GB1124610A - Continuous emulsion polymerization - Google Patents
Continuous emulsion polymerizationInfo
- Publication number
- GB1124610A GB1124610A GB55363/65A GB5536365A GB1124610A GB 1124610 A GB1124610 A GB 1124610A GB 55363/65 A GB55363/65 A GB 55363/65A GB 5536365 A GB5536365 A GB 5536365A GB 1124610 A GB1124610 A GB 1124610A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- acrylic acid
- sulphonate
- monomers
- ascending
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007720 emulsion polymerization reaction Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 7
- 230000001174 ascending effect Effects 0.000 abstract 3
- 239000000839 emulsion Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000004815 dispersion polymer Substances 0.000 abstract 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004160 Ammonium persulphate Substances 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- XGFHWMMEKYDAEA-UHFFFAOYSA-N C(C(=C)C)(=O)N.C(C=C)#N.C(=C)(Cl)Cl Chemical compound C(C(=C)C)(=O)N.C(C=C)#N.C(=C)(Cl)Cl XGFHWMMEKYDAEA-UHFFFAOYSA-N 0.000 abstract 1
- RDFMVCBRSFPCLB-UHFFFAOYSA-M C(C=C)(=O)O.C(=C)S(=O)(=O)[O-].[Na+].C(C)(=O)OC=C.C(C=C)(=O)OCCCC Chemical compound C(C=C)(=O)O.C(=C)S(=O)(=O)[O-].[Na+].C(C)(=O)OC=C.C(C=C)(=O)OCCCC RDFMVCBRSFPCLB-UHFFFAOYSA-M 0.000 abstract 1
- YAAQEISEHDUIFO-UHFFFAOYSA-N C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 Chemical compound C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 YAAQEISEHDUIFO-UHFFFAOYSA-N 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004159 Potassium persulphate Substances 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- JGLARGMSJZNJLM-UHFFFAOYSA-M [Na+].[O-]S(=O)(=O)C=C.CCC(=O)OC=C Chemical compound [Na+].[O-]S(=O)(=O)C=C.CCC(=O)OC=C JGLARGMSJZNJLM-UHFFFAOYSA-M 0.000 abstract 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 230000005587 bubbling Effects 0.000 abstract 1
- XHVYCNBSAALTIH-UHFFFAOYSA-N butyl prop-2-enoate;ethenyl acetate;prop-2-enoic acid Chemical compound OC(=O)C=C.CC(=O)OC=C.CCCCOC(=O)C=C XHVYCNBSAALTIH-UHFFFAOYSA-N 0.000 abstract 1
- BPOZNMOEPOHHSC-UHFFFAOYSA-N butyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCCCOC(=O)C=C BPOZNMOEPOHHSC-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 abstract 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Polymers CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000019394 potassium persulphate Nutrition 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2435—Loop-type reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB79970A DE1240286B (de) | 1965-01-02 | 1965-01-02 | Verfahren zur kontinuierlichen Emulsions-polymerisation olefinisch ungesaettigter Verbindungen |
| DE1965B0080403 DE1255926C2 (de) | 1965-01-02 | 1965-02-06 | Verfahren zur kontinuierlichen emulsionspolymerisation olefinisch ungesaettigter verbindungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1124610A true GB1124610A (en) | 1968-08-21 |
Family
ID=25967345
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB55363/65A Expired GB1124610A (en) | 1965-01-02 | 1965-12-31 | Continuous emulsion polymerization |
Country Status (6)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0145325A3 (en) * | 1983-11-18 | 1986-06-11 | Reed International P.L.C. | Production of emulsion polymers |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2044364A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1969-05-19 | 1971-02-19 | Pechiney Saint Gobain | |
| US3927982A (en) * | 1970-03-18 | 1975-12-23 | Du Pont | Recirculating apparatus for continuous esterification reactions |
| DE2309368C3 (de) * | 1973-02-24 | 1984-09-27 | Bayer Ag, 5090 Leverkusen | Kontinuierliches Verfahren zur Herstellung von Copolymerisat-Dispersionen |
| NL181435B (nl) * | 1973-10-17 | 1900-01-01 | Montedison Spa | Werkwijze voor polymerisatie onder druk in een buisvormige reactor. |
| IT1062730B (it) * | 1976-07-12 | 1984-11-10 | Montedison Spa | Reattore tubolare per la polimerizzazione ad alta pressione delle alfa olefine |
| DE2810644A1 (de) * | 1978-03-11 | 1979-09-13 | Basf Ag | Verfahren zur hydroformylierung von olefinen |
| DE2830126A1 (de) * | 1978-07-08 | 1980-01-24 | Blenke Heinz | Verfahren und vorrichtung zur durchfuehrung (bio-)chemischer reaktionen in fluiden systemen |
| FR2430794A1 (fr) * | 1978-07-13 | 1980-02-08 | Ugine Kuhlmann | Perfectionnement aux reacteurs d'hydroformylation |
| DE2847443A1 (de) * | 1978-11-02 | 1980-05-22 | Blenke Heinz | Verfahren und vorrichtung zur durchfuehrung (bio-)chemischer reaktionen und verfahrenstechnischer grundoperationen in fluiden systemen |
| US4402914A (en) * | 1981-07-10 | 1983-09-06 | Eckhoff Paul S | Apparatus for continuous production of emulsions |
| US4508858A (en) * | 1983-02-16 | 1985-04-02 | Marathon Oil Company | Apparatus and method for preparing polymer solutions |
| US4965298A (en) * | 1988-08-16 | 1990-10-23 | Marathon Oil Company | Preparation and cooling of aqueous polymer solution |
| DE4120203A1 (de) * | 1991-06-19 | 1992-12-24 | Basf Ag | Verfahren zur herstellung von schlagzaehem polystyrol |
| DE19648744A1 (de) † | 1996-11-25 | 1998-05-28 | Basf Ag | Verfahren zur Herstellung einer Polymerdispersion durch radikalische wäßrige Emulsionspolymerisation mit einer kontinuierlich hergestellten wäßrigen Monomerenemulsion |
| CA2378013C (en) | 1999-07-14 | 2007-10-09 | Marco A. Villalobos | Process for the continuous production of epoxy-(meth)acrylic-styrene polymers and their use in coating |
| WO2001034293A1 (en) * | 1999-11-11 | 2001-05-17 | Akzo Nobel N.V. | Emulsion polymerization process and reactor for such a process |
| US6605681B1 (en) | 2000-07-12 | 2003-08-12 | Johnson Polymer, Inc. | Process for the continuous production of epoxylated addition polymers, and powder and liquid coating applications containing epoxylated addition polymers |
| US6906164B2 (en) * | 2000-12-07 | 2005-06-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
| PL217902B1 (pl) * | 2000-12-07 | 2014-09-30 | Eastman Chem Co | Sposób wytwarzania monomeru poliestru i urządzenie do wytwarzania monomeru poliestru |
| US7135541B2 (en) | 2003-06-06 | 2006-11-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
| US7074879B2 (en) * | 2003-06-06 | 2006-07-11 | Eastman Chemical Company | Polyester process using a pipe reactor |
| US7332548B2 (en) * | 2004-03-04 | 2008-02-19 | Eastman Chemical Company | Process for production of a polyester product from alkylene oxide and carboxylic acid |
| US20080139780A1 (en) * | 2006-12-07 | 2008-06-12 | Debruin Bruce Roger | Polyester production system employing short residence time esterification |
| US7649109B2 (en) * | 2006-12-07 | 2010-01-19 | Eastman Chemical Company | Polyester production system employing recirculation of hot alcohol to esterification zone |
| US7943094B2 (en) | 2006-12-07 | 2011-05-17 | Grupo Petrotemex, S.A. De C.V. | Polyester production system employing horizontally elongated esterification vessel |
| US7863477B2 (en) * | 2007-03-08 | 2011-01-04 | Eastman Chemical Company | Polyester production system employing hot paste to esterification zone |
| US7858730B2 (en) | 2007-07-12 | 2010-12-28 | Eastman Chemical Company | Multi-level tubular reactor with dual headers |
| US7872090B2 (en) | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Reactor system with optimized heating and phase separation |
| US7868129B2 (en) | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Sloped tubular reactor with spaced sequential trays |
| US7872089B2 (en) | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Multi-level tubular reactor with internal tray |
| US7829653B2 (en) | 2007-07-12 | 2010-11-09 | Eastman Chemical Company | Horizontal trayed reactor |
| US7842777B2 (en) | 2007-07-12 | 2010-11-30 | Eastman Chemical Company | Sloped tubular reactor with divided flow |
| US7868130B2 (en) | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Multi-level tubular reactor with vertically spaced segments |
| US7847053B2 (en) | 2007-07-12 | 2010-12-07 | Eastman Chemical Company | Multi-level tubular reactor with oppositely extending segments |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL46748C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1936-10-10 | |||
| DE728644C (de) * | 1937-08-11 | 1942-12-01 | Ig Farbenindustrie Ag | Verfahren zur Herstellung von kuenstlischen kautschukartigen Massen |
| NL73983C (nl) * | 1949-12-27 | 1954-01-15 | Bataafsche Petroleum | Werkwijze voor het polymeriseren van onverzadigde verbindingen, in water geëmulgeerd. |
| DE905547C (de) * | 1951-01-17 | 1954-03-04 | Bataafsche Petroleum | Verfahren zum Polymerisieren olefinisch ungesaettigter Verbindungen |
| US2989517A (en) * | 1954-05-06 | 1961-06-20 | Dow Chemical Co | Polymerization method |
| US2885389A (en) * | 1955-07-05 | 1959-05-05 | Koppers Co Inc | Polymerization processes |
-
1965
- 1965-01-02 DE DEB79970A patent/DE1240286B/de active Pending
- 1965-02-06 DE DE1965B0080403 patent/DE1255926C2/de not_active Expired
- 1965-12-27 US US516274A patent/US3458467A/en not_active Expired - Lifetime
- 1965-12-30 NL NL6517186A patent/NL6517186A/xx unknown
- 1965-12-31 BE BE674648D patent/BE674648A/xx unknown
- 1965-12-31 FR FR44468A patent/FR1466640A/fr not_active Expired
- 1965-12-31 GB GB55363/65A patent/GB1124610A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0145325A3 (en) * | 1983-11-18 | 1986-06-11 | Reed International P.L.C. | Production of emulsion polymers |
Also Published As
| Publication number | Publication date |
|---|---|
| US3458467A (en) | 1969-07-29 |
| BE674648A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1966-04-15 |
| DE1255926C2 (de) | 1975-06-12 |
| FR1466640A (fr) | 1967-01-20 |
| NL6517186A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1966-07-04 |
| DE1255926B (de) | 1975-06-12 |
| DE1240286B (de) | 1967-05-11 |
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