GB1118293A - Acyloin compounds - Google Patents
Acyloin compoundsInfo
- Publication number
- GB1118293A GB1118293A GB3459965A GB3459965A GB1118293A GB 1118293 A GB1118293 A GB 1118293A GB 3459965 A GB3459965 A GB 3459965A GB 3459965 A GB3459965 A GB 3459965A GB 1118293 A GB1118293 A GB 1118293A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acyloin
- compounds
- methyl
- produced
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MWKAGZWJHCTVJY-UHFFFAOYSA-N 3-hydroxyoctadecan-2-one Chemical class CCCCCCCCCCCCCCCC(O)C(C)=O MWKAGZWJHCTVJY-UHFFFAOYSA-N 0.000 title abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
- MZQGUGAQJZCZOC-UHFFFAOYSA-N 5-(3,4-dimethoxyphenyl)-4-methyl-2-oxo-1,3-oxazolidine-4-carboxamide Chemical compound C(N)(=O)C1(NC(OC1C1=CC(=C(C=C1)OC)OC)=O)C MZQGUGAQJZCZOC-UHFFFAOYSA-N 0.000 abstract 1
- 241000588915 Klebsiella aerogenes Species 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 abstract 1
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 abstract 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical group [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Acyloin compounds of the formula R1CHOHCOCH3 where R1 is a 3,4-disubstituted phenyl radical in which said substituents are hydroxyl, C1-C4 alkoxy or C1-C4 alkylenedioxy radicals, said compounds being in the L configuration, are produced by contacting an aldehyde of the formula R1CO, where R1 is as defined above, with an acyloin producing strain of a growing culture of Aerobacter aerogenes (A.T.C.C. No. 211) or Saccharomyces cerevisiae. The invention also comprises L(-)3,4-dimethoxy-, L(-)3-methoxy - 4 - hydroxy- and L(-)3,4 - methylene-dioxy-phenyl acetyl carbinols. Examples are furnished. L - a - methyl - 3,4 - dihydroxyphenylalanine is produced by converting L(-)3,4-dimethoxyphenylacetyl carbinol to 4-carbamoyl - 4 - methyl - 5 - (3,4 - dimethoxyphenyl)-2-oxazolidinone and treating the latter with hydrogen iodide and red phosphorus.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39050264A | 1964-08-19 | 1964-08-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1118293A true GB1118293A (en) | 1968-06-26 |
Family
ID=23542721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3459965A Expired GB1118293A (en) | 1964-08-19 | 1965-08-12 | Acyloin compounds |
Country Status (5)
| Country | Link |
|---|---|
| BR (1) | BR6572223D0 (en) |
| CH (1) | CH454162A (en) |
| DE (1) | DE1518029B1 (en) |
| GB (1) | GB1118293A (en) |
| NL (1) | NL6510879A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013061041A1 (en) | 2011-10-24 | 2013-05-02 | The Secretary Of State For Business Innovation & Skills Of Her Majesty's Britannic Goverment | Electrochemical assay |
-
1965
- 1965-07-14 CH CH989065A patent/CH454162A/en unknown
- 1965-08-12 GB GB3459965A patent/GB1118293A/en not_active Expired
- 1965-08-18 BR BR17222365A patent/BR6572223D0/en unknown
- 1965-08-18 DE DE19651518029 patent/DE1518029B1/en active Pending
- 1965-08-19 NL NL6510879A patent/NL6510879A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013061041A1 (en) | 2011-10-24 | 2013-05-02 | The Secretary Of State For Business Innovation & Skills Of Her Majesty's Britannic Goverment | Electrochemical assay |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6510879A (en) | 1966-02-21 |
| DE1518029B1 (en) | 1971-02-11 |
| CH454162A (en) | 1968-04-15 |
| BR6572223D0 (en) | 1973-08-14 |
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