GB1228479A - - Google Patents

Info

Publication number
GB1228479A
GB1228479A GB4613968A GB1228479DA GB1228479A GB 1228479 A GB1228479 A GB 1228479A GB 4613968 A GB4613968 A GB 4613968A GB 1228479D A GB1228479D A GB 1228479DA GB 1228479 A GB1228479 A GB 1228479A
Authority
GB
United Kingdom
Prior art keywords
dimethyl
accelerator
acid
toluidene
sept
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4613968A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1228479A publication Critical patent/GB1228479A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/04—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving separate application of adhesive ingredients to the different surfaces to be joined
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/20—Esters of polyhydric alcohols or polyhydric phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

1,228,479. Anaerobic polymerization. BORDEN CHEMICAL CO. (U.K.) Ltd. 15 Sept., 1969 [27 Sept., 1968], No. 46139/68. Heading C3P. [Also in Division F2] Anaerobic polymerization e.g. between two surfaces which are being adhered together, is brought about by bringing two compositions, both of which are stable in the presence of air, the first composition containing a major proportion of an anaerobically curing monomer and a minor proportion of a first accelerator moiety (defined) and the second composition containing a similar monomer and a second accelerator moiety complementary to the first (defined), so that when both compositions are brought together in the absence of air, polymerization occurs. Preferred monomers are those having the formulµ where R is H, -CH 3 , -C 2 H 5 , -CH 2 OH or R<SP>1</SP> is -H, -Cl, -CH 3 or -C 2 H 5 ; R<SP>11</SP> is H, -OH or x and y are each integers equal to at least 1 and n is 0 or 1; where R<SP>1</SP>, R<SP>11</SP>, n and y are as above, x<SP>1</SP> is 0 or an integer, z is 1, 2, 3 or 4 and Q is an organic radical with a valency of z; where R<SP>1</SP> is as above, and R<SP>111</SP> is -H, -CH 3 or -C 2 H 5 . The first accelerator is preferably an amine such as N,N - dimethyl - p - toluidene with, or replaced by, N,N - dimethyl aniline, N,N- diethylaniline, N,N - di - # - hydroxyethylaniline, N,N - dimethyl - m - toluidene, N,N- dimethyl - p - anisidine, triethylamine, trin - butylamine or 2 - diethylaminoethanol. The second accelerator is preferably a sulphimide such as saccharin (2,3 - benzisothiazolinone- 1,1 - dioxide), but this can be replaced by or used with a hydroperoxide such as cumene hydroperoxide or a peroxide such as 2,5 - dimethyl- 2,5 - di(tertiary butyl peroxy) hexane, or benzoic acid, or phenoxyacetic acid, dichloroacetic acid or trichloroacetic acid. Examples 1- 13 describe the use of the monomers, tetraethyleneglycol dimethacrylate, the monoacrylate ester of dimethyleneglycol monomethylether, hexamethyleneglycol dimethacrylate, pentaerythrityl tetrakis (dimethylene glycol acrylate), and a mixture of tetraethyleneglycol dimethacrylate and N-methyl methacrylamide, with some of the above accelerator moieties.
GB4613968A 1968-09-27 1968-09-27 Expired GB1228479A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4613968 1968-09-27

Publications (1)

Publication Number Publication Date
GB1228479A true GB1228479A (en) 1971-04-15

Family

ID=10440007

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4613968A Expired GB1228479A (en) 1968-09-27 1968-09-27

Country Status (5)

Country Link
BE (1) BE739465A (en)
DE (1) DE1948782A1 (en)
FR (1) FR2018998A1 (en)
GB (1) GB1228479A (en)
NL (1) NL6914623A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4500629A (en) * 1982-04-08 1985-02-19 Ciba-Geigy Corporation Method of forming images from liquid masses
CN102229539A (en) * 2011-05-12 2011-11-02 东北农业大学 Synthetic process for 4-iodo-phenoxyacetic acid diethylaminoethanol ester
US10414846B2 (en) 2014-12-22 2019-09-17 Arkema France Liquid (meth)acrylic syrup, method for impregnating a fibrous substrate with said syrup, and composite material produced after polymerisation of said impregnation syrup

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4500629A (en) * 1982-04-08 1985-02-19 Ciba-Geigy Corporation Method of forming images from liquid masses
CN102229539A (en) * 2011-05-12 2011-11-02 东北农业大学 Synthetic process for 4-iodo-phenoxyacetic acid diethylaminoethanol ester
US10414846B2 (en) 2014-12-22 2019-09-17 Arkema France Liquid (meth)acrylic syrup, method for impregnating a fibrous substrate with said syrup, and composite material produced after polymerisation of said impregnation syrup

Also Published As

Publication number Publication date
BE739465A (en) 1970-03-02
FR2018998A1 (en) 1970-06-26
DE1948782A1 (en) 1970-09-10
NL6914623A (en) 1970-04-01

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLE Entries relating assignments, transmissions, licences in the register of patents
PCNP Patent ceased through non-payment of renewal fee