GB1104644A - Preparation of acrylonitrile and methacrylonitrile - Google Patents
Preparation of acrylonitrile and methacrylonitrileInfo
- Publication number
- GB1104644A GB1104644A GB44718/66A GB4471866A GB1104644A GB 1104644 A GB1104644 A GB 1104644A GB 44718/66 A GB44718/66 A GB 44718/66A GB 4471866 A GB4471866 A GB 4471866A GB 1104644 A GB1104644 A GB 1104644A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- stannous
- silica
- reaction
- silica gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title abstract 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 title abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 8
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 abstract 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- 238000006243 chemical reaction Methods 0.000 abstract 4
- 239000000741 silica gel Substances 0.000 abstract 4
- 229910002027 silica gel Inorganic materials 0.000 abstract 4
- 239000000377 silicon dioxide Substances 0.000 abstract 4
- 239000003513 alkali Substances 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 239000003960 organic solvent Substances 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 2
- 239000001569 carbon dioxide Substances 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 230000003301 hydrolyzing effect Effects 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000002825 nitriles Chemical class 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000007792 gaseous phase Substances 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000002823 nitrates Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6572265 | 1965-10-28 | ||
| JP6572365 | 1965-10-28 | ||
| JP1027166 | 1966-02-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1104644A true GB1104644A (en) | 1968-02-28 |
Family
ID=27278904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB44718/66A Expired GB1104644A (en) | 1965-10-28 | 1966-10-06 | Preparation of acrylonitrile and methacrylonitrile |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3520915A (enExample) |
| DE (1) | DE1568047A1 (enExample) |
| GB (1) | GB1104644A (enExample) |
| NL (2) | NL6615289A (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0255395A1 (en) * | 1986-07-31 | 1988-02-03 | Amoco Corporation | Catalyst for production of alpha,beta-ethylenically unsaturated monocarboxylic acid |
| EP0227461A3 (en) * | 1985-12-23 | 1988-07-27 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Catalyst for vapor-phase intramolecular dehydration reaction of alkanolamines |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4178305A (en) * | 1976-10-15 | 1979-12-11 | Monsanto Company | Oxidative dehydrogenation of propionitrile to acrylonitrile |
| US5095151A (en) * | 1985-05-21 | 1992-03-10 | American Home Products Corporation | Preparation of propranolol hydrochloride macrocrystals |
| CA1276615C (en) * | 1985-12-27 | 1990-11-20 | Yuuji Shimasaki | Catalyst for vapor-phase intermolecular dehydration reaction of alkanolamines |
| US4761393A (en) * | 1987-07-27 | 1988-08-02 | Amoco Corporation | Method for placing a catalytically active alkali metal on a catalyst support |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2385552A (en) * | 1941-12-05 | 1945-09-25 | Rohm & Haas | Dehydrogenation of aliphatic nitriles |
| US2554484A (en) * | 1950-06-17 | 1951-05-29 | Du Pont | Preparation of cyanoalkenes |
| US2554482A (en) * | 1950-06-17 | 1951-05-29 | Du Pont | Preparation of cyanoalkenes |
| US3207805A (en) * | 1960-06-17 | 1965-09-21 | Petro Tex Chem Corp | Dehydrogenation in the presence of oxygen and an ammonium halide |
| US3207806A (en) * | 1960-11-23 | 1965-09-21 | Petro Tex Chem Corp | Dehydrogenation process |
-
0
- NL NL130983D patent/NL130983C/xx active
-
1966
- 1966-10-06 GB GB44718/66A patent/GB1104644A/en not_active Expired
- 1966-10-19 DE DE19661568047 patent/DE1568047A1/de active Granted
- 1966-10-20 US US588108A patent/US3520915A/en not_active Expired - Lifetime
- 1966-10-28 NL NL6615289A patent/NL6615289A/xx unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0227461A3 (en) * | 1985-12-23 | 1988-07-27 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Catalyst for vapor-phase intramolecular dehydration reaction of alkanolamines |
| EP0255395A1 (en) * | 1986-07-31 | 1988-02-03 | Amoco Corporation | Catalyst for production of alpha,beta-ethylenically unsaturated monocarboxylic acid |
| EP0400692A1 (en) * | 1986-07-31 | 1990-12-05 | Amoco Corporation | Process for producing Si02 Sn02 mixed oxide |
Also Published As
| Publication number | Publication date |
|---|---|
| NL130983C (enExample) | |
| NL6615289A (enExample) | 1967-05-02 |
| DE1568047B2 (enExample) | 1973-10-31 |
| DE1568047C3 (enExample) | 1974-06-27 |
| DE1568047A1 (de) | 1970-01-08 |
| US3520915A (en) | 1970-07-21 |
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