GB831421A - ª‡,ª‡ bis (chlorophenyl) alkanols - Google Patents
ª‡,ª‡ bis (chlorophenyl) alkanolsInfo
- Publication number
- GB831421A GB831421A GB8504/56A GB850456A GB831421A GB 831421 A GB831421 A GB 831421A GB 8504/56 A GB8504/56 A GB 8504/56A GB 850456 A GB850456 A GB 850456A GB 831421 A GB831421 A GB 831421A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethyl
- chlorophenyl
- bis
- ring
- substituents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/34—Halogenated alcohols
Abstract
Alpha-alpha-bis (chlorophenyl) alkanols are prepared by reaction between a chlorphenyl halide, magnesium and an ester of an organic acid, in presence of a substituted or unsubstituted heterocyclic ether having a 5- or 6membered ring containing only one oxygen atom, the remaining atoms in the ring being carbon except that a substituted nitrogen atom may replace the carbon atom in the 4-position when the ring has 6 atoms, at least one carbon atom adjacent to the oxygen atom being free from substituents, and the ring having at most one double bond and bearing no substituents reactive with the reactants under complexforming conditions. The products may have the formula <FORM:0831421/IV (b)/1> in which R represents 0-4 chlorine atoms or saturated or unsaturated aliphatic radicals, and R1 is a fluorine- or chlorine-substituted or unsubstituted aliphatic radical, or an esterified carboxylic group. In examples, the Grignard compound of Mg. with p-chlorphenyl chloride or bromide is prepared and treated with the esters: ethyl acetate, butyl acetate, ethyl perfluorobutyrate, ethyl perfluorocaprate, ethyl trichloroacetate, dioctyl oxalate, ethyl oxalate, in the compounds tetrahydropyran, tetrahydrofuran, 2 - methyltetrahydrofuran, 2 - ethoxytetrahydropyran, dihydropyran, and tetrahydrofurfuryl ether, as reaction medium. The products are a -a -bis-(p-chlorophenyl)-ethanol, -perfluoro-carbinol and -trichloromethyl carbinol, p-p1-dichlorobenzilate, ethyl dichlorobenzilate, and bis-(p-chlorophenyl)-trifluoromethyl carbinol; a complex is formed between the Mg-compound and the abovementioned reaction media. Other reaction media specified include N-methylmorpholine, and may have as substituents also aryloxy groups. The O of the heterocyclic compound is described as available for co-ordination with the phenyl - magnesium chloride. Specification 826,620 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US831421XA | 1955-11-28 | 1955-11-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB831421A true GB831421A (en) | 1960-03-30 |
Family
ID=22176460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8504/56A Expired GB831421A (en) | 1955-11-28 | 1956-03-19 | ª‡,ª‡ bis (chlorophenyl) alkanols |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB831421A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4482759A (en) * | 1982-02-20 | 1984-11-13 | Degussa Aktiengesellschaft | Fungicidally active benzhydrol derivatives |
US4705902A (en) * | 1985-10-03 | 1987-11-10 | Rohm And Haas Company | DDTR-free 1,1-bis(chlorophenyl)-2,2,2-trichloroethanol |
WO1992000264A1 (en) * | 1990-06-22 | 1992-01-09 | Atochem | Method for preparing 1,1-bis(chlorophenyl) 2,2,2-trichloroethanol |
US5081319A (en) * | 1989-07-18 | 1992-01-14 | Sociedad Espanola De Desarrollos Quimicos S.A. | Process for the preparation of 1,1-bis(4-chlorophenyl)-2,2,2-trichloroethanol |
-
1956
- 1956-03-19 GB GB8504/56A patent/GB831421A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4482759A (en) * | 1982-02-20 | 1984-11-13 | Degussa Aktiengesellschaft | Fungicidally active benzhydrol derivatives |
US4705902A (en) * | 1985-10-03 | 1987-11-10 | Rohm And Haas Company | DDTR-free 1,1-bis(chlorophenyl)-2,2,2-trichloroethanol |
US5081319A (en) * | 1989-07-18 | 1992-01-14 | Sociedad Espanola De Desarrollos Quimicos S.A. | Process for the preparation of 1,1-bis(4-chlorophenyl)-2,2,2-trichloroethanol |
WO1992000264A1 (en) * | 1990-06-22 | 1992-01-09 | Atochem | Method for preparing 1,1-bis(chlorophenyl) 2,2,2-trichloroethanol |
US5245091A (en) * | 1990-06-22 | 1993-09-14 | Elf Atochem S.A. | Process for the preparation of 1,1-bis(chlorophenyl)-2,2,2-trichloroethanol |
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