GB1182073A - Improvements in and relating to Aqueous Copolymer Dispersions - Google Patents

Improvements in and relating to Aqueous Copolymer Dispersions

Info

Publication number
GB1182073A
GB1182073A GB2720/68A GB272068A GB1182073A GB 1182073 A GB1182073 A GB 1182073A GB 2720/68 A GB2720/68 A GB 2720/68A GB 272068 A GB272068 A GB 272068A GB 1182073 A GB1182073 A GB 1182073A
Authority
GB
United Kingdom
Prior art keywords
vinyl
oxide
copolymer
monomers
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2720/68A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Farbwerke Hoechst AG filed Critical Farbwerke Hoechst AG
Publication of GB1182073A publication Critical patent/GB1182073A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/10—Vinyl esters of monocarboxylic acids containing three or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

1,182,073. Aqueous copolymer dispersion. FARBWERKE HOECHST A.G. 18 Jan., 1968 [18 Jan., 19671, No. 2720/68. Heading C3P. An aqueous dispersion of a copolymer is prepared by copolymerizing, by an emulsion p )lymerization, (1) a vinyl ester, an acrylic acid ester, a methacrylic acid ester, or a mixture of any two or more of these substances, if desired together with up to 50%, based on the weight of the total monomer mixture, of one or more other olefinically unsaturated monomers, and (2) at least one monomer of the formula in which n is 1 or 2, B, represents a methyl or a phenyl group and, when n is 1, R 2 represents -OCH 2 COOCH=CH 2 , -COO-CH = CH 2 and when n is 2, R 2 represents in which radicals R 3 represent a straight-chained or branched alkyl radical having from I to 10 carbon atoms, in the presence of from 0.1 to 15% by weight, based on the monomers, of at least one emulsifier and/or protective colloid. In the examples vinyl acetate, vinyl esters of a mixture of C 9 _ 11 aliphatic carboxylic acids branched in the a-position, p-benzoyl-phenoxyacetic acid vinyl ester, p-hydroxybenzophenone acrylate, benzophenone-o-carboxylic acid vinyl ester, 4 - acrylamido - benzophenone, di - nbutylmaleate monomers of formula methyl methacrylate, acrylic acid and butyl acrylate were copolymerized in the presence of water, hydroxyethylation product of nonyl phenol with ethylene oxide, sodium vinylsulphonate, anhydrous sodium acetate, reaction l product of polypropylene oxide and ethylene t oxide, a copolymer of N-vinyl-N-methylacetamide and di-2-ethylhexylmaleate, potassium persulphate and polyvinyl alcohol. The copolymers are pigmented, e.g. with titanium dioxide, barium sulphate, talcum, chalk, heavy spar and hydrated iron oxide and cross-linked with a xenon lamp.
GB2720/68A 1967-01-18 1968-01-18 Improvements in and relating to Aqueous Copolymer Dispersions Expired GB1182073A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0051278 1967-01-18

Publications (1)

Publication Number Publication Date
GB1182073A true GB1182073A (en) 1970-02-25

Family

ID=7104486

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2720/68A Expired GB1182073A (en) 1967-01-18 1968-01-18 Improvements in and relating to Aqueous Copolymer Dispersions

Country Status (5)

Country Link
BE (1) BE709565A (en)
DE (1) DE1720605B2 (en)
FR (1) FR1551563A (en)
GB (1) GB1182073A (en)
NL (1) NL154527B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI455952B (en) * 2010-12-16 2014-10-11 Agi Corp Crosslinkable liquid benzophenone (meth) acrylate

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010002232A1 (en) * 2010-02-23 2011-08-25 Evonik Röhm GmbH, 64293 Benzophenone-containing dispersions for textile applications

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI455952B (en) * 2010-12-16 2014-10-11 Agi Corp Crosslinkable liquid benzophenone (meth) acrylate

Also Published As

Publication number Publication date
FR1551563A (en) 1968-12-27
DE1720605B2 (en) 1975-11-20
NL154527B (en) 1977-09-15
NL6800501A (en) 1968-07-19
DE1720605A1 (en) 1971-06-24
BE709565A (en) 1968-07-18

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