ES345416A1 - Process for the manufacture of n-carbamoyloxyphenyl-carbamates - Google Patents
Process for the manufacture of n-carbamoyloxyphenyl-carbamatesInfo
- Publication number
- ES345416A1 ES345416A1 ES345416A ES345416A ES345416A1 ES 345416 A1 ES345416 A1 ES 345416A1 ES 345416 A ES345416 A ES 345416A ES 345416 A ES345416 A ES 345416A ES 345416 A1 ES345416 A1 ES 345416A1
- Authority
- ES
- Spain
- Prior art keywords
- denote
- amine
- reaction
- formula
- atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
- Incineration Of Waste (AREA)
Abstract
The invention comprises a process of preparing N-carbamoyloxyphenyl carbamates of the formula in which R 4 and R 5 denote hydrogen atoms or aliphatic hydrocarbon groups and R 1 , R 2 and R 3 denote aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic groups, any of which may carry one or more specified substituents, including halogen atoms and alkyl, halogenalkyl and alkoxy groups alternatively, R 1 and R 2 may denote hydrogen atoms or, together with the adjacent nitrogen atom, may denote a heterocyclic group that may contain at least one further nitrogen atom or an oxygen atom. The process of the invention consists in reacting a compound of the formula in which X denotes a hydrogen atom, a monovalent metal or an ammonium, N-alkylammonium, N,N-dialkylammonium or N,N,N- trialkyl-anunonium group, with phosgene in the presence of an amine of the formula R 6 N(R 1 )R 2 , in which R 6 denotes a hydrogen atom or an aliphatic hydrocarbon group. In a modification of the process, the reaction of phosgene with the N-hydroxyphenyl urethane, which yields a chloroformic ester, may precede the reaction with the amine R 6 N(R 1 )R 2 . The reaction may be effected at 0-100 C., optionally in the presence of a solvent and an acid-binding agent, which may be an excess of the amine. A number of phenyl urethanes and amines for use as starting materials are specified, and numerous products obtainable by the process of the invention are listed.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESC039678 | 1966-10-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES345416A1 true ES345416A1 (en) | 1968-11-16 |
Family
ID=7435280
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES345416A Expired ES345416A1 (en) | 1966-10-15 | 1967-09-23 | Process for the manufacture of n-carbamoyloxyphenyl-carbamates |
Country Status (17)
| Country | Link |
|---|---|
| JP (1) | JPS5140073B1 (en) |
| BE (1) | BE705071A (en) |
| BR (1) | BR6792549D0 (en) |
| CH (1) | CH487128A (en) |
| CS (1) | CS151462B2 (en) |
| CY (1) | CY610A (en) |
| DE (1) | DE1593523A1 (en) |
| ES (1) | ES345416A1 (en) |
| FI (1) | FI48724C (en) |
| FR (1) | FR1547627A (en) |
| GB (1) | GB1205786A (en) |
| IL (1) | IL28661A (en) |
| LU (1) | LU54269A1 (en) |
| NL (1) | NL6713925A (en) |
| NO (1) | NO124109B (en) |
| SE (1) | SE355357B (en) |
| YU (1) | YU31709B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2121958C3 (en) * | 1971-04-27 | 1981-05-27 | Schering Ag Berlin Und Bergkamen, 1000 Berlin | Herbicidal agents based on carbamoyloxyphenyl carbamate mixtures |
| DE2310648C3 (en) * | 1973-03-01 | 1982-05-06 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Diurethanes, processes for the preparation of these compounds and selective herbicidal agents containing them |
| JPS63149254U (en) * | 1987-03-23 | 1988-09-30 | ||
| DE3827221A1 (en) * | 1988-08-11 | 1990-02-15 | Bayer Ag | SUBSTITUTED N-PHENYL NITROGEN OR NITROGEN-SULFUR HETEROCYCLES, METHODS AND CORRESPONDING HETEROCYCLIC PHENOL DERIVATIVES, PHENYLISO (THIO) CYANATES AND CARBAMATES AS INTERMEDIATE PRODUCTS FOR THEIR PRODUCTION, THEIR USE IN PLANTING PLANT |
-
1966
- 1966-10-15 DE DE19661593523 patent/DE1593523A1/en active Pending
-
1967
- 1967-08-03 CH CH1098867A patent/CH487128A/en not_active IP Right Cessation
- 1967-08-08 LU LU54269D patent/LU54269A1/xx unknown
- 1967-08-30 BR BR192549/67A patent/BR6792549D0/en unknown
- 1967-08-30 YU YU1702/67A patent/YU31709B/en unknown
- 1967-09-20 IL IL28661A patent/IL28661A/en unknown
- 1967-09-23 ES ES345416A patent/ES345416A1/en not_active Expired
- 1967-09-25 CS CS6806A patent/CS151462B2/cs unknown
- 1967-10-02 GB GB44736/67A patent/GB1205786A/en not_active Expired
- 1967-10-04 SE SE13612/67A patent/SE355357B/xx unknown
- 1967-10-13 NL NL6713925A patent/NL6713925A/xx unknown
- 1967-10-13 NO NO170117A patent/NO124109B/no unknown
- 1967-10-13 FI FI672755A patent/FI48724C/en active
- 1967-10-13 FR FR124357A patent/FR1547627A/en not_active Expired
- 1967-10-13 BE BE705071D patent/BE705071A/xx not_active IP Right Cessation
- 1967-10-16 JP JP42066510A patent/JPS5140073B1/ja active Pending
-
1971
- 1971-09-14 CY CY61071A patent/CY610A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL6713925A (en) | 1968-04-16 |
| GB1205786A (en) | 1970-09-16 |
| CH487128A (en) | 1970-03-15 |
| NO124109B (en) | 1972-03-06 |
| DE1593523A1 (en) | 1970-07-16 |
| FR1547627A (en) | 1968-11-29 |
| JPS5140073B1 (en) | 1976-11-01 |
| CY610A (en) | 1971-09-14 |
| IL28661A (en) | 1972-05-30 |
| BE705071A (en) | 1968-04-16 |
| SE355357B (en) | 1973-04-16 |
| FI48724B (en) | 1974-09-02 |
| YU170267A (en) | 1973-04-30 |
| CS151462B2 (en) | 1973-10-19 |
| YU31709B (en) | 1973-10-31 |
| BR6792549D0 (en) | 1973-08-28 |
| LU54269A1 (en) | 1967-10-09 |
| FI48724C (en) | 1974-12-10 |
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