GB1103334A - New cyanine dyes derived from the 2-ethylmercapto-5-acetaminothiazole, and their use especially as photographic sensitizers - Google Patents

New cyanine dyes derived from the 2-ethylmercapto-5-acetaminothiazole, and their use especially as photographic sensitizers

Info

Publication number
GB1103334A
GB1103334A GB2894965A GB2894965A GB1103334A GB 1103334 A GB1103334 A GB 1103334A GB 2894965 A GB2894965 A GB 2894965A GB 2894965 A GB2894965 A GB 2894965A GB 1103334 A GB1103334 A GB 1103334A
Authority
GB
United Kingdom
Prior art keywords
ethylmercapto
acetaminothiazole
cyanine dyes
use especially
dyes derived
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2894965A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ferrania SpA
Original Assignee
Ferrania SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ferrania SpA filed Critical Ferrania SpA
Publication of GB1103334A publication Critical patent/GB1103334A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/08Sensitivity-increasing substances
    • G03C1/10Organic substances
    • G03C1/12Methine and polymethine dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/04Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups one >CH- group, e.g. cyanines, isocyanines, pseudocyanines
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/10The polymethine chain containing an even number of >CH- groups
    • C09B23/102The polymethine chain containing an even number of >CH- groups two heterocyclic rings linked carbon-to-carbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

Cyanine and merocyanine dyes are obtained by quaternizing 2 - ethylmercapto - 5 - acetylamino-thiazole and condensing the quaternary salt obtained with a heterocyclic base containing a reactive methyl or keto-methylene group. The invention also comprises cyanine and merocyanine dyes of the formula <FORM:1103334/C4-C5/1> <FORM:1103334/C4-C5/2> where R and R1 are each alkyl, aryl or aralkyl, completes a 5- or 6-membered heterocyclic nucleus which may be substituted, n is 1 or 2 and X is an anion. Examples of the dyes are given, including those of the formulae <FORM:1103334/C4-C5/3> <FORM:1103334/C4-C5/4>
GB2894965A 1964-07-15 1965-07-08 New cyanine dyes derived from the 2-ethylmercapto-5-acetaminothiazole, and their use especially as photographic sensitizers Expired GB1103334A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT4930564 1964-07-15
IT1543764 1964-07-15

Publications (1)

Publication Number Publication Date
GB1103334A true GB1103334A (en) 1968-02-14

Family

ID=26326793

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2894965A Expired GB1103334A (en) 1964-07-15 1965-07-08 New cyanine dyes derived from the 2-ethylmercapto-5-acetaminothiazole, and their use especially as photographic sensitizers

Country Status (3)

Country Link
BE (1) BE666576A (en)
DE (1) DE1569830A1 (en)
GB (1) GB1103334A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USB342886I5 (en) * 1972-03-23 1975-01-28

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USB342886I5 (en) * 1972-03-23 1975-01-28
US3923507A (en) * 1972-03-23 1975-12-02 Agfa Gevaert Ag Sensitized electrophotographic layers

Also Published As

Publication number Publication date
BE666576A (en) 1965-11-03
DE1569830A1 (en) 1970-07-23

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