GB1137544A - Electrochemical hydrodimerization of acrylonitrile - Google Patents
Electrochemical hydrodimerization of acrylonitrileInfo
- Publication number
- GB1137544A GB1137544A GB16133/66A GB1613366A GB1137544A GB 1137544 A GB1137544 A GB 1137544A GB 16133/66 A GB16133/66 A GB 16133/66A GB 1613366 A GB1613366 A GB 1613366A GB 1137544 A GB1137544 A GB 1137544A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catholyte
- anolyte
- acrylonitrile
- lead
- anode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 229920000867 polyelectrolyte Polymers 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 abstract 1
- QKFFSWPNFCXGIQ-UHFFFAOYSA-M 4-methylbenzenesulfonate;tetraethylazanium Chemical compound CC[N+](CC)(CC)CC.CC1=CC=C(S([O-])(=O)=O)C=C1 QKFFSWPNFCXGIQ-UHFFFAOYSA-M 0.000 abstract 1
- 229910000497 Amalgam Inorganic materials 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 229910052586 apatite Inorganic materials 0.000 abstract 1
- 229940000488 arsenic acid Drugs 0.000 abstract 1
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000004568 cement Substances 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052631 glauconite Inorganic materials 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 229910001410 inorganic ion Inorganic materials 0.000 abstract 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical class [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 abstract 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920001195 polyisoprene Polymers 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 239000012266 salt solution Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/29—Coupling reactions
- C25B3/295—Coupling reactions hydrodimerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB0081447 | 1965-04-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1137544A true GB1137544A (en) | 1968-12-27 |
Family
ID=6981102
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB16133/66A Expired GB1137544A (en) | 1965-04-14 | 1966-04-13 | Electrochemical hydrodimerization of acrylonitrile |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3427234A (cs) |
| BE (1) | BE679514A (cs) |
| DE (1) | DE1518548A1 (cs) |
| GB (1) | GB1137544A (cs) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2019108A1 (cs) * | 1968-09-28 | 1970-06-26 | Ucb Union Chimique | |
| US3887442A (en) * | 1970-11-23 | 1975-06-03 | Scm Corp | Polymerization process |
| US3925172A (en) * | 1972-02-14 | 1975-12-09 | American Cyanamid Co | Electrochemical oxidation and reduction |
| US4043879A (en) * | 1972-07-21 | 1977-08-23 | Keuffel & Esser Company | Electrolytically induced polymerization utilizing bisulfite adduct free radical precursor |
| US4012295A (en) * | 1972-07-21 | 1977-03-15 | Keuffel & Esser Company | Electrolytically induced polymerization utilizing bisulfite adduct free radical precursor |
| US3898140A (en) * | 1973-08-06 | 1975-08-05 | Monsanto Co | Electrolytic hydrodimerization process improvement |
| US3871976A (en) * | 1973-09-10 | 1975-03-18 | Standard Oil Co | Electrochemical adiponitrile process |
| US3966566A (en) * | 1974-08-15 | 1976-06-29 | Monsanto Company | Electrolytic hydrodimerization process improvement |
| JPS526374A (en) * | 1975-07-07 | 1977-01-18 | Tokuyama Soda Co Ltd | Anode structure for electrolysis |
| US4101395A (en) * | 1976-08-30 | 1978-07-18 | Tokuyama Soda Kabushiki Kaisha | Cathode-structure for electrolysis |
| US4235695A (en) * | 1977-12-09 | 1980-11-25 | Diamond Shamrock Technologies S.A. | Novel electrodes and their use |
| US4521283A (en) * | 1983-03-25 | 1985-06-04 | Ppg Industries, Inc. | Electro organic method and apparatus for carrying out same |
| US4472252A (en) * | 1983-03-25 | 1984-09-18 | Ppg Industries, Inc. | Electrolytic synthesis of organic compounds from gaseous reactants |
| US4636286A (en) * | 1983-03-25 | 1987-01-13 | Ppg Industries, Inc. | Electro organic method |
| US4462876A (en) * | 1983-03-25 | 1984-07-31 | Ppg Industries, Inc. | Electro organic method and apparatus for carrying out same |
| US4472251A (en) * | 1983-03-25 | 1984-09-18 | Ppg Industries, Inc. | Electrolytic synthesis of organic compounds from gaseous reactant |
| US4596638A (en) * | 1985-04-26 | 1986-06-24 | International Fuel Cells Corporation | Method for the electrochemical production of adiponitrile using anodes having NiCo2 O4 catalyst |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE496550A (cs) * | 1949-07-09 | |||
| US2815320A (en) * | 1953-10-23 | 1957-12-03 | Kollsman Paul | Method of and apparatus for treating ionic fluids by dialysis |
| US3124520A (en) * | 1959-09-28 | 1964-03-10 | Electrode | |
| US3135674A (en) * | 1960-06-06 | 1964-06-02 | Electric Storage Battery Co | Method and apparatus for the purification of water |
| US3193480A (en) * | 1963-02-01 | 1965-07-06 | Monsanto Co | Adiponitrile process |
| US3244612A (en) * | 1961-11-29 | 1966-04-05 | George W Murphy | Demineralization electrodes and fabrication techniques therefor |
| US3245889A (en) * | 1963-02-25 | 1966-04-12 | Monsanto Co | Electrolytic method for preparing low weight polymers of acrylonitrile |
-
1965
- 1965-04-14 DE DE19651518548 patent/DE1518548A1/de active Pending
-
1966
- 1966-04-13 GB GB16133/66A patent/GB1137544A/en not_active Expired
- 1966-04-13 US US542255A patent/US3427234A/en not_active Expired - Lifetime
- 1966-04-14 BE BE679514D patent/BE679514A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1518548A1 (de) | 1969-05-14 |
| US3427234A (en) | 1969-02-11 |
| BE679514A (cs) | 1966-10-14 |
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