ES324898A1 - A procedure for the preparation of ciclopentenonas. (Machine-translation by Google Translate, not legally binding) - Google Patents
A procedure for the preparation of ciclopentenonas. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES324898A1 ES324898A1 ES0324898A ES324898A ES324898A1 ES 324898 A1 ES324898 A1 ES 324898A1 ES 0324898 A ES0324898 A ES 0324898A ES 324898 A ES324898 A ES 324898A ES 324898 A1 ES324898 A1 ES 324898A1
- Authority
- ES
- Spain
- Prior art keywords
- general formula
- formula
- translation
- preparation
- machine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- BZKFMUIJRXWWQK-UHFFFAOYSA-N Cyclopentenone Chemical class O=C1CCC=C1 BZKFMUIJRXWWQK-UHFFFAOYSA-N 0.000 abstract 2
- 150000002081 enamines Chemical class 0.000 abstract 2
- 150000003509 tertiary alcohols Chemical class 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0061—Essential oils; Perfumes compounds containing a six-membered aromatic ring not condensed with another ring
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/203—Alicyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/516—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of nitrogen-containing compounds to >C = O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
- C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/597—Unsaturated compounds containing a keto groups being part of a ring of a five-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/613—Unsaturated compounds containing a keto groups being part of a ring polycyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/647—Unsaturated compounds containing a keto groups being part of a ring having unsaturation outside the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
- C07C49/683—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings having unsaturation outside the aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
- C11B9/003—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing less than six carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
Abstract
A process for the preparation of cyclopentenones, of the general formula ** (See formula) ** wherein R1 represents hydrogen or an alkyl radical and R2 represents an alkyl, alkenyl, aryl or aralkyl radical or a saturated or unsaturated cycloaliphatic radical, characterized in that it consists in reacting a compound of the general formula ** (See formula) ** wherein R1 has the meaning set forth above, with a secondary amine of the general formula ** (See formula) ** where A and B represent organic radicals, which can be linked together to form a cyclic system, to form an enamine of the general formula ** (See formula) ** where A, B and R1 have the meaning stated above, in reacting the enamine with a donor agent of R2, so as to form a tertiary alcohol of the general formula ** (See formula) ** where R1 and R2 have the meaning stated above, and in dehydrating said tertiary alcohol, to form a cyclopentenone of the general formula I above. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US44441065A | 1965-03-31 | 1965-03-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES324898A1 true ES324898A1 (en) | 1966-12-16 |
Family
ID=23764770
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES0324898A Expired ES324898A1 (en) | 1965-03-31 | 1966-03-30 | A procedure for the preparation of ciclopentenonas. (Machine-translation by Google Translate, not legally binding) |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE677905A (en) |
CH (1) | CH464182A (en) |
DE (1) | DE1568668A1 (en) |
ES (1) | ES324898A1 (en) |
GB (1) | GB1096427A (en) |
IT (1) | IT1043759B (en) |
NL (1) | NL6604284A (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55127316A (en) * | 1979-03-26 | 1980-10-02 | Nippon Zeon Co Ltd | Perfume composition |
ATE380474T1 (en) | 2000-05-23 | 2007-12-15 | Nestle Sa | USE OF ALPHA-KETOENAMINE DERIVATIVES AS COOLING AGENT |
EP1157617B1 (en) * | 2000-05-23 | 2007-12-12 | Nestle Sa | Use of alpha-keto enamine derivatives as coolants |
CN113185392A (en) * | 2021-04-26 | 2021-07-30 | 安徽华业香料合肥有限公司 | Synthesis method of dihydro jasmone |
CN117813368A (en) * | 2021-08-13 | 2024-04-02 | 巴斯夫欧洲公司 | Use of substituted cyclopentenones and cyclopentanones as fragrance ingredients |
-
1966
- 1966-02-25 CH CH280266A patent/CH464182A/en unknown
- 1966-03-01 DE DE19661568668 patent/DE1568668A1/en active Pending
- 1966-03-16 BE BE677905D patent/BE677905A/xx unknown
- 1966-03-23 IT IT6559/66A patent/IT1043759B/en active
- 1966-03-24 GB GB13081/66A patent/GB1096427A/en not_active Expired
- 1966-03-30 ES ES0324898A patent/ES324898A1/en not_active Expired
- 1966-03-31 NL NL6604284A patent/NL6604284A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
CH464182A (en) | 1968-10-31 |
IT1043759B (en) | 1980-02-29 |
NL6604284A (en) | 1966-10-03 |
BE677905A (en) | 1966-09-16 |
DE1568668A1 (en) | 1970-03-26 |
GB1096427A (en) | 1967-12-29 |
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