GB1205786A - Process for the manufacture of n-carbamoyloxyphenyl-carbamates - Google Patents
Process for the manufacture of n-carbamoyloxyphenyl-carbamatesInfo
- Publication number
- GB1205786A GB1205786A GB44736/67A GB4473667A GB1205786A GB 1205786 A GB1205786 A GB 1205786A GB 44736/67 A GB44736/67 A GB 44736/67A GB 4473667 A GB4473667 A GB 4473667A GB 1205786 A GB1205786 A GB 1205786A
- Authority
- GB
- United Kingdom
- Prior art keywords
- denote
- amine
- reaction
- formula
- carbamates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Incineration Of Waste (AREA)
- Furan Compounds (AREA)
Abstract
1,205,786. Substituted phenyl carbamates. SCHERING A.G. 2 Oct., 1967 [15 Oct., 1966], No. 44736/67. Heading C2C. The invention comprises a process of preparing N-carbamoyloxyphenyl carbamates of the formula in which R 4 and R 5 denote hydrogen atoms or aliphatic hydrocarbon groups and R 1 , R 2 and R 3 denote aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic groups, any of which may carry one or more specified substituents, including halogen atoms and alkyl, halogenalkyl and alkoxy groups; alternatively, R 1 and R 2 may denote hydrogen atoms or, together with the adjacent nitrogen atom, may denote a heterocyclic group that may contain at least one further nitrogen atom or an oxygen atom. The process of the invention consists in reacting a compound of the formula in which X denotes a hydrogen atom, a monovalent metal or an ammonium, N-alkylammonium, N,N-dialkylammonium or N,N,N- trialkyl-anunonium group, with phosgene in the presence of an amine of the formula R 6 N(R 1 )R 2 , in which R 6 denotes a hydrogen atom or an aliphatic hydrocarbon group. In a modification of the process, the reaction of phosgene with the N-hydroxyphenyl urethane, which yields a chloroformic ester, may precede the reaction with the amine R 6 N(R 1 )R 2 . The reaction may be effected at 0-100‹ C., optionally in the presence of a solvent and an acid-binding agent, which may be an excess of the amine. A number of phenyl urethanes and amines for use as starting materials are specified, and numerous products obtainable by the process of the invention are listed.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DESC039678 | 1966-10-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1205786A true GB1205786A (en) | 1970-09-16 |
Family
ID=7435280
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB44736/67A Expired GB1205786A (en) | 1966-10-15 | 1967-10-02 | Process for the manufacture of n-carbamoyloxyphenyl-carbamates |
Country Status (17)
Country | Link |
---|---|
JP (1) | JPS5140073B1 (en) |
BE (1) | BE705071A (en) |
BR (1) | BR6792549D0 (en) |
CH (1) | CH487128A (en) |
CS (1) | CS151462B2 (en) |
CY (1) | CY610A (en) |
DE (1) | DE1593523A1 (en) |
ES (1) | ES345416A1 (en) |
FI (1) | FI48724C (en) |
FR (1) | FR1547627A (en) |
GB (1) | GB1205786A (en) |
IL (1) | IL28661A (en) |
LU (1) | LU54269A1 (en) |
NL (1) | NL6713925A (en) |
NO (1) | NO124109B (en) |
SE (1) | SE355357B (en) |
YU (1) | YU31709B (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2121958C3 (en) * | 1971-04-27 | 1981-05-27 | Schering Ag Berlin Und Bergkamen, 1000 Berlin | Herbicidal agents based on carbamoyloxyphenyl carbamate mixtures |
DE2310648C3 (en) * | 1973-03-01 | 1982-05-06 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Diurethanes, processes for the preparation of these compounds and selective herbicidal agents containing them |
JPS63149254U (en) * | 1987-03-23 | 1988-09-30 | ||
DE3827221A1 (en) * | 1988-08-11 | 1990-02-15 | Bayer Ag | SUBSTITUTED N-PHENYL NITROGEN OR NITROGEN-SULFUR HETEROCYCLES, METHODS AND CORRESPONDING HETEROCYCLIC PHENOL DERIVATIVES, PHENYLISO (THIO) CYANATES AND CARBAMATES AS INTERMEDIATE PRODUCTS FOR THEIR PRODUCTION, THEIR USE IN PLANTING PLANT |
-
1966
- 1966-10-15 DE DE19661593523 patent/DE1593523A1/en active Pending
-
1967
- 1967-08-03 CH CH1098867A patent/CH487128A/en not_active IP Right Cessation
- 1967-08-08 LU LU54269D patent/LU54269A1/xx unknown
- 1967-08-30 YU YU1702/67A patent/YU31709B/en unknown
- 1967-08-30 BR BR192549/67A patent/BR6792549D0/en unknown
- 1967-09-20 IL IL28661A patent/IL28661A/en unknown
- 1967-09-23 ES ES345416A patent/ES345416A1/en not_active Expired
- 1967-09-25 CS CS6806A patent/CS151462B2/cs unknown
- 1967-10-02 GB GB44736/67A patent/GB1205786A/en not_active Expired
- 1967-10-04 SE SE13612/67A patent/SE355357B/xx unknown
- 1967-10-13 NO NO170117A patent/NO124109B/no unknown
- 1967-10-13 NL NL6713925A patent/NL6713925A/xx unknown
- 1967-10-13 FI FI672755A patent/FI48724C/en active
- 1967-10-13 BE BE705071D patent/BE705071A/xx not_active IP Right Cessation
- 1967-10-13 FR FR124357A patent/FR1547627A/en not_active Expired
- 1967-10-16 JP JP42066510A patent/JPS5140073B1/ja active Pending
-
1971
- 1971-09-14 CY CY61071A patent/CY610A/en unknown
Also Published As
Publication number | Publication date |
---|---|
LU54269A1 (en) | 1967-10-09 |
JPS5140073B1 (en) | 1976-11-01 |
CY610A (en) | 1971-09-14 |
DE1593523A1 (en) | 1970-07-16 |
CH487128A (en) | 1970-03-15 |
YU170267A (en) | 1973-04-30 |
CS151462B2 (en) | 1973-10-19 |
FI48724B (en) | 1974-09-02 |
NL6713925A (en) | 1968-04-16 |
SE355357B (en) | 1973-04-16 |
FR1547627A (en) | 1968-11-29 |
BE705071A (en) | 1968-04-16 |
YU31709B (en) | 1973-10-31 |
NO124109B (en) | 1972-03-06 |
IL28661A (en) | 1972-05-30 |
BR6792549D0 (en) | 1973-08-28 |
ES345416A1 (en) | 1968-11-16 |
FI48724C (en) | 1974-12-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |