GB1228479A - - Google Patents
Info
- Publication number
- GB1228479A GB1228479A GB4613968A GB1228479DA GB1228479A GB 1228479 A GB1228479 A GB 1228479A GB 4613968 A GB4613968 A GB 4613968A GB 1228479D A GB1228479D A GB 1228479DA GB 1228479 A GB1228479 A GB 1228479A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dimethyl
- accelerator
- acid
- toluidene
- sept
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/04—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving separate application of adhesive ingredients to the different surfaces to be joined
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/20—Esters of polyhydric alcohols or polyhydric phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
1,228,479. Anaerobic polymerization. BORDEN CHEMICAL CO. (U.K.) Ltd. 15 Sept., 1969 [27 Sept., 1968], No. 46139/68. Heading C3P. [Also in Division F2] Anaerobic polymerization e.g. between two surfaces which are being adhered together, is brought about by bringing two compositions, both of which are stable in the presence of air, the first composition containing a major proportion of an anaerobically curing monomer and a minor proportion of a first accelerator moiety (defined) and the second composition containing a similar monomer and a second accelerator moiety complementary to the first (defined), so that when both compositions are brought together in the absence of air, polymerization occurs. Preferred monomers are those having the formulµ where R is H, -CH 3 , -C 2 H 5 , -CH 2 OH or R<SP>1</SP> is -H, -Cl, -CH 3 or -C 2 H 5 ; R<SP>11</SP> is H, -OH or x and y are each integers equal to at least 1 and n is 0 or 1; where R<SP>1</SP>, R<SP>11</SP>, n and y are as above, x<SP>1</SP> is 0 or an integer, z is 1, 2, 3 or 4 and Q is an organic radical with a valency of z; where R<SP>1</SP> is as above, and R<SP>111</SP> is -H, -CH 3 or -C 2 H 5 . The first accelerator is preferably an amine such as N,N - dimethyl - p - toluidene with, or replaced by, N,N - dimethyl aniline, N,N- diethylaniline, N,N - di - # - hydroxyethylaniline, N,N - dimethyl - m - toluidene, N,N- dimethyl - p - anisidine, triethylamine, trin - butylamine or 2 - diethylaminoethanol. The second accelerator is preferably a sulphimide such as saccharin (2,3 - benzisothiazolinone- 1,1 - dioxide), but this can be replaced by or used with a hydroperoxide such as cumene hydroperoxide or a peroxide such as 2,5 - dimethyl- 2,5 - di(tertiary butyl peroxy) hexane, or benzoic acid, or phenoxyacetic acid, dichloroacetic acid or trichloroacetic acid. Examples 1- 13 describe the use of the monomers, tetraethyleneglycol dimethacrylate, the monoacrylate ester of dimethyleneglycol monomethylether, hexamethyleneglycol dimethacrylate, pentaerythrityl tetrakis (dimethylene glycol acrylate), and a mixture of tetraethyleneglycol dimethacrylate and N-methyl methacrylamide, with some of the above accelerator moieties.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4613968 | 1968-09-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1228479A true GB1228479A (en) | 1971-04-15 |
Family
ID=10440007
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4613968A Expired GB1228479A (en) | 1968-09-27 | 1968-09-27 |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE739465A (en) |
DE (1) | DE1948782A1 (en) |
FR (1) | FR2018998A1 (en) |
GB (1) | GB1228479A (en) |
NL (1) | NL6914623A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4500629A (en) * | 1982-04-08 | 1985-02-19 | Ciba-Geigy Corporation | Method of forming images from liquid masses |
CN102229539A (en) * | 2011-05-12 | 2011-11-02 | 东北农业大学 | Synthetic process for 4-iodo-phenoxyacetic acid diethylaminoethanol ester |
US10414846B2 (en) | 2014-12-22 | 2019-09-17 | Arkema France | Liquid (meth)acrylic syrup, method for impregnating a fibrous substrate with said syrup, and composite material produced after polymerisation of said impregnation syrup |
-
1968
- 1968-09-27 GB GB4613968A patent/GB1228479A/en not_active Expired
-
1969
- 1969-09-22 FR FR6932105A patent/FR2018998A1/fr not_active Withdrawn
- 1969-09-26 NL NL6914623A patent/NL6914623A/xx not_active Application Discontinuation
- 1969-09-26 DE DE19691948782 patent/DE1948782A1/en active Pending
- 1969-09-26 BE BE739465D patent/BE739465A/xx unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4500629A (en) * | 1982-04-08 | 1985-02-19 | Ciba-Geigy Corporation | Method of forming images from liquid masses |
CN102229539A (en) * | 2011-05-12 | 2011-11-02 | 东北农业大学 | Synthetic process for 4-iodo-phenoxyacetic acid diethylaminoethanol ester |
US10414846B2 (en) | 2014-12-22 | 2019-09-17 | Arkema France | Liquid (meth)acrylic syrup, method for impregnating a fibrous substrate with said syrup, and composite material produced after polymerisation of said impregnation syrup |
Also Published As
Publication number | Publication date |
---|---|
BE739465A (en) | 1970-03-02 |
FR2018998A1 (en) | 1970-06-26 |
DE1948782A1 (en) | 1970-09-10 |
NL6914623A (en) | 1970-04-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PLE | Entries relating assignments, transmissions, licences in the register of patents | ||
PCNP | Patent ceased through non-payment of renewal fee |