GB1150303A - A Process for Reducing Anode Corrosion in an Acrylonitrile Hydrodimerization Cell. - Google Patents
A Process for Reducing Anode Corrosion in an Acrylonitrile Hydrodimerization Cell.Info
- Publication number
- GB1150303A GB1150303A GB31072/66A GB3107266A GB1150303A GB 1150303 A GB1150303 A GB 1150303A GB 31072/66 A GB31072/66 A GB 31072/66A GB 3107266 A GB3107266 A GB 3107266A GB 1150303 A GB1150303 A GB 1150303A
- Authority
- GB
- United Kingdom
- Prior art keywords
- amine
- acrylonitrile
- anolyte
- july
- catholyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/29—Coupling reactions
- C25B3/295—Coupling reactions hydrodimerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
1,150,303. Dimerization of acrylonitrile. MONSANTO CO. 11 July, 1966 [26 July, 1965], No. 31072/66. Heading C2C. [Also in Division C7] Acrylonitrile is electrohydrodimerized to adiponitrile in an electrolytic cell having a continuously circulated catholyte including an aqueous quaternary ammonium salt solution, acrylonitrile and reaction products, and a continuously circulated anolyte of aqueous sulphuric acid which is intimately contacted with a water insoluble organic solution of an amine having a molecular weight 250-500, e.g. a mixture of the secondary amines N-dodecenyl- or N-lauryl-N-trialkylmethylamine having molecular weights 350-400 dissolved in xylene, benzene or kerosene, to reduce corrosion of the anode, e.g. made of Pb, Pb-Ag, Pb-Sb, Pt or steel. Other examples of amine, including primary and tertiary, are specified. The amount of amine is preferably sufficient to produce a milliequivalency ratio of amine to deleterious ions, e.g. nitrate or (per)chlorate of at most 5À5. The amine loaded with deleterious ions, on separating from the anolyte, can be recharged by contact with NH 3 or NaOH solution. The anolyte and catholyte may be separated by a cation permselective membrane.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US474934A US3402112A (en) | 1965-07-26 | 1965-07-26 | Process for reducing anode corrosion in an acrylonitrile hydrodimerization cell |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1150303A true GB1150303A (en) | 1969-04-30 |
Family
ID=23885567
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB31072/66A Expired GB1150303A (en) | 1965-07-26 | 1966-07-11 | A Process for Reducing Anode Corrosion in an Acrylonitrile Hydrodimerization Cell. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3402112A (en) |
| AT (1) | AT264493B (en) |
| BE (1) | BE684628A (en) |
| CH (1) | CH456565A (en) |
| DE (1) | DE1593054A1 (en) |
| FR (1) | FR1487571A (en) |
| GB (1) | GB1150303A (en) |
| IL (1) | IL26151A (en) |
| LU (1) | LU51543A1 (en) |
| NL (1) | NL6610248A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL130334C (en) * | 1966-05-03 | |||
| US3619388A (en) * | 1969-02-05 | 1971-11-09 | Asahi Chemical Ind | Process for electrolyzing nitriles |
| US3664936A (en) * | 1969-05-08 | 1972-05-23 | Asahi Chemical Ind | Electrolytic hydrodimerization of acrylonitrile |
| US3897318A (en) * | 1973-08-06 | 1975-07-29 | Monsanto Co | Single-compartment electrolytic hydrodimerization process |
| US4377453A (en) * | 1978-02-10 | 1983-03-22 | National Research Development Corporation | Electrochemical synthesis and product |
| CN105543888A (en) * | 2015-12-29 | 2016-05-04 | 重庆紫光国际化工有限责任公司 | Electrolytic solution used in electrolysis of acrylonitrile for preparing adiponitrile and method |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1065112A (en) * | 1912-04-06 | 1913-06-17 | Thomas James Clarke | Label-holder. |
| US2460259A (en) * | 1946-01-22 | 1949-01-25 | W H And L D Betz | Method of protecting systems for transporting media corrosive to metal |
| US3193480A (en) * | 1963-02-01 | 1965-07-06 | Monsanto Co | Adiponitrile process |
| US3335162A (en) * | 1965-05-10 | 1967-08-08 | Monsanto Co | Polymeric impurity removal from an aqueous quaternary ammonium salt solution |
-
1965
- 1965-07-26 US US474934A patent/US3402112A/en not_active Expired - Lifetime
-
1966
- 1966-07-11 GB GB31072/66A patent/GB1150303A/en not_active Expired
- 1966-07-12 LU LU51543D patent/LU51543A1/xx unknown
- 1966-07-14 IL IL26151A patent/IL26151A/en unknown
- 1966-07-20 NL NL6610248A patent/NL6610248A/xx unknown
- 1966-07-22 FR FR70473A patent/FR1487571A/en not_active Expired
- 1966-07-25 AT AT707466A patent/AT264493B/en active
- 1966-07-25 CH CH1078366A patent/CH456565A/en unknown
- 1966-07-26 DE DE19661593054 patent/DE1593054A1/en active Pending
- 1966-07-26 BE BE684628D patent/BE684628A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1593054A1 (en) | 1970-07-30 |
| US3402112A (en) | 1968-09-17 |
| FR1487571A (en) | 1967-07-07 |
| IL26151A (en) | 1970-02-19 |
| CH456565A (en) | 1968-07-31 |
| LU51543A1 (en) | 1967-01-12 |
| NL6610248A (en) | 1967-01-27 |
| AT264493B (en) | 1968-09-10 |
| BE684628A (en) | 1967-01-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |