GB1175345A - Process for the Manufacture of beta-Thioether-Thiocarboxylic Acid Esters. - Google Patents

Process for the Manufacture of beta-Thioether-Thiocarboxylic Acid Esters.

Info

Publication number
GB1175345A
GB1175345A GB2868468A GB2868468A GB1175345A GB 1175345 A GB1175345 A GB 1175345A GB 2868468 A GB2868468 A GB 2868468A GB 2868468 A GB2868468 A GB 2868468A GB 1175345 A GB1175345 A GB 1175345A
Authority
GB
United Kingdom
Prior art keywords
thioether
general formula
ester
thiocarboxylic acid
acid esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2868468A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wacker Chemie AG
Original Assignee
Wacker Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wacker Chemie AG filed Critical Wacker Chemie AG
Publication of GB1175345A publication Critical patent/GB1175345A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/38—Thiocarbonic acids; Derivatives thereof, e.g. xanthates ; i.e. compounds containing -X-C(=X)- groups, X being oxygen or sulfur, at least one X being sulfur
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,175,345. # - Thioether - thiocarboxylic acid esters. WACKER-CHEMIE G.m.b.H. 17 June, 1968 [16 June, 1967], No. 28684/68. Heading C2C. The invention comprises a #-thioether-thiocarboxylic acid ester of the general formula prepared by reacting a trithio-o-formic acid ester of the general formula with a ketene of the general formula in the presence of at least 0À05% by weight, calculated on the ester, of, as catalyst, a mineral acid or a Friedel-Crafts catalyst at a temperature within the range of from - 80‹ to 200‹ C., X being -SR, or -CR<SP>1</SP> 2 -CO-SR and each R, which may be the same or different, being a branched or unbranched optionally substituted alkyl radical and each R<SP>1</SP>, which may be the same or different, being a hydrogen or chlorine atom or an alkyl radical. Preferably the radicals R each contain not more than 12 carbon atoms. The process described above may be carried out in the gas or liquid phase, either continuously or discontinuously. If the process is carried out in solution any inert solvent may be used, for example, an ether, a chlorinated hydrocarbon, a hydrocarbon, a carboxylic acid alkyl ester, acetic anhydride, nitrobenzene or a silicon tetraalkylate.
GB2868468A 1967-06-16 1968-06-17 Process for the Manufacture of beta-Thioether-Thiocarboxylic Acid Esters. Expired GB1175345A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEW0044190 1967-06-16

Publications (1)

Publication Number Publication Date
GB1175345A true GB1175345A (en) 1969-12-23

Family

ID=7603972

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2868468A Expired GB1175345A (en) 1967-06-16 1968-06-17 Process for the Manufacture of beta-Thioether-Thiocarboxylic Acid Esters.

Country Status (6)

Country Link
BE (1) BE716581A (en)
CH (1) CH498815A (en)
DE (1) DE1643215B2 (en)
FR (1) FR1568644A (en)
GB (1) GB1175345A (en)
NL (1) NL6808249A (en)

Also Published As

Publication number Publication date
DE1643215A1 (en) 1971-05-27
NL6808249A (en) 1968-12-17
DE1643215C3 (en) 1973-09-27
FR1568644A (en) 1969-05-23
DE1643215B2 (en) 1973-02-15
CH498815A (en) 1970-11-15
BE716581A (en) 1968-12-16

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees