GB1111920A - A process for production of filaments,fibres and films from acrylonitrile polymers - Google Patents

A process for production of filaments,fibres and films from acrylonitrile polymers

Info

Publication number
GB1111920A
GB1111920A GB37780/66A GB3778066A GB1111920A GB 1111920 A GB1111920 A GB 1111920A GB 37780/66 A GB37780/66 A GB 37780/66A GB 3778066 A GB3778066 A GB 3778066A GB 1111920 A GB1111920 A GB 1111920A
Authority
GB
United Kingdom
Prior art keywords
polymer
plasticizer
fibres
films
filaments
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB37780/66A
Inventor
Wilhelm Brenschede
Herbert Marzolph
Alfred Nogaj
Helmut Reichardt
Alfred Reichle
Martin Wandel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1111920A publication Critical patent/GB1111920A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18—Homopolymers or copolymers of nitriles
    • C08L33/20—Homopolymers or copolymers of acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Artificial Filaments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Acrylonitrile polymers containing at least 80% by weight of acrylonitrile units are plasticized with 1 to 20% by weight of polymer of a plasticizer comprising an aryl ester of a C6-C18 aliphatic sulphonic acid or a mixture of a dialkyl phthalate having 1 to 4 carbon atoms in each alkyl group and either an aryl ester of an aliphatic sulphonic acid or a polyester derived from adipic acid and a diol (e.g. a C2-C8 aliphatic diol). The polymer may be a homopolymer or a copolymer, e.g. with methyl acrylate. The plasticized polymers are processed to form filaments, fibres or films. The plasticizer may be added to a solution of the polymer in a solvent such as dimethyl formamide, dimethyl acetamide or dimethyl sulphone, from which the shaped products can then be formed; or the plasticizer may be admixed with the polymer before dissolution.
GB37780/66A 1965-09-11 1966-08-23 A process for production of filaments,fibres and films from acrylonitrile polymers Expired GB1111920A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEF0047166 1965-09-11
DEF0047165 1965-09-11
DEF0047167 1965-09-11

Publications (1)

Publication Number Publication Date
GB1111920A true GB1111920A (en) 1968-05-01

Family

ID=27210456

Family Applications (1)

Application Number Title Priority Date Filing Date
GB37780/66A Expired GB1111920A (en) 1965-09-11 1966-08-23 A process for production of filaments,fibres and films from acrylonitrile polymers

Country Status (8)

Country Link
US (1) US3535251A (en)
BE (1) BE686694A (en)
CH (1) CH469823A (en)
DE (3) DE1544915C3 (en)
FR (1) FR1513308A (en)
GB (1) GB1111920A (en)
NL (1) NL6612675A (en)
SE (1) SE337922B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3875102A (en) * 1969-09-15 1975-04-01 Chevron Res Polyvinyl chloride plasticized with methyl esters of organic sulfonic acid oligomer
US4244852A (en) * 1978-11-16 1981-01-13 The Standard Oil Company Rubber-modified high nitrile copolymers with improved impact resistance

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2404717A (en) * 1942-06-17 1946-07-23 Du Pont Preparation of solutions
US2426728A (en) * 1944-02-25 1947-09-02 Prophylactic Brush Co Molecularly oriented copolymers of acrylonitrile, a saturated monohydric alcohol ester of an ethylene alpha beta dicarboxylic acid, and acrylic esters or vinyl ethers
US2474350A (en) * 1944-06-24 1949-06-28 Pittsburgh Plate Glass Co Polysulfone resin plasticized with ester of organic sulfonic acid
US2555062A (en) * 1948-03-24 1951-05-29 Ici Ltd Vinyl chloride polymers plasticized with plyesters
US2503245A (en) * 1948-09-16 1950-04-11 Eastman Kodak Co Solutions of acrylonitrile polymers
US2559172A (en) * 1950-09-19 1951-07-03 American Cyanamid Co Compositions comprising polyacrylonitrile and beta, beta'-iminodipropionitrile
US2613195A (en) * 1950-09-26 1952-10-07 Chemstrand Corp Fiber spinning solutions
US2689862A (en) * 1951-04-20 1954-09-21 Monsanto Chemicals Improvement in color of aryl alkane sulfonates
NL122410C (en) * 1960-03-11
US3328365A (en) * 1964-03-11 1967-06-27 Monsanto Co Acrylonitrile, vinyl chloride 1, 2-dichloroethylene terpolymer and process of preparing same

Also Published As

Publication number Publication date
DE1544916A1 (en) 1969-07-24
US3535251A (en) 1970-10-20
DE1544915C3 (en) 1974-11-14
DE1544914A1 (en) 1969-07-24
DE1544915B2 (en) 1974-03-28
DE1544915A1 (en) 1969-07-24
NL6612675A (en) 1967-03-13
CH469823A (en) 1969-03-15
FR1513308A (en) 1968-02-16
DE1544914B2 (en) 1973-11-29
SE337922B (en) 1971-08-23
BE686694A (en) 1967-02-15

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