1274545A (en) | 1968-07-22 | 1969-07-16 | DERIVATIVES OF 4,4'-BIS(s-TRIAZINYLAMINO)-STILBENE-2,2'-DISULPHONIC ACID, AND PROCESSES FOR THEIR MANUFACTURE AND USE AS OPTICAL BRIGHTENERS |
Country Status (11)
Country | Link |
---|---|
US (1) | US3663538A (en) |
AT (1) | AT294751B (en) |
BE (1) | BE736364A (en) |
CH (3) | CH525991A (en) |
DE (1) | DE1930307C3 (en) |
DK (1) | DK137755B (en) |
FR (1) | FR2013466A1 (en) |
GB (1) | GB1274545A (en) |
NL (1) | NL6911208A (en) |
NO (1) | NO125051B (en) |
SE (1) | SE346539B (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4012378A (en) * | 1972-02-11 | 1977-03-15 | Imperial Chemical Industries Limited | Reactive dyestuffs |
GB1441109A (en) * | 1973-01-23 | 1976-06-30 | Ici Ltd | Coating compositions |
CH597204A5 (en) * | 1973-02-16 | 1978-03-31 | Sandoz Ag | |
CH603878B5 (en) * | 1973-09-21 | 1978-08-31 | Hoechst Ag | |
DE2915323A1 (en) * | 1978-04-26 | 1979-11-08 | Sandoz Ag | BASIC OR CATIONIC MONOAZO OR DISAZO COMPOUNDS CONTAINING SULPHONIC ACID GROUPS |
ATE4600T1 (en) * | 1979-09-21 | 1983-09-15 | The Procter & Gamble Company | DETERGENT AND SOAK COMPOSITIONS AND PROCESS FOR THEIR MANUFACTURE. |
EP0059684B1 (en) * | 1981-02-26 | 1984-06-13 | Ciba-Geigy Ag | Amphoteric styrene derivatives |
GB9626851D0 (en) * | 1996-12-24 | 1997-02-12 | Ciba Geigy Ag | Compounds |
GB9930247D0 (en) * | 1999-12-22 | 2000-02-09 | Clariant Int Ltd | Improvements in or relating to organic compounds |
GB9930177D0 (en) * | 1999-12-22 | 2000-02-09 | Clariant Int Ltd | Improvements in or relating to organic compounds |
JP2005529854A (en) * | 2002-03-19 | 2005-10-06 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | Amphoteric and cationic fluorescent whitening agents |
CN1835933A (en) * | 2003-08-21 | 2006-09-20 | 西巴特殊化学品控股有限公司 | Optical brighteners |
US8262744B2 (en) | 2010-05-18 | 2012-09-11 | Milliken & Company | Optical brighteners and compositions comprising the same |
EP2571941A2 (en) | 2010-05-18 | 2013-03-27 | Milliken & Company | Optical brighteners and compositions comprising the same |
USD840116S1 (en) | 2017-04-19 | 2019-02-05 | Gramercy Products, Inc. | Ball toy |
-
1968
- 1968-07-22 CH CH1095368A patent/CH525991A/en not_active IP Right Cessation
- 1968-07-22 CH CH631672A patent/CH534170A/en not_active IP Right Cessation
- 1968-07-22 CH CH1095368D patent/CH1095368A4/xx unknown
-
1969
- 1969-06-14 DE DE1930307A patent/DE1930307C3/en not_active Expired
- 1969-07-07 US US839640A patent/US3663538A/en not_active Expired - Lifetime
- 1969-07-15 NO NO2955/69A patent/NO125051B/no unknown
- 1969-07-16 GB GB35888/69A patent/GB1274545A/en not_active Expired
- 1969-07-21 SE SE10243/69A patent/SE346539B/xx unknown
- 1969-07-21 AT AT698769A patent/AT294751B/en not_active IP Right Cessation
- 1969-07-21 DK DK392469AA patent/DK137755B/en unknown
- 1969-07-22 NL NL6911208A patent/NL6911208A/xx unknown
- 1969-07-22 BE BE736364D patent/BE736364A/xx unknown
- 1969-07-22 FR FR6924879A patent/FR2013466A1/fr not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
DK137755B (en) | 1978-05-01 |
US3663538A (en) | 1972-05-16 |
AT294751B (en) | 1971-12-10 |
DE1930307C3 (en) | 1979-03-15 |
CH1095368A4 (en) | 1972-03-30 |
FR2013466A1 (en) | 1970-04-03 |
BE736364A (en) | 1970-01-22 |
DK137755C (en) | 1978-10-09 |
SE346539B (en) | 1972-07-10 |
NL6911208A (en) | 1970-01-26 |
DE1930307A1 (en) | 1970-02-12 |
DE1930307B2 (en) | 1978-06-15 |
CH534170A (en) | 1973-02-28 |
NO125051B (en) | 1972-07-10 |
CH525991A (en) | 1972-03-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |