GB1099559A - A process for producing orthoformic acid alkanol esters - Google Patents

A process for producing orthoformic acid alkanol esters

Info

Publication number
GB1099559A
GB1099559A GB3064566A GB3064566A GB1099559A GB 1099559 A GB1099559 A GB 1099559A GB 3064566 A GB3064566 A GB 3064566A GB 3064566 A GB3064566 A GB 3064566A GB 1099559 A GB1099559 A GB 1099559A
Authority
GB
United Kingdom
Prior art keywords
orthoformic acid
producing
ester
acid alkanol
relatively lower
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3064566A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dynamit Nobel AG
Original Assignee
Dynamit Nobel AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dynamit Nobel AG filed Critical Dynamit Nobel AG
Publication of GB1099559A publication Critical patent/GB1099559A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/04—Formic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/04—Formic acid esters
    • C07C69/06—Formic acid esters of monohydroxylic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Esters of orthoformic acid with C2- 6 alkanols are obtained by reacting an ester of orthoformic acid and a relatively lower alkanol with the appropriate C2- 6 alkanol in the presence of an insoluble organic ion exchanger which contains sulphonic acid residue, and removing from the reaction mixture the relatively lower alkanol liberated by the ester interchange. The reaction may be effected at 15-60 DEG C. and may be carried out batchwise or continuously. In examples orthoformic acid trimethyl ester is reacted with ethanol, n- and iso-propanol and n-butanol in the presence of a sulphonated copolymer of styrene and divinyl benzene as the ion exchanger.
GB3064566A 1965-07-10 1966-07-07 A process for producing orthoformic acid alkanol esters Expired GB1099559A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED0047704 1965-07-10

Publications (1)

Publication Number Publication Date
GB1099559A true GB1099559A (en) 1968-01-17

Family

ID=7050611

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3064566A Expired GB1099559A (en) 1965-07-10 1966-07-07 A process for producing orthoformic acid alkanol esters

Country Status (6)

Country Link
BE (1) BE683679A (en)
CH (1) CH462796A (en)
DE (1) DE1518712C3 (en)
GB (1) GB1099559A (en)
LU (1) LU51512A1 (en)
NL (1) NL6609612A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10350105A1 (en) * 2003-10-27 2005-05-25 Basf Ag Process for the preparation of orthoesters

Also Published As

Publication number Publication date
BE683679A (en) 1967-01-05
DE1518712C3 (en) 1975-04-17
LU51512A1 (en) 1966-09-08
DE1518712A1 (en) 1969-06-12
NL6609612A (en) 1967-01-11
DE1518712B2 (en) 1974-08-22
CH462796A (en) 1968-09-30

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