GB1299120A - Stilbene compounds and their use as optical brighteners - Google Patents
Stilbene compounds and their use as optical brightenersInfo
- Publication number
- GB1299120A GB1299120A GB58647/70A GB5864770A GB1299120A GB 1299120 A GB1299120 A GB 1299120A GB 58647/70 A GB58647/70 A GB 58647/70A GB 5864770 A GB5864770 A GB 5864770A GB 1299120 A GB1299120 A GB 1299120A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radical
- formula
- mols
- optionally substituted
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/14—Styryl dyes
- C09B23/148—Stilbene dyes containing the moiety -C6H5-CH=CH-C6H5
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Coloring (AREA)
Abstract
1299120 Optical brighteners SANDOZ Ltd 10 Dec 1970 [11 Dec 1969] 58647/70 Heading C2C [Also in Division D1] Novel compounds of the general Formula I wherein each of X and Y represents an optionally substituted phenylamino radical or a radical of Formula II or of the Formula III and wherein each of T and Z represents a radical of Formula II or III, R represents H or C 1-5 alkyl optionally substituted by one or more hydroxy, alkoxy, cyano, aminocarbonyl, phenyl, phenoxy or cresoxy radicals, R 1 represents H or C 1-5 alkyl, R 2 represents OH, CN, or CO 2 R 7 radical, each of R 3 and R 4 represents C 1-5 alkyl or hydroxyalkyl or R 3 and R 4 together with the N atom form a saturated heterocyclic radical, R 7 is C 1-5 alkyl optionally substituted by OH, alkoxy, phenoxy, cresoxy or phenyl, M represents an alkali metal, an ammonium radical or an equivalent of an alkaline earth metal, anion<SP>(-)</SP> represents a colourless anion, m is 1-3, n is 1 or 2, p is 2-6, provided that the molecule is devoid of a chromophoric radical and contains as the only anionic watersolubilizing groups the two sulphonic acid groups attached to the stilbene residue, and protonization and quaternization products of these compounds, are prepared by reacting 2 mols. of a cyanuric halide with (a) 1 mol. of 4,4<SP>1</SP>-diaminostilbene - 2,2<SP>1</SP> - disulphonic acid or a salt thereof, (b) 0-2 mols. of an optionally substituted aminobenzene and (c) 2-4 mols. of an amine of Formula IV (or mixture thereof) with the proviso that (b)+(c) amount in all to 4 mols., the product being protonized, quaternized or salified if necessary.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1842569A CH529770A (en) | 1969-12-11 | 1969-12-11 | Process for the preparation of new stilbene compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1299120A true GB1299120A (en) | 1972-12-06 |
Family
ID=4432886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB58647/70A Expired GB1299120A (en) | 1969-12-11 | 1970-12-10 | Stilbene compounds and their use as optical brighteners |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3757010A (en) |
| JP (2) | JPS527011B1 (en) |
| BE (1) | BE760178A (en) |
| CH (1) | CH529770A (en) |
| DE (1) | DE2060085A1 (en) |
| ES (1) | ES386268A1 (en) |
| FR (1) | FR2073529A5 (en) |
| GB (1) | GB1299120A (en) |
| NL (1) | NL7018032A (en) |
| ZA (1) | ZA708379B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH597204A5 (en) * | 1973-02-16 | 1978-03-31 | Sandoz Ag | |
| CH583211A5 (en) * | 1973-05-22 | 1976-12-31 | Sandoz Ag | |
| CH583212A5 (en) * | 1973-07-02 | 1976-12-31 | Sandoz Ag | |
| CH603878B5 (en) * | 1973-09-21 | 1978-08-31 | Hoechst Ag | |
| CH590965A5 (en) * | 1973-12-19 | 1977-08-31 | Ciba Geigy Ag | |
| DE2712686C2 (en) * | 1977-03-23 | 1986-09-04 | Bayer Ag, 5090 Leverkusen | 4-Triazinyl-4'-benzoxazolyl or 4'-phenyl-stilbene derivatives |
| ATE7898T1 (en) * | 1981-02-26 | 1984-06-15 | Ciba-Geigy Ag | AMPHOTERE STYRENE DERIVATIVES. |
| DE3922494A1 (en) * | 1989-07-08 | 1991-01-17 | Bayer Ag | FLUESSIGWASCHMITTEL |
| US5319126A (en) * | 1993-01-29 | 1994-06-07 | Akzo N.V. | α-aminonitriles derived from fatty alkyl alkylene diamines |
| GB9930247D0 (en) * | 1999-12-22 | 2000-02-09 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| GB9930177D0 (en) * | 1999-12-22 | 2000-02-09 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| WO2003078406A1 (en) * | 2002-03-19 | 2003-09-25 | Ciba Specialty Chemicals Holding Inc. | Amphoteric and cationic fluorescent whitening agents |
| EP1511901B1 (en) * | 2002-06-11 | 2007-07-04 | Ciba SC Holding AG | Whitening pigments |
| CN102898855B (en) * | 2012-09-29 | 2013-12-11 | 山东大学 | Synthesis and application of cetyl or octadecyl dimethyl tertiary amine quaternary ammonium salt high performance fluorescent whitening agent having amino acid structure |
-
1969
- 1969-12-11 CH CH1842569A patent/CH529770A/en not_active IP Right Cessation
-
1970
- 1970-12-07 US US00095935A patent/US3757010A/en not_active Expired - Lifetime
- 1970-12-07 DE DE19702060085 patent/DE2060085A1/en active Pending
- 1970-12-09 ES ES386268A patent/ES386268A1/en not_active Expired
- 1970-12-10 BE BE760178A patent/BE760178A/en unknown
- 1970-12-10 JP JP45110044A patent/JPS527011B1/ja active Pending
- 1970-12-10 GB GB58647/70A patent/GB1299120A/en not_active Expired
- 1970-12-10 NL NL7018032A patent/NL7018032A/xx unknown
- 1970-12-10 FR FR7044483A patent/FR2073529A5/en not_active Expired
- 1970-12-11 ZA ZA708379A patent/ZA708379B/en unknown
-
1972
- 1972-11-10 JP JP47112819A patent/JPS4924127B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ES386268A1 (en) | 1974-01-01 |
| NL7018032A (en) | 1971-06-15 |
| JPS527011B1 (en) | 1977-02-26 |
| US3757010A (en) | 1973-09-04 |
| ZA708379B (en) | 1972-07-26 |
| FR2073529A5 (en) | 1971-10-01 |
| BE760178A (en) | 1971-05-17 |
| DE2060085A1 (en) | 1971-06-16 |
| CH529770A (en) | 1972-10-31 |
| JPS4924127B1 (en) | 1974-06-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |