GB1175345A - Process for the Manufacture of beta-Thioether-Thiocarboxylic Acid Esters. - Google Patents
Process for the Manufacture of beta-Thioether-Thiocarboxylic Acid Esters.Info
- Publication number
- GB1175345A GB1175345A GB2868468A GB2868468A GB1175345A GB 1175345 A GB1175345 A GB 1175345A GB 2868468 A GB2868468 A GB 2868468A GB 2868468 A GB2868468 A GB 2868468A GB 1175345 A GB1175345 A GB 1175345A
- Authority
- GB
- United Kingdom
- Prior art keywords
- thioether
- general formula
- ester
- thiocarboxylic acid
- acid esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/38—Thiocarbonic acids; Derivatives thereof, e.g. xanthates ; i.e. compounds containing -X-C(=X)- groups, X being oxygen or sulfur, at least one X being sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C327/00—Thiocarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1,175,345. # - Thioether - thiocarboxylic acid esters. WACKER-CHEMIE G.m.b.H. 17 June, 1968 [16 June, 1967], No. 28684/68. Heading C2C. The invention comprises a #-thioether-thiocarboxylic acid ester of the general formula prepared by reacting a trithio-o-formic acid ester of the general formula with a ketene of the general formula in the presence of at least 0À05% by weight, calculated on the ester, of, as catalyst, a mineral acid or a Friedel-Crafts catalyst at a temperature within the range of from - 80‹ to 200‹ C., X being -SR, or -CR<SP>1</SP> 2 -CO-SR and each R, which may be the same or different, being a branched or unbranched optionally substituted alkyl radical and each R<SP>1</SP>, which may be the same or different, being a hydrogen or chlorine atom or an alkyl radical. Preferably the radicals R each contain not more than 12 carbon atoms. The process described above may be carried out in the gas or liquid phase, either continuously or discontinuously. If the process is carried out in solution any inert solvent may be used, for example, an ether, a chlorinated hydrocarbon, a hydrocarbon, a carboxylic acid alkyl ester, acetic anhydride, nitrobenzene or a silicon tetraalkylate.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEW0044190 | 1967-06-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1175345A true GB1175345A (en) | 1969-12-23 |
Family
ID=7603972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2868468A Expired GB1175345A (en) | 1967-06-16 | 1968-06-17 | Process for the Manufacture of beta-Thioether-Thiocarboxylic Acid Esters. |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE716581A (en) |
CH (1) | CH498815A (en) |
DE (1) | DE1643215B2 (en) |
FR (1) | FR1568644A (en) |
GB (1) | GB1175345A (en) |
NL (1) | NL6808249A (en) |
-
1967
- 1967-06-16 DE DE19671643215 patent/DE1643215B2/en active Granted
-
1968
- 1968-06-12 NL NL6808249A patent/NL6808249A/xx unknown
- 1968-06-13 FR FR1568644D patent/FR1568644A/fr not_active Expired
- 1968-06-13 CH CH877268A patent/CH498815A/en not_active IP Right Cessation
- 1968-06-14 BE BE716581D patent/BE716581A/xx unknown
- 1968-06-17 GB GB2868468A patent/GB1175345A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1643215C3 (en) | 1973-09-27 |
DE1643215B2 (en) | 1973-02-15 |
CH498815A (en) | 1970-11-15 |
FR1568644A (en) | 1969-05-23 |
NL6808249A (en) | 1968-12-17 |
BE716581A (en) | 1968-12-16 |
DE1643215A1 (en) | 1971-05-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |